N,N-Dimethyl-1,4-phenylenediamine sulfate

Modify Date: 2024-01-13 14:27:57

N,N-Dimethyl-1,4-phenylenediamine sulfate Structure
N,N-Dimethyl-1,4-phenylenediamine sulfate structure
Common Name N,N-Dimethyl-1,4-phenylenediamine sulfate
CAS Number 6219-73-4 Molecular Weight 234.273
Density N/A Boiling Point 495 °C(lit.)
Molecular Formula C8H14N2O4S Melting Point 200-205 °C (dec.)(lit.)
MSDS N/A Flash Point 88.6ºC

 Names

Name 4-Amino-N,N-dimethylaniline sulfate
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 495 °C(lit.)
Melting Point 200-205 °C (dec.)(lit.)
Molecular Formula C8H14N2O4S
Molecular Weight 234.273
Flash Point 88.6ºC
Exact Mass 234.067429
PSA 112.24000
LogP 2.34400
Storage condition 2-8°C

 MSDS

Name: N N-Dimethyl-P-Phenylenediamine Sulfate 99% (Titr.) Material Safety Data Sheet
Synonym: 1,4-Benzenediamine, N,N-Dimethyl-, Sulfate
CAS: 6219-73-4
Section 1 - Chemical Product MSDS Name:N N-Dimethyl-P-Phenylenediamine Sulfate 99% (Titr.) Material Safety Data Sheet
Synonym:1,4-Benzenediamine, N,N-Dimethyl-, Sulfate

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
6219-73-4 1,4-Benzenediamine, N,N-Dimethyl-, Sul 98 228-292-7
Hazard Symbols: T
Risk Phrases: 23/24/25

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.The toxicological properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
Chronic:
No information found.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Containers may explode when heated. Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use water spray, fog or regular foam. Cool containers with flooding quantities of water until well after fire is out.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

Section 7 - HANDLING and STORAGE
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 6219-73-4: Personal Protective Equipment Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Powder
Color: beige to gray
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 495 deg C @ 760.00mm Hg
Freezing/Melting Point: 234.00 - 236.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C8H12N2.H2SO4
Molecular Weight: 234.28

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable at room temperature in closed containers under normal storage and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, hydrogen sulfide.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 6219-73-4 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1,4-Benzenediamine, N,N-Dimethyl-, Sulfate - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: DYE, SOLID, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3143
Packing Group: II
IMO
Shipping Name: DYE, SOLID, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3143
Packing Group: II
RID/ADR
Shipping Name: DYE, SOLID, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3143
Packing group: II

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 28 After contact with skin, wash immediately
with...
S 28A After contact with skin, wash immediately with
plenty of water.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 6219-73-4: No information available.
Canada
CAS# 6219-73-4 is listed on Canada's DSL List.
CAS# 6219-73-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 6219-73-4 is listed on the TSCA inventory.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes T:Toxic;
Risk Phrases R23/24/25;R36/37/38
Safety Phrases S26-S36/37/39-S45
RIDADR UN 2811 6.1/PG 2
WGK Germany 3
Packaging Group II
Hazard Class 6.1(a)

 Synonyms

N,N-Dimethylbenzene-1,4-diamine sulfate (1:1)
Dimethylpphenylenediaminesulfate
Fourrine Blue Grey R
N,N-dimethyl-p-phenylenediamine,sulfate
1,4-Benzenediamine, N,N-dimethyl-, sulfate (1:1)
MFCD00012992
1,4-Benzenediamine, N,N-dimethyl-, sulfate (2:1)
N,N-Dimethyl-p-phenylendiamin,Sulfat
4-DIMETHYLAMINOANILINE SULFATE
N,N-Dimethyl-1,4-benzenediamine sulfate (1:1)
Einecs 228-292-7
P-AMINODIMETHYLANILINE SULFATE
EINECS 208-636-2
4-AMINODIMETHYLANILINE SULFATE
Nako Grey DMS
N,N-Dimethyl-1,4-phenylenediamine sulfate
BASF Ursol Grey DMG
C.I. Oxidation Base 8A
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