N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine

Modify Date: 2024-01-10 14:24:09

N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine Structure
N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine structure
Common Name N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine
CAS Number 848618-13-3 Molecular Weight 371.44000
Density 0.95g/cm3 Boiling Point 452.1ºC at 760 mmHg
Molecular Formula C22H38BNOSi Melting Point 130-134ºC
MSDS N/A Flash Point 227.2ºC

 Names

Name (1S,2S)-N-methyl-1-phenyl-1-[[(10R)-10-trimethylsilyl-9-borabicyclo[3.3.2]decan-9-yl]oxy]propan-2-amine

 Chemical & Physical Properties

Density 0.95g/cm3
Boiling Point 452.1ºC at 760 mmHg
Melting Point 130-134ºC
Molecular Formula C22H38BNOSi
Molecular Weight 371.44000
Flash Point 227.2ºC
Exact Mass 371.28200
PSA 21.26000
LogP 6.33640
Index of Refraction 1.5

 Safety Information

Hazard Codes Xi: Irritant;
Risk Phrases 36/37/38
Safety Phrases 26

 Synthetic Route

~69%

N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine Structure

N,α-Dimethyl-β-...

CAS#:848618-13-3

Literature: Hernandez, Eliud; Soderquist, John A. Organic Letters, 2005 , vol. 7, # 24 p. 5397 - 5400

~38%

N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine Structure

N,α-Dimethyl-β-...

CAS#:848618-13-3

Literature: Munoz-Hernandez, Lorell; Soderquist, John A. Organic Letters, 2009 , vol. 11, # 12 p. 2571 - 2574

~%

N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine Structure

N,α-Dimethyl-β-...

CAS#:848618-13-3

Literature: Hernandez, Eliud; Soderquist, John A. Organic Letters, 2005 , vol. 7, # 24 p. 5397 - 5400

~%

N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine Structure

N,α-Dimethyl-β-...

CAS#:848618-13-3

Literature: Burgos, Carlos H.; Canales, Eda; Matos, Karl; Soderquist, John A. Journal of the American Chemical Society, 2005 , vol. 127, # 22 p. 8044 - 8049

~%

N,α-Dimethyl-β-[[(10R)-10-(trimethylsilyl)-9-borabicyclo[3.3.2]dec-9-yl]oxy]-(αS,βS)-benzeneethanamine Structure

N,α-Dimethyl-β-...

CAS#:848618-13-3

Literature: Hernandez, Eliud; Soderquist, John A. Organic Letters, 2005 , vol. 7, # 24 p. 5397 - 5400