Titanium(IV) iodide

Synonym:Titanium tetraiodide

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Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title Compound7720-83-4100%no datano data

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Section 3: Hazards Identification
Corrosive to skin, eyes, and mucous membranes. May cause coughing, wheezing, shortness of breath,
Emergency Overview:
headache, nausea and vomiting. Ingestion may cause damage to the mouth, throat and esophagus.
Primary Routes of Exposure:Ingestion, inhalation, skin, eyes.
Eye Contact:Corrosive to eyes.
Skin Contact:Corrosive to skin.
Inhalation:Inhalation may cause inflammation of the respiratory tract, edema and chemical pneumonitis.
Ingestion:Ingestion may cause damage to the mouth, throat and esophagus.
Corrosive to skin, eyes and mucous membranes. Inhalation causes coughing, wheezing, shortness of breath,
Acute Health Affects:
headache, nausea, and vomiting. Ingestion may cause damage to the mouth throat and esophagus.
Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running nose, headache and
Chronic Health Affects:
irritation of mucous membranes.
NTP:No
IARC:No
OSHA:No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point:not applicable
Autoignition Temperature:none
Explosion Limits:none
Extinguishing Medium:none required
If involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure self-contained
Special Fire Fighting Procedures:
breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit corrosive hydrogen iodide fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Small spills can be mixed with powdered sodium bicarbonate, lime, or calcium carbonate and swept up.
Spill and Leak Procedures:Spillage in areas not adequately ventilated may require an evacuation of area. Emergency response teams
will require self-contained breathing apparatus.

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SECTION 7: Handling and Storage
Store material in a tightly sealed bottle away from moisture. If possible, handle material in an efficient fume
Handling and Storage:
hood. Prolonged exposure to the atmosphere may lead to degradation of the product.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves. Consult with glove manufacturer to determine the proper type of glove.
Ventilation:If possible, handle the material in an efficient fume hood.
In the absence of adequate ventilation a respirator should be worn. The use of a respiratory requires a
Respirator:
Respirator Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:If possible, handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form:black xtl.
Molecular Weight:555.52
Melting Point:150°
Boiling Point:377.1°C
Vapor Pressure:no data
Specific Gravity:4.3
Odor:Pungent odor.
Solubility in Water:reacts with water

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SECTION 10: Stability and Reactivity
Stability:moisture sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:contact with moisture
Incompatibility:Oxidizing agents, water, alcohols, active metals and halogens
Decomposition Products:with moisture: hydrogen iodide

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SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files.
Carcinogenic Effects:no data
Mutagenic Effects:no data
Tetratogenic Effects:no data

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SECTION 12: Ecological Information
Ecological Information:No information available

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SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR):Corrosive Solid, Acidic, Inorganic, N.O.S.
Hazard Class (CFR):8
Additional Hazard Class (CFR):NA
Packaging Group (CFR):II
UN ID Number (CFR):UN# 3260
Shipping Name (IATA):Corrosive Solid, Acidic, Inorganic, N.O.S.
Hazard Class (IATA):8
Additional Hazard Class (IATA):NA
Packaging Group (IATA):II
UN ID Number (IATA):UN# 3260

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SECTION 15: Regulatory Information
TSCA:Listed in the TSCA inventory.
SARA (Title 313):Title compound not listed.
Second Ingredient:none

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SECTION 16 - ADDITIONAL INFORMATION
N/A