2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide
Modify Date: 2024-01-11 12:45:11
2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide structure
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Common Name | 2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl gold(I) bis(trifluoromethanesulfonyl)imide | ||
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| CAS Number | 934506-10-2 | Molecular Weight | 953.82900 | |
| Density | N/A | Boiling Point | N/A | |
| Molecular Formula | C35H49AuF6NO4PS2 | Melting Point | N/A | |
| MSDS | Chinese USA | Flash Point | N/A | |
| Symbol |
GHS07 |
Signal Word | Warning | |
| Name | bis(trifluoromethylsulfonyl)azanide,dicyclohexyl-[2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane,gold(1+) |
|---|---|
| Synonym | More Synonyms |
| Molecular Formula | C35H49AuF6NO4PS2 |
|---|---|
| Molecular Weight | 953.82900 |
| Exact Mass | 953.24100 |
| PSA | 98.63000 |
| LogP | 13.71480 |
| Symbol |
GHS07 |
|---|---|
| Signal Word | Warning |
| Hazard Statements | H315-H319-H335 |
| Precautionary Statements | P261-P305 + P351 + P338 |
| Personal Protective Equipment | dust mask type N95 (US);Eyeshields;Gloves |
| Hazard Codes | Xi |
| RIDADR | NONH for all modes of transport |
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2-Dicyclohexylp... CAS#:934506-10-2 |
| Literature: Iwai, Tomohiro; Okochi, Hiori; Ito, Hideto; Sawamura, Masaya Angewandte Chemie - International Edition, 2013 , vol. 52, # 15 p. 4239 - 4242 Angew. Chem., 2013 , vol. 125, # 15 p. 4333 - 4336,4 |
![Chloro[2-dicyclohexyl(2′,4′,6′-trisopropylbiphenyl)phosphine]gold(I) structure](https://image.chemsrc.com/caspic/035/854045-94-6.png)
![Silver(1+) bis[(trifluoromethyl)sulfonyl]azanide structure](https://image.chemsrc.com/caspic/099/189114-61-2.png)
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Gold(I)-catalyzed isomerization of allenyl carbinol esters: an efficient access to functionalized 1,3-butadien-2-ol esters.
Org. Lett. 9 , 985, (2007) A study concerning the gold(I)-catalyzed rearrangement of diversely substituted allenyl carbinol esters into functionalized 1,3-butadien-2-ol esters is described. The mild conditions employed allow th... |
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Gold(I)-catalyzed 5-endo hydroxy- and alkoxycyclization of 1,5-enynes: efficient access to functionalized cyclopentenes.
Angew. Chem. Int. Ed. Engl. 46 , 1141, (2007)
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An unusual access to medium sized cycloalkynes by a new gold(I)-catalysed cycloisomerisation of diynes.
Chemistry 15 , 8966, (2009)
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| tBuXPhosAuNTf |
| XPhos AuNTf2 |