Chromium fluoride

Modify Date: 2024-01-09 11:21:30

Chromium fluoride Structure
Chromium fluoride structure
Common Name Chromium fluoride
CAS Number 7788-97-8 Molecular Weight 108.99100
Density 3.8 g/mL at 25ºC(lit.) Boiling Point 19.5ºC at 760 mmHg
Molecular Formula CrF3 Melting Point 1000ºC
MSDS USA Flash Point N/A
Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger

 Names

Name Chromium(Iii) Fluoride
Synonym More Synonyms

 Chemical & Physical Properties

Density 3.8 g/mL at 25ºC(lit.)
Boiling Point 19.5ºC at 760 mmHg
Melting Point 1000ºC
Molecular Formula CrF3
Molecular Weight 108.99100
Exact Mass 108.93600

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GB6125000
CHEMICAL NAME :
Chromium(III) fluoride
CAS REGISTRY NUMBER :
7788-97-8
LAST UPDATED :
199712
DATA ITEMS CITED :
37
MOLECULAR FORMULA :
Cr-F3
MOLECULAR WEIGHT :
109.00
WISWESSER LINE NOTATION :
CR F3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
150 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
YAKUD5 Gekkan Yakuji. Pharmaceuticals Monthly. (Yakugyo Jihosha, Inaoka Bldg., 2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo 101, Japan) V.1- 1959- Volume(issue)/page/year: 22,291,1980
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Amphibian - frog
DOSE/DURATION :
420 mg/kg
REFERENCE :
CRSBAW Comptes Rendus des Seances de la Societe de Biologie et de Ses Filiales. (SPPIF, B.P.22, F-41353 Vineuil, France) V.1- 1849- Volume(issue)/page/year: 124,133,1937 *** REVIEWS *** ACGIH TLV-TWA 0.5 mg(Cr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 TOXICOLOGY REVIEW AMSSAQ Acta Medica Scandinavica, Supplement. (Almqvist & Wiksell, POB 45150, S-10430 Stockholm, Sweden) No.1-730, 1921-88. Volume(issue)/page/year: 400,5,1963 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 1 mg(Cr)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,35,1971 OSHA PEL (Gen Indu):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(Cr)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2.5 mg(F)/m3 JAN 1993 OEL-BELGIUM:TWA 2.5 mg(F)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FRANCE:TWA 2.5 mg(F)/m3 JAN 1993 OEL-GERMANY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3 JAN 1993 OEL-POLAND:TWA 1 mg(F)/m3 JAN 1993 OEL-RUSSIA:STEL 0.5 ppm (2.5 mg/m3) JAN 1993 OEL-SWEDEN:TWA 2 mg(F)/m3 JAN 1993 OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm JAN 1993 OEL-THAILAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-TURKEY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1040 No. of Facilities: 64 (estimated) No. of Industries: 2 No. of Occupations: 4 No. of Employees: 1176 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1040 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 42 (estimated)

 Safety Information

Symbol GHS05 GHS07
GHS05, GHS07
Signal Word Danger
Hazard Statements H302 + H312 + H332-H314
Supplemental HS Contact with water liberates toxic gas.
Precautionary Statements P260-P280-P301 + P312 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338 + P310
Personal Protective Equipment Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
Hazard Codes C
Risk Phrases R20/21/22
Safety Phrases 26-27-28-36/37/39-45
RIDADR UN 1756 8
WGK Germany 3
RTECS GB6125000
Packaging Group II
Hazard Class 8

 Synthetic Route

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, , vol. 116, p. 253 - 256 Cr: MVol.B, 108, page 222 - 225

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Cr: MVol.B, 107, page 220 - 222

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Z. Anorg. Chem., , vol. 247, p. 135 - 146 Cr: MVol.B, 91, page 185 - 187

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Z. Anorg. Chem., , vol. 247, p. 135 - 146 Cr: MVol.B, 87, page 177 - 179

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Z. Anorg. Chem., , vol. 247, p. 135 - 146 Cr: MVol.B, 91, page 185 - 187

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Materials Research Bulletin, , vol. 23, p. 1611 - 1620

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Journal fuer Praktische Chemie (Leipzig), , vol. 73, p. 393 - 419

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Literature: Ann. Chim. Phys., , vol. 2, # 7 p. 5 - 5

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Chromium fluoride Structure

Chromium fluoride

CAS#:7788-97-8

Detail
Literature: Inorganic Chemistry, , vol. 24, p. 2286 - 2292

 Articles1

More Articles

Catal. Letters 41 , 221, (1996)

 Synonyms

MFCD00016045
chromium(3+),trifluoride
EINECS 232-137-9
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