methylpropiolate

Modify Date: 2024-01-02 13:41:57

methylpropiolate Structure
methylpropiolate structure
Common Name methylpropiolate
CAS Number 922-67-8 Molecular Weight 84.073
Density 1.0±0.1 g/cm3 Boiling Point 104.0±9.0 °C at 760 mmHg
Molecular Formula C4H4O2 Melting Point N/A
MSDS Chinese USA Flash Point 10.0±0.0 °C
Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger

 Names

Name Methyl propiolate
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.0±0.1 g/cm3
Boiling Point 104.0±9.0 °C at 760 mmHg
Molecular Formula C4H4O2
Molecular Weight 84.073
Flash Point 10.0±0.0 °C
Exact Mass 84.021126
PSA 26.30000
LogP 0.89
Vapour Pressure 31.4±0.2 mmHg at 25°C
Index of Refraction 1.408
Storage condition Refrigerator (+4°C) + Flammables area
Stability Stable. Highly flammable. Incompatible with strong oxidizing agents, bases, acids.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UE0050000
CHEMICAL NAME :
Propiolic acid, methyl ester
CAS REGISTRY NUMBER :
922-67-8
BEILSTEIN REFERENCE NO. :
0605462
LAST UPDATED :
199612
DATA ITEMS CITED :
1
MOLECULAR FORMULA :
C4-H4-O2
MOLECULAR WEIGHT :
84.08
WISWESSER LINE NOTATION :
1UU1VO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
18 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#08364

 Safety Information

Symbol GHS02 GHS07
GHS02, GHS07
Signal Word Danger
Hazard Statements H225-H315-H319-H335
Precautionary Statements P210-P261-P305 + P351 + P338
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
Hazard Codes F:Flammable;Xi:Irritant;
Risk Phrases R11;R36/37/38
Safety Phrases S26-S36-S36/37/39-S23-S16
RIDADR UN 3272 3/PG 2
WGK Germany 3
RTECS UE0050000
Packaging Group II
Hazard Class 3
HS Code 29161980

 Synthetic Route

 Customs

HS Code 2916190090
Summary 2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

 Articles5

More Articles
Predator lipids induce paralytic shellfish toxins in bloom-forming algae.

Proc. Natl. Acad. Sci. U. S. A. 112 , 6395-400, (2015)

Interactions among microscopic planktonic organisms underpin the functioning of open ocean ecosystems. With few exceptions, these organisms lack advanced eyes and thus rely largely on chemical sensing...

Determination of glutathione in baker's yeast by capillary electrophoresis using methyl propiolate as derivatizing reagent.

J. Chromatogr. A. 1300 , 204-8, (2013)

In this study we demonstrate - for the first time - the suitability of methyl propiolate - an alkylester of propiolic acid - as a thiol derivatizing reagent for capillary electrophoresis. Glutathione ...

Synthesis of tetrahydropyrimidin-2-ones via FeCl3 catalyzed one-pot domino reaction of amines, methyl propiolate, aromatic aldehydes, and urea.

Mol. Divers. 18(1) , 79-89, (2014)

Polysubstituted 3-arylaminoacrylate and tetrahydropyrimidin-2-one derivatives could be selectively produced from the one-pot domino reaction of arylamines, methyl propiolate, aromatic aldehydes, and u...

 Synonyms

Methyl propiolate
Propynoic acid, methyl ester
EINECS 213-083-5
methyl prop-2-ynoate
methylpropiolate
Propynoic acid methyl ester
2-Propynoic acid, methyl ester (9CI)
Methyl acetylenecarboxylate
Methyl propynoate
MFCD00008572
2-Propynoic acid, methyl ester
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