Benzyl 2,2,2-trichloroacetimidate

Modify Date: 2024-01-10 06:14:19

Benzyl 2,2,2-trichloroacetimidate Structure
Benzyl 2,2,2-trichloroacetimidate structure
Common Name Benzyl 2,2,2-trichloroacetimidate
CAS Number 81927-55-1 Molecular Weight 252.525
Density 1.4±0.1 g/cm3 Boiling Point 319.5±0.0 °C at 760 mmHg
Molecular Formula C9H8Cl3NO Melting Point N/A
MSDS Chinese USA Flash Point 107.0±30.1 °C
Symbol GHS07
GHS07
Signal Word Warning

 Names

Name Benzyl 2,2,2-Trichloroacetimidate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.4±0.1 g/cm3
Boiling Point 319.5±0.0 °C at 760 mmHg
Molecular Formula C9H8Cl3NO
Molecular Weight 252.525
Flash Point 107.0±30.1 °C
Exact Mass 250.967148
PSA 33.08000
LogP 3.51
Vapour Pressure 0.0±0.6 mmHg at 25°C
Index of Refraction 1.550
Storage condition 2-8°C

 Safety Information

Symbol GHS07
GHS07
Signal Word Warning
Hazard Statements H302-H315-H319-H335
Precautionary Statements P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes Xi:Irritant;
Risk Phrases R36/37/38
Safety Phrases S26
RIDADR NONH for all modes of transport
WGK Germany 3
HS Code 2925290090

 Synthetic Route

~95%

Benzyl 2,2,2-trichloroacetimidate Structure

Benzyl 2,2,2-tr...

CAS#:81927-55-1

Literature: Patil, Vijay J. Tetrahedron Letters, 1996 , vol. 37, # 9 p. 1481 - 1484

 Customs

HS Code 2925290090
Summary 2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

 Articles3

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Tetrahedron Asymmetry 3 , 1547, (1992)

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Tetrahedron Lett. 41(49) , 9397-9401, (2000)

The total synthesis of scytophycin C. Part 1: stereocontrolled synthesis of the C1? C32 protected seco acid. Paterson I, et al.

Tetrahedron 54(39) , 11935-11954, (1998)

 Synonyms

Benzyl 2,2,2-trichloroethanimidate
Ethanimidic acid, 2,2,2-trichloro-, phenylmethyl ester
MFCD00000805
Benzyl 2,2,2-trichloroethanimidoate
BENZYL TRICHLOROACETIMIDATE
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