(1R,2R)-1-(DIPHENYLPHOSPHINO)-1-PHENYLPROPAN-2-AMINE

Modify Date: 2024-01-04 04:51:04

(1R,2R)-1-(DIPHENYLPHOSPHINO)-1-PHENYLPROPAN-2-AMINE Structure
(1R,2R)-1-(DIPHENYLPHOSPHINO)-1-PHENYLPROPAN-2-AMINE structure
Common Name (1R,2R)-1-(DIPHENYLPHOSPHINO)-1-PHENYLPROPAN-2-AMINE
CAS Number 799297-44-2 Molecular Weight 319.38000
Density N/A Boiling Point N/A
Molecular Formula C21H22NP Melting Point N/A
MSDS Chinese USA Flash Point N/A
Symbol GHS05
GHS05
Signal Word Danger

 Names

Name (1R,2R)-1-diphenylphosphanyl-1-phenylpropan-2-amine
Synonym More Synonyms

 Chemical & Physical Properties

Molecular Formula C21H22NP
Molecular Weight 319.38000
Exact Mass 319.14900
PSA 39.61000
LogP 4.90810

 MSDS


Section 1: Product Identification
Chemical Name:(1R,2R)-2-Amino-1-phenylpropyldiphenylphosphine, min. 97%
CAS Registry Number:799297-44-2
Formula:C21H22NP
EINECS Number:none
Chemical Family:organophosphine ligand
Synonym:(1R,2R)-2-Amino-1-phenylpropyldiphenylphosphane

Section 2: Composition and Information on Ingredients
IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
Title compound799297-44-2100%no datano data

Section 3: Hazards Identification
Emergency Overview:Irritating to skin, eyes and respiratory tract. May be harmful if swallowed.
Primary Routes of Exposure:Ingestion, inhalation
Eye Contact:Causes slight to mild irritation of the eyes.
Skin Contact:Causes moderate irritation of the skin.
Inhalation:Dust is Irritating to the nose, mucous membranes and respiratory tract.
Ingestion:No information available on the physiological effects of ingestion. May be harmful if swallowed.
Acute Health Affects:Irritating to skin, eyes and respiratory tract.
Chronic Health Affects:No information on long-term chronic effects.
NTP:No
IARC:No
OSHA:No

SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

SECTION 5: Fire Fighting Measures
Flash Point:no data
Autoignition Temperature:no data
Explosion Limits:no data
Extinguishing Medium:carbon dioxide, dry powder or foam
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion andIf involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

SECTION 6: Accidental Release Measures
Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up.

SECTION 7: Handling and Storage
Store in a tightly sealed container under an inert atmosphere of nitrogen or argon. Keep in a cool, dry, well
Handling and Storage:
ventilated place.

SECTION 8: Exposure Controls and Personal Protection
Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection:Wear protective clothing and gloves.
Ventilation:Handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation:Handle the material in an efficient fume hood.
Additional Protection:No additional protection required.

SECTION 9: Physical and Chemical Properties
Color and Form:white solid
Molecular Weight:319.38
Melting Point:no data
Boiling Point:no data
Vapor Pressure:no data
Specific Gravity:no data
Odor:none
Solubility in Water:Insoluble

SECTION 10: Stability and Reactivity
Stability:air sensitive
Hazardous Polymerization:no hazardous polymerization
Conditions to Avoid:prolonged exposure to air
Incompatibility:strong oxidizing agents
Decomposition Products:carbon monoxide, carbon dioxide, nitrogen oxides, phosphorous oxides and organic fumes

SECTION 11: Toxicological Information
RTECS Data:No information available in the RTECS files
Carcinogenic Effects:No data
Mutagenic Effects:No data
Tetratogenic Effects:No data

SECTION 12: Ecological Information
Ecological Information:No information available

SECTION 13: Disposal Considerations
Disposal:Dispose of according to local, state and federal regulations.

SECTION 14: Transportation
Shipping Name (CFR):Non-hazardous
Hazard Class (CFR):NA
Additional Hazard Class (CFR):NA
Packaging Group (CFR):NA
UN ID Number (CFR):NA
Shipping Name (IATA):Non-hazardous
Hazard Class (IATA):NA
Additional Hazard Class (IATA):NA
Packaging Group (IATA):NA
UN ID Number (IATA):NA

SECTION 15: Regulatory Information
TSCA:Not listed in the TSCA inventory
SARA (Title 313):Title compound not listed
Second Ingredient:none


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Symbol GHS05
GHS05
Signal Word Danger
Hazard Statements H314
Precautionary Statements P280-P305 + P351 + P338-P310
Hazard Codes C
RIDADR UN 3263 8 / PGIII

 Articles6

More Articles
Chemoselective hydrogenation of imides catalyzed by Cp*Ru(PN) complexes and its application to the asymmetric synthesis of paroxetine.

J. Am. Chem. Soc. 129 , 290, (2007)

Hydrogenation of N-acylcarbamates and N-acylsulfonamides catalyzed by a bifunctional [Cp*Ru(PN)] complex.

Angew. Chem. Int. Ed. Engl. 48 , 1324, (2009)

Awakening of the Cp one: The bifunctional complex 1 facilitates the interaction with substrates bearing less electrophilic carbon atoms than ketones, epoxides, and imides. The title reaction was appli...

D. Amoroso, T.W. Graham et al.

Aldrichimica Acta 41 , 1, 15, (2008)

 Synonyms

MFCD17018768
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