N'-Isopropylidene-2-nitrobenzenesulfonohydrazide
N'-Isopropylidene-2-nitrobenzenesulfonohydrazide structure
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Common Name | N'-Isopropylidene-2-nitrobenzenesulfonohydrazide | ||
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| CAS Number | 6655-27-2 | Molecular Weight | 257.266 | |
| Density | 1.4±0.1 g/cm3 | Boiling Point | 421.3±47.0 °C at 760 mmHg | |
| Molecular Formula | C9H11N3O4S | Melting Point | 131-135ºC | |
| MSDS | USA | Flash Point | 208.6±29.3 °C | |
| Name | N-Isopropylidene-N-2-Nitrobenzenesulfonohydrazide |
|---|---|
| Synonym | More Synonyms |
| Density | 1.4±0.1 g/cm3 |
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| Boiling Point | 421.3±47.0 °C at 760 mmHg |
| Melting Point | 131-135ºC |
| Molecular Formula | C9H11N3O4S |
| Molecular Weight | 257.266 |
| Flash Point | 208.6±29.3 °C |
| Exact Mass | 257.047028 |
| PSA | 112.73000 |
| LogP | 1.02 |
| Vapour Pressure | 0.0±1.0 mmHg at 25°C |
| Index of Refraction | 1.603 |
| Storage condition | <0°C |
| Personal Protective Equipment | Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter |
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| Hazard Codes | Xi |
| RIDADR | NONH for all modes of transport |
| WGK Germany | 3.0 |
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~97%
N'-Isopropylide... CAS#:6655-27-2 |
| Literature: Movassaghi, Mohammad; Piizzi, Grazia; Siegel, Dustin S.; Piersanti, Giovanni Angewandte Chemie - International Edition, 2006 , vol. 45, # 35 p. 5859 - 5863 |
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~%
N'-Isopropylide... CAS#:6655-27-2 |
| Literature: Bulletin of the Chemical Society of Japan, , vol. 58, # 1 p. 377 - 378 |
| Precursor 3 | |
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| DownStream 0 | |
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N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine, a reagent for reduction of alcohols via the corresponding monoalkyl diazenes.
J. Org. Chem. 72 , 1838, (2007) The reagent N-isopropylidene-N'-2-nitrobenzenesulfonyl hydrazine (IPNBSH) is used in the reduction of alcohols via the loss of dinitrogen from transiently formed monoalkyl diazene intermediates access... |
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A stereospecific palladium-catalyzed route to monoalkyl diazenes for mild allylic reduction.
Angew. Chem. Int. Ed. Engl. 47 , 8909, (2008)
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| 2-nitro-N-(propan-2-ylideneamino)benzenesulfonamide |
| MFCD09800525 |
| Benzenesulfonic acid, 2-nitro-, 2-(1-methylethylidene)hydrazide |
| N'-Isopropylidene-2-nitrobenzenesulfonohydrazide |