(5-NITRO-2-FURYL)METHYL AMINOMETHANIMIDOTHIOATE HYDROBROMIDE

Modify Date: 2024-01-14 12:39:41

(5-NITRO-2-FURYL)METHYL AMINOMETHANIMIDOTHIOATE HYDROBROMIDE Structure
(5-NITRO-2-FURYL)METHYL AMINOMETHANIMIDOTHIOATE HYDROBROMIDE structure
Common Name (5-NITRO-2-FURYL)METHYL AMINOMETHANIMIDOTHIOATE HYDROBROMIDE
CAS Number 82118-18-1 Molecular Weight 282.11500
Density N/A Boiling Point 366.2ºC at 760 mmHg
Molecular Formula C6H8BrN3O3S Melting Point 183ºC
MSDS N/A Flash Point 175.3ºC

 Names

Name (5-nitrofuran-2-yl)methyl carbamimidothioate,hydrobromide
Synonym More Synonyms

 Chemical & Physical Properties

Boiling Point 366.2ºC at 760 mmHg
Melting Point 183ºC
Molecular Formula C6H8BrN3O3S
Molecular Weight 282.11500
Flash Point 175.3ºC
Exact Mass 280.94700
PSA 134.13000
LogP 3.59580

 MSDS

Name: (5-Nitro-2-furyl)methyl aminomethanimidothioate hydrobromide 97% Material Safety Data Sheet
Synonym: 2-Amidinothiomethyl-5-nitrofuran hydrobromid
CAS: 82118-18-1
Section 1 - Chemical Product MSDS Name:(5-Nitro-2-furyl)methyl aminomethanimidothioate hydrobromide 97% Material Safety Data Sheet
Synonym:2-Amidinothiomethyl-5-nitrofuran hydrobromid

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
82118-18-1 (5-Nitro-2-furyl)methyl aminomethanimi 97% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 82118-18-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: tan
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 183 - 185 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H8BrN3O3S
Molecular Weight: 282

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen bromide, bromine.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 82118-18-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
(5-Nitro-2-furyl)methyl aminomethanimidothioate hydrobromide - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 82118-18-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 82118-18-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 82118-18-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xn:Harmful;
Risk Phrases R20/21/22;R36/37/38
Safety Phrases S26-S36/37/39
HS Code 2932190090

 Synthetic Route

~94%

(5-NITRO-2-FURYL)METHYL AMINOMETHANIMIDOTHIOATE HYDROBROMIDE Structure

(5-NITRO-2-FURY...

CAS#:82118-18-1

Literature: Usova, E. B.; Krapivin, G. D.; Kul'nevich, V. G. Chemistry of Heterocyclic Compounds (New York, NY, United States), 1990 , vol. 26, # 4 p. 477 - 482 Khimiya Geterotsiklicheskikh Soedinenii, 1990 , # 4 p. 557 - 562

~91%

(5-NITRO-2-FURYL)METHYL AMINOMETHANIMIDOTHIOATE HYDROBROMIDE Structure

(5-NITRO-2-FURY...

CAS#:82118-18-1

Literature: Kazimierczuk, Zygmunt; Chalimoniuk, Malgorzata; Laudy, Agnieszka Ewa; Moo-Puc, Rosa; Cedillo-Rivera, Roberto; Starosciak, Bohdan Jerzy; Chrapusta, Stanislaw J. Archives of Pharmacal Research, 2010 , vol. 33, # 6 p. 821 - 830

~%

(5-NITRO-2-FURYL)METHYL AMINOMETHANIMIDOTHIOATE HYDROBROMIDE Structure

(5-NITRO-2-FURY...

CAS#:82118-18-1

Literature: Krapivin, G. D.; Usova, E. B.; Kul'nevich, V. G. Chemistry of Heterocyclic Compounds (New York, NY, United States), 1985 , vol. 21, # 2 p. 230 Khimiya Geterotsiklicheskikh Soedinenii, 1985 , vol. 21, # 2 p. 272

 Customs

HS Code 2932190090
Summary 2932190090 other compounds containing an unfused furan ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

 Synonyms

(5-Nitrofuran-2-yl)methyl carbamimidothioate hydrobromide
S-2-(5-nitrofuran-2-ylmethyl)isothiourea hydrobromide