Togni's Reagent
Togni's Reagent structure
|
Common Name | Togni's Reagent | ||
|---|---|---|---|---|
| CAS Number | 887144-97-0 | Molecular Weight | 330.086 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C10H10F3IO | Melting Point | 75-79ºC | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS02, GHS07 |
Signal Word | Warning | |
| Name | 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole |
|---|---|
| Synonym | More Synonyms |
| Melting Point | 75-79ºC |
|---|---|
| Molecular Formula | C10H10F3IO |
| Molecular Weight | 330.086 |
| Exact Mass | 329.972839 |
| PSA | 9.23000 |
| LogP | 4.06270 |
| Symbol |
GHS02, GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H228-H315-H319-H335 |
| Precautionary Statements | P210-P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi: Irritant; |
| Risk Phrases | R36/37/38 |
| Safety Phrases | 26-36/37 |
| RIDADR | UN1325 - class 4.1 - PG 3 - Flammable solids, organic, n.o.s., HI: all |
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~92%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Kieltsch, Iris; Eisenberger, Patrick; Stanek, Kyrill; Togni, Antonio Chimia, 2008 , vol. 62, # 4 p. 260 - 263 |
|
~77%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Powers, David C.; Lee, Eunsung; Ariafard, Alireza; Sanford, Melanie S.; Yates, Brian F.; Canty, Allan J.; Ritter, Tobias Journal of the American Chemical Society, 2012 , vol. 134, # 29 p. 12002 - 12009 |
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~%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Matousek, Vaclav; Pietrasiak, Ewa; Schwenk, Rino; Togni, Antonio Journal of Organic Chemistry, 2013 , vol. 78, # 13 p. 6763 - 6768 |
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~%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Journal of the American Chemical Society, , vol. 134, # 29 p. 12002 - 12009 |
|
~%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Chemistry - A European Journal, , vol. 12, # 9 p. 2579 - 2586 |
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~%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Chemistry - A European Journal, , vol. 12, # 9 p. 2579 - 2586 |
|
~%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Journal of the American Chemical Society, , vol. 134, # 29 p. 12002 - 12009 |
|
~%
Togni's Reagent CAS#:887144-97-0 |
| Literature: Journal of Organic Chemistry, , vol. 78, # 13 p. 6763 - 6768 |
![3,3-dimethyl-1λ3-benzo[d][1,2]iodoxol-1(3H)-yl acetate structure](https://image.chemsrc.com/caspic/193/175786-58-0.png)
| Precursor 6 | |
|---|---|
| DownStream 10 | |
![2-[(Trifluoromethyl)sulfanyl]aniline structure](https://image.chemsrc.com/caspic/081/347-55-7.png)
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A Ritter-type reaction: direct electrophilic trifluoromethylation at nitrogen atoms using hypervalent iodine reagents.
Angew. Chem. Int. Ed. Engl. 5th ed., 50 , 1059-1063, (2011)
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The productive merger of iodonium salts and organocatalysis: a non-photolytic approach to the enantioselective alpha-trifluoromethylation of aldehydes.
J. Am. Chem. Soc. 132 , 4986-4987, (2010) An enantioselective organocatalytic alpha-trifluoromethylation of aldehydes has been accomplished using a commercially available, electrophilic trifluoromethyl source. The merging of Lewis acid and or... |
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Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter.
J. Am. Chem. Soc. 11th ed., 132 , 3648-3649, (2010) A Pd(II)-catalyzed C-H activation/trifluoromethylation of arenes with an electrophilic trifluoromethylation reagent using diverse heterocycle directing groups is reported. The presence of trifluoroace... |
| MFCD10567056 |
| Togni's Reagent |
| 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole |
| 3,3-Dmethyl-1-(trifluoromethyl)-1,2-benziodoxole |
| 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole |
| Togni's Reagent: dimethyl compound |
| 3,3-Dimethyl-1-(trifluoromethyl)-1,3-dihydro-1λ,2-benziodoxole |
| UNII:3OK0E02MT6 |
| 3,3-dimethyl-1-(trifluoromethyl)-1λ<sup>3</sup>,2-benziodoxole |
- Shanghai Nianxing Industrial Co., Ltd
- China
- Product Name: Togni's Reagent
- Price: Click To Check
- Purity: 98.0%
- Delivery: 10 Day
- Contact: Yang
- Email: sales@echemcloud.com
- Shanghai Jizhi Biochemical Technology Co., Ltd
- China
- Product Name: Togni's Reagent
- Price: ￥418.0/500mg ￥128.0/100mg
- Purity: 97.0%
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- Email: 2130147988@qq.com
- Dayang Chem (Hangzhou) Co., Ltd.
- China
- Product Name: 3,3-Dimethyl-1-(trifluoromethyl)-1,2-benziodoxole
- Price: $Inquiry/100g $Inquiry/1kg $Inquiry/100kg $Inquiry/1000kg
- Purity: 98.0%
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- Henan Tianfu Chemical Co., Ltd.
- China
- Product Name: 1,3-Dihydro-3,3-dimethyl-1-(trifluoromethyl)-1,2-benziodoxole, Tognis Reagent
- Price: $Inquiry/1kg $Inquiry/25kg $Inquiry/1000kg $Inquiry/10ton
- Purity: 99.0%
- Delivery: Inquiry
- Contact: Anson
- Email: info@tianfuchem.com
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