4-(Dimethylamino)pyridine, polymer-bound
Modify Date: 2024-01-09 00:39:21
4-(Dimethylamino)pyridine, polymer-bound structure
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Common Name | 4-(Dimethylamino)pyridine, polymer-bound | ||
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| CAS Number | 82942-26-5 | Molecular Weight | 198.26400 | |
| Density | 1.093g/cm3 | Boiling Point | 337.6ºC at 760 mmHg | |
| Molecular Formula | C13H14N2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | 4ºC | |
| Symbol |
GHS07 |
Signal Word | Warning | |
Use of 4-(Dimethylamino)pyridine, polymer-boundPolymer-bound 4-(dimethylamino)pyridine is used as a supported base in the Michael addition and nitrous acid elimination process step involved in the synthesis of thiophene-2-carboxylates using β-nitroacrylates as starting materials, under a general and efficient continuous flow-based protocol. It also serves as a supported catalyst in the preparation of ω-nitro esters starting from cyclic 2-nitro ketones under solid heterogeneous catalysis. |
| Name | N-Benzyl-N-methyl-4-pyridinamine |
|---|---|
| Synonym | More Synonyms |
| Density | 1.093g/cm3 |
|---|---|
| Boiling Point | 337.6ºC at 760 mmHg |
| Molecular Formula | C13H14N2 |
| Molecular Weight | 198.26400 |
| Flash Point | 4ºC |
| Exact Mass | 198.11600 |
| PSA | 16.13000 |
| LogP | 2.71800 |
| Index of Refraction | 1.613 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi: Irritant;T: Toxic; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | 26-37/39-45-36/37/39-28-16 |
| RIDADR | UN 3175 4.1/PG 2 |
| WGK Germany | 3 |
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S. Shinkai et al.
Bull. Chem. Soc. Jpn. 54 , 631, (1981)
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M. Tomoi et al.
Macromol. Chem. Rapid Commun. 3 , 537, (1982)
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E.F. Scriven
Chem. Soc. Rev. 12 , 129, (1983)
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| MFCD04041220 |