3,3-Dimethyloxetane

Modify Date: 2024-01-06 23:20:18

3,3-Dimethyloxetane Structure
3,3-Dimethyloxetane structure
Common Name 3,3-Dimethyloxetane
CAS Number 6921-35-3 Molecular Weight 86.13230
Density 0.835 Boiling Point 81ºC
Molecular Formula C5H10O Melting Point N/A
MSDS Chinese USA Flash Point -9ºC
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger

 Names

Name 3,3-Dimethyloxetane
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.835
Boiling Point 81ºC
Molecular Formula C5H10O
Molecular Weight 86.13230
Flash Point -9ºC
Exact Mass 86.07320
PSA 9.23000
LogP 1.04280
Index of Refraction 1.399

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ3150000
CHEMICAL NAME :
Propane, 1,3-epoxy-2,2-dimethyl-
CAS REGISTRY NUMBER :
6921-35-3
BEILSTEIN REFERENCE NO. :
0102430
LAST UPDATED :
199612
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C5-H10-O
MOLECULAR WEIGHT :
86.15
WISWESSER LINE NOTATION :
T4OTJ C1 C1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2 gm/kg
TOXIC EFFECTS :
Behavioral - general anesthetic
REFERENCE :
JMPCAS Journal of Medicinal and Pharmaceutical Chemistry. (Washington, DC) V.1-5, 1959-62. For publisher information, see JMCMAR. Volume(issue)/page/year: 1,355,1959 ** TUMORIGENIC DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1020 mg/kg/61W-I
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
REFERENCE :
BJCAAI British Journal of Cancer. (Macmillan Press Ltd., Houndmills, Basingstoke, Hants. RG21 2XS, UK) V.1- 1947- Volume(issue)/page/year: 17,100,1963 *** REVIEWS *** TOXICOLOGY REVIEW 22HAAD "Microbial Toxins, 1970-72," Ajil, S.J., et al., eds., New York, Academic Press, Inc., 1970-72 Volume(issue)/page/year: 6,409,1971

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H302 + H312 + H332
Precautionary Statements P210-P280
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xn;F
Risk Phrases R11;R20/21/22
Safety Phrases 16-36/37/39-45
RIDADR UN 1993
RTECS TZ3150000
Packaging Group II
HS Code 2932999099

 Synthetic Route

 Customs

HS Code 2932999099
Summary 2932999099. other heterocyclic compounds with oxygen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Articles3

More Articles
Cyclic oligomers in the cationic polymerization of 3, 3-dimethyloxetane. Bucquoye M and Goethals EJ.

Makromol. Chem. 179(7) , 1681-88, (1978)

Copolymerization of oxetane with 3, 3-dimethyloxetane-I. Reactivity parameters and microstructure of the copolymers. Bucquoye M and Goethals EJ.

Eur. Polymer J. 14(5) , 323-28, (1978)

Mild one-step synthesis of dibromo compounds from cyclic ethers.

J. Org. Chem. 77(24) , 11227-31, (2012)

A novel one-step method for mildly converting cyclic ethers into dibromo compounds is reported. Alcohols, oximes, aldehydes, and ketones are known to react under Appel or Corey-Fuchs reaction conditio...

 Synonyms

3,3-dimethyloxetane
MFCD00005168
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