4-(Trimethysilyl)-ethynylbenzaldehyde

Modify Date: 2024-01-05 18:37:40

4-(Trimethysilyl)-ethynylbenzaldehyde Structure
4-(Trimethysilyl)-ethynylbenzaldehyde structure
Common Name 4-(Trimethysilyl)-ethynylbenzaldehyde
CAS Number 77123-57-0 Molecular Weight 202.32400
Density 0.98g/cm3 Boiling Point 262.1ºC at 760 mmHg
Molecular Formula C12H14OSi Melting Point 66-70ºC
MSDS Chinese USA Flash Point 112.3ºC

 Names

Name 4-[(Trimethylsilyl)ethynyl]benzaldehyde
Synonym More Synonyms

 Chemical & Physical Properties

Density 0.98g/cm3
Boiling Point 262.1ºC at 760 mmHg
Melting Point 66-70ºC
Molecular Formula C12H14OSi
Molecular Weight 202.32400
Flash Point 112.3ºC
Exact Mass 202.08100
PSA 17.07000
LogP 2.72800
Index of Refraction 1.514

 Safety Information

Personal Protective Equipment Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter
Hazard Codes T: Toxic;
RIDADR NONH for all modes of transport
HS Code 2931900090

 Synthetic Route

~98%

4-(Trimethysilyl)-ethynylbenzaldehyde Structure

4-(Trimethysily...

CAS#:77123-57-0

Literature: Sommer, William J.; Weck, Marcus Advanced Synthesis and Catalysis, 2006 , vol. 348, # 15 p. 2101 - 2113

~93%

4-(Trimethysilyl)-ethynylbenzaldehyde Structure

4-(Trimethysily...

CAS#:77123-57-0

Literature: Worm-Leonhard, Kasper; Meldal, Morten European Journal of Organic Chemistry, 2008 , # 31 p. 5244 - 5253

~93%

4-(Trimethysilyl)-ethynylbenzaldehyde Structure

4-(Trimethysily...

CAS#:77123-57-0

Literature: Vicente, Maria da Graca Henriques; Marzilli, Luigi G. Patent: US2004/116385 A1, 2004 ;

~10%

4-(Trimethysilyl)-ethynylbenzaldehyde Structure

4-(Trimethysily...

CAS#:77123-57-0

Literature: Thorand; Krause Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8551 - 8553

~%

4-(Trimethysilyl)-ethynylbenzaldehyde Structure

4-(Trimethysily...

CAS#:77123-57-0

Literature: Tetrahedron Letters, , vol. 48, # 33 p. 5817 - 5820

~%

4-(Trimethysilyl)-ethynylbenzaldehyde Structure

4-(Trimethysily...

CAS#:77123-57-0

Literature: Organic Letters, , vol. 15, # 4 p. 840 - 843

 Customs

HS Code 2931900090
Summary 2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

 Articles5

More Articles
Facile synthesis of ethynylated benzoic acid derivatives and aromatic compounds via ethynyltrimethylsilane. Austin WB, et al.

J. Org. Chem. 46(11) , 2280-2286, (1981)

Cascade Reactions of Me3Si-Substituted Imidazolidine-1, 3-Diols with PbO2, Including Oxidation of the Corresponding Diol and Subsequent Elimination of the Trimethylsilyl Fragment. Tretyakov E, et al.

European J. Org. Chem. 2007(22) , 3639-3647, (2007)

On the potential of porphyrin-spiked triarylamine stars for bulk heterojunction solar cells. Kengthanomma T, et al.

J. Mater. Chem. A 1(35) , 10524-10531, (2013)

 Synonyms

4-(2-trimethylsilylethynyl)benzaldehyde
MFCD02093765