5-(4-Bromophenyl)-1,3-oxazole structure
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Common Name | 5-(4-Bromophenyl)-1,3-oxazole | ||
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CAS Number | 72571-06-3 | Molecular Weight | 224.05400 | |
Density | 1.524g/cm3 | Boiling Point | 315.8ºC at 760 mmHg | |
Molecular Formula | C9H6BrNO | Melting Point | 78-80ºC | |
MSDS | N/A | Flash Point | 144.8ºC |
Name | 5-(4-Bromophenyl)oxazole |
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Synonym | More Synonyms |
Density | 1.524g/cm3 |
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Boiling Point | 315.8ºC at 760 mmHg |
Melting Point | 78-80ºC |
Molecular Formula | C9H6BrNO |
Molecular Weight | 224.05400 |
Flash Point | 144.8ºC |
Exact Mass | 222.96300 |
PSA | 26.03000 |
LogP | 3.10410 |
Index of Refraction | 1.58 |
Synonym: Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
Risk Phrases: 36/37/38 Section 3 - HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin. Potential Health Effects Eye: Causes eye irritation. Skin: Causes skin irritation. May be harmful if absorbed through the skin. Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. Chronic: Not available. Section 4 - FIRST AID MEASURES Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Ingestion: Get medical aid. Wash mouth out with water. Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively. Section 5 - FIRE FIGHTING MEASURES General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. Section 6 - ACCIDENTAL RELEASE MEASURES General Information: Use proper personal protective equipment as indicated in Section 8. Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Section 7 - HANDLING and STORAGE Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Storage: Store in a cool, dry place. Store in a tightly closed container. Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 72571-06-3: Personal Protective Equipment Eyes: Not available. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure. Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES Physical State: Solid Color: yellow Odor: odorless - slight odor pH: Not available. Vapor Pressure: Not available. Viscosity: Not available. Boiling Point: Not available. Freezing/Melting Point: 78 - 80 deg C Autoignition Temperature: Not available. Flash Point: Not available. Explosion Limits, lower: Not available. Explosion Limits, upper: Not available. Decomposition Temperature: Solubility in water: Specific Gravity/Density: Molecular Formula: C9H6BrNO Molecular Weight: 224 Section 10 - STABILITY AND REACTIVITY Chemical Stability: Not available. Conditions to Avoid: Incompatible materials. Incompatibilities with Other Materials: Strong oxidizing agents. Hazardous Decomposition Products: Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide, bromine. Hazardous Polymerization: Has not been reported Section 11 - TOXICOLOGICAL INFORMATION RTECS#: CAS# 72571-06-3 unlisted. LD50/LC50: Not available. Carcinogenicity: 5-(4-Bromophenyl)-1,3-oxazole - Not listed by ACGIH, IARC, or NTP. Section 12 - ECOLOGICAL INFORMATION Section 13 - DISPOSAL CONSIDERATIONS Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - TRANSPORT INFORMATION IATA No information available. IMO No information available. RID/ADR No information available. Section 15 - REGULATORY INFORMATION European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols: XI Risk Phrases: R 36/37/38 Irritating to eyes, respiratory system and skin. Safety Phrases: S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 37/39 Wear suitable gloves and eye/face protection. WGK (Water Danger/Protection) CAS# 72571-06-3: No information available. Canada None of the chemicals in this product are listed on the DSL/NDSL list. CAS# 72571-06-3 is not listed on Canada's Ingredient Disclosure List. US FEDERAL TSCA CAS# 72571-06-3 is not listed on the TSCA inventory. It is for research and development use only. SECTION 16 - ADDITIONAL INFORMATION N/A |
Hazard Codes | Xi:Irritant; |
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Risk Phrases | 36/37/38 |
Safety Phrases | S26-S37/39 |
HS Code | 2934999090 |
~% 5-(4-Bromopheny... CAS#:72571-06-3 |
Literature: Tetrahedron Letters, , vol. 50, # 26 p. 3273 - 3276 |
~88% 5-(4-Bromopheny... CAS#:72571-06-3 |
Literature: Ding, Zhenhua; Yoshikai, Naohiko Organic Letters, 2010 , vol. 12, # 18 p. 4180 - 4183 |
~58% 5-(4-Bromopheny... CAS#:72571-06-3 |
Literature: Morton-Norwich Products, Inc. Patent: US4171307 A1, 1979 ; |
~19% 5-(4-Bromopheny... CAS#:72571-06-3 |
Literature: SIGNAL PHARMACEUTICALS, LLC Patent: WO2008/51493 A2, 2008 ; Location in patent: Page/Page column 179 ; |
~19% 5-(4-Bromopheny... CAS#:72571-06-3 |
Literature: Mortensen, Deborah S.; Perrin-Ninkovic, Sophie M.; Harris, Roy; Lee, Branden G.S.; Shevlin, Graziella; Hickman, Matt; Khambatta, Gody; Bisonette, Rene R.; Fultz, Kimberly E.; Sankar, Sabita Bioorganic and Medicinal Chemistry Letters, 2011 , vol. 21, # 22 p. 6793 - 6799 |
~48% 5-(4-Bromopheny... CAS#:72571-06-3 |
Literature: LaMattina, John L. Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2261 - 2262 |
Precursor 8 | |
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DownStream 3 | |
HS Code | 2934999090 |
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Summary | 2934999090. other heterocyclic compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0% |
5-(4-bromophenyl)-1,3-oxazole |