fenoprop

Modify Date: 2024-01-11 19:03:21

fenoprop Structure
fenoprop structure
Common Name fenoprop
CAS Number 93-72-1 Molecular Weight 269.50900
Density 1.2085(20ºC ) Boiling Point 378.4ºC at 760 mmHg
Molecular Formula C9H7Cl3O3 Melting Point 175-180 °C
MSDS Chinese USA Flash Point 11 °C
Symbol GHS02 GHS06 GHS08 GHS09
GHS02, GHS06, GHS08, GHS09
Signal Word Danger

 Names

Name fenoprop
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.2085(20ºC )
Boiling Point 378.4ºC at 760 mmHg
Melting Point 175-180 °C
Molecular Formula C9H7Cl3O3
Molecular Weight 269.50900
Flash Point 11 °C
Exact Mass 267.94600
PSA 46.53000
LogP 3.49870
Stability Stablr. Incompatible with strong bases, strong oxidizing agents.

 Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
UF8225000
CHEMICAL NAME :
Propionic acid, 2-(2,4,5-trichlorophenoxy)-
CAS REGISTRY NUMBER :
93-72-1
BEILSTEIN REFERENCE NO. :
1985768
LAST UPDATED :
199710
DATA ITEMS CITED :
13
MOLECULAR FORMULA :
C9-H7-Cl3-O3
MOLECULAR WEIGHT :
269.51
WISWESSER LINE NOTATION :
QVY1&OR BG DG EG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
650 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RREVAH Residue Reviews. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 07094) V.1- 1962- Volume(issue)/page/year: 10,97,1965
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
276 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
RPZHAW Roczniki Panstwowego Zakladu Higieny. (Ars Polona, POB 1001, 00-068 Warsaw 1, Poland) V.1- 1950- Volume(issue)/page/year: 31,373,1980
TYPE OF TEST :
LD - Lethal dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
>250 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
ANTCAO Antibiotics and Chemotherapy (Washington, DC). (Washington, DC) V.1-12, 1951-62. For publisher information, see CLMEA3. Volume(issue)/page/year: 9,715,1959
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 8,376,1987
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
650 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
SCIEAS Science. (American Assoc. for the Advancement of Science, 1333 H St., NW, Washington, DC 20005) V.1- 1895- Volume(issue)/page/year: 165,465,1969
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Mammal - species unspecified
DOSE/DURATION :
650 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
30ZDA9 "Chemistry of Pesticides," Melnikov, N.N., New York, Springer-Verlag New York, Inc., 1971 Volume(issue)/page/year: -,173,1971 ** REPRODUCTIVE DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
1617 mg/kg
SEX/DURATION :
female 12-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 6,33,1977
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Subcutaneous
DOSE :
1617 mg/kg
SEX/DURATION :
female 12-15 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Effects on Embryo or Fetus - fetal death Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
REFERENCE :
AECTCV Archives of Environmental Contamination and Toxicology. (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ 070944) V.1- 1973- Volume(issue)/page/year: 6,33,1977 *** REVIEWS *** IARC Cancer Review:Human Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 41,357,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84581 No. of Facilities: 32 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 65 (estimated)

 Safety Information

Symbol GHS02 GHS06 GHS08 GHS09
GHS02, GHS06, GHS08, GHS09
Signal Word Danger
Hazard Statements H225-H301 + H311 + H331-H370-H411
Precautionary Statements P210-P260-P273-P280-P301 + P310-P311
Personal Protective Equipment Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)
Hazard Codes Xn:Harmful;N:Dangerousfortheenvironment;
Risk Phrases R22;R38;R50/53
Safety Phrases S37-S60-S61-S45-S36/37-S16-S7
RIDADR UN 3077 9/PG 3
WGK Germany 3
RTECS UF8225000
Packaging Group III
Hazard Class 9
HS Code 2918990090

 Synthetic Route

~%

fenoprop Structure

fenoprop

CAS#:93-72-1

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 74, p. 155,159

~%

fenoprop Structure

fenoprop

CAS#:93-72-1

Literature: Recueil des Travaux Chimiques des Pays-Bas, , vol. 74, p. 155,159

~%

fenoprop Structure

fenoprop

CAS#:93-72-1

Literature: Contributions from Boyce Thompson Institute, , vol. 14, p. 91,95, 96 Chem.Abstr., , p. 1473

 Customs

HS Code 2918990090
Summary 2918990090. other carboxylic acids with additional oxygen function and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

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 Synonyms

rac-(2R)-2-(2,4,5-trichlorophenoxy)propanoic acid
Kuran
MFCD00002646
(RS)-2-(2,4,5-trichlorophenoxy)propionic acid
2-(2,4,5-trichlorophenoxy)propanoic acid
EINECS 202-271-2
Color-set
2,4,5-TP
Sta-fast
Double strength
Fenoprop
Fenormone
Aqua-vex
2,6-DIFLUOROPYRIDINE-3-BORONIC ACID HYDRATE
SILVEX
2,4,5-trichlorophenoxypropionic acid
Propon