3-CHLORO-5-(TRIFLUOROMETHYL)PYRID-2-YLHYDRAZINE

Modify Date: 2024-01-13 17:36:02

3-CHLORO-5-(TRIFLUOROMETHYL)PYRID-2-YLHYDRAZINE Structure
3-CHLORO-5-(TRIFLUOROMETHYL)PYRID-2-YLHYDRAZINE structure
Common Name 3-CHLORO-5-(TRIFLUOROMETHYL)PYRID-2-YLHYDRAZINE
CAS Number 89570-82-1 Molecular Weight 211.572
Density 1.6±0.1 g/cm3 Boiling Point 238.7±40.0 °C at 760 mmHg
Molecular Formula C6H5ClF3N3 Melting Point 90 °C
MSDS N/A Flash Point 98.1±27.3 °C

 Names

Name [3-chloro-5-(trifluoromethyl)pyridin-2-yl]hydrazine
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.6±0.1 g/cm3
Boiling Point 238.7±40.0 °C at 760 mmHg
Melting Point 90 °C
Molecular Formula C6H5ClF3N3
Molecular Weight 211.572
Flash Point 98.1±27.3 °C
Exact Mass 211.012405
PSA 50.94000
LogP 2.26
Vapour Pressure 0.0±0.5 mmHg at 25°C
Index of Refraction 1.547

 MSDS

Name: 1-[3-Chloro-5-(trifluoromethyl)-2-pyridyl] hydrazine 95+% Material Safety Data Sheet
Synonym:
CAS: 89570-82-1
Section 1 - Chemical Product MSDS Name:1-[3-Chloro-5-(trifluoromethyl)-2-pyridyl] hydrazine 95+% Material Safety Data Sheet
Synonym:

Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS
CAS# Chemical Name content EINECS#
89570-82-1 1-[3-Chloro-5-(trifluoromethyl)-2-pyri 95+% unlisted
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38

Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
Not available.

Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:

Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 89570-82-1: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: off-white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 90 - 92 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C6H5ClF3N3
Molecular Weight: 212

Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, acids, acid chlorides.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide, fluorine, hydrogen fluoride gas.
Hazardous Polymerization: Has not been reported

Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 89570-82-1 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
1-[3-Chloro-5-(trifluoromethyl)-2-pyridyl] hydrazine - Not listed by ACGIH, IARC, or NTP.

Section 12 - ECOLOGICAL INFORMATION


Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

Section 14 - TRANSPORT INFORMATION

IATA
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
IMO
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing Group: III
RID/ADR
Shipping Name: TOXIC SOLID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2811
Packing group: III

Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 89570-82-1: No information available.
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 89570-82-1 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 89570-82-1 is not listed on the TSCA inventory.
It is for research and development use only.


SECTION 16 - ADDITIONAL INFORMATION
N/A

 Safety Information

Hazard Codes Xi: Irritant;Xn: Harmful;
Risk Phrases R20/21/22
Safety Phrases S20/21-S36/37/39
HS Code 2933990090

 Synthetic Route

~88%

3-CHLORO-5-(TRIFLUOROMETHYL)PYRID-2-YLHYDRAZINE Structure

3-CHLORO-5-(TRI...

CAS#:89570-82-1

Literature: Haga, Takahiro; Fujikawa, Kan-ichi; Koyanagi, Tohru; Nakajima, Toshio; Hayashi, Kouji Heterocycles, 1984 , vol. 22, # 1 p. 117 - 124

~%

3-CHLORO-5-(TRIFLUOROMETHYL)PYRID-2-YLHYDRAZINE Structure

3-CHLORO-5-(TRI...

CAS#:89570-82-1

Literature: Heterocycles, , vol. 22, # 1 p. 117 - 124

 Customs

HS Code 2933990090
Summary 2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

 Synonyms

(3-chloro-5-trifluoromethyl-pyrid-2-yl)-hydrazine
3-CHLORO-5-(TRIFLUOROMETHYL)PYRID-2-YLHYDRAZINE
(3-Chloro-5-trifluoromethyl-pyridin-2-yl)-hydrazine
Pyridine,3-chloro-2-hydrazinyl-5-(trifluoromethyl)
(3-chloro-5-trifluoromethylpyridin-2-yl)hydrazine
Pyridine, 3-chloro-2-hydrazinyl-5-(trifluoromethyl)-
3-chloro-2-hydrazinyl-5-(trifluoromethyl)pyridine
3-chloro-5-trifluoromethyl-2-hydrazinopyridine
3-Chloro-2-hydrazino-5-(trifluoromethyl)pyridine
3-chloro-5-(trifluoromethyl)-2-pyridylhydrazine
MFCD00067865
1-[3-chloro-5-(trifluoromethyl)-2-pyridyl]hydrazine
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