SnAP Pip Reagent
SnAP Pip Reagent structure
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Common Name | SnAP Pip Reagent | ||
|---|---|---|---|---|
| CAS Number | 1557287-99-6 | Molecular Weight | 463.29 | |
| Density | 1.108 g/mL | Boiling Point | N/A | |
| Molecular Formula | C20H44N2O2Sn | Melting Point | N/A | |
| MSDS | USA | Flash Point | N/A | |
| Symbol |
GHS06, GHS09 |
Signal Word | Danger | |
| Name | SnAP Pip Reagent |
|---|
| Density | 1.108 g/mL |
|---|---|
| Molecular Formula | C20H44N2O2Sn |
| Molecular Weight | 463.29 |
| Appearance of Characters | liquid |
| Index of Refraction | n/D1.4860 |
| Storage condition | -20°C |
| Symbol |
GHS06, GHS09 |
|---|---|
| Signal Word | Danger |
| Hazard Statements | H301 + H311 + H331-H315-H319-H335-H410 |
| Precautionary Statements | P261-P273-P280-P301 + P310-P305 + P351 + P338-P311 |
| RIDADR | UN 2788 6.1 / PGIII |
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SnAP reagents for the transformation of aldehydes into substituted thiomorpholines--an alternative to cross-coupling with saturated heterocycles.
Angew. Chem. Int. Ed. Engl. 52(6) , 1705-8, (2013)
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SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes.
Nature Chemistry 6(4) , 310-4, (2014) Interest in saturated N-heterocycles as scaffolds for the synthesis of bioactive molecules is increasing. Reliable and predictable synthetic methods for the preparation of these compounds, especially ... |
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One-step synthesis of saturated spirocyclic N-heterocycles with stannyl amine protocol (SnAP) reagents and ketones.
J. Am. Chem. Soc. 136(51) , 17726-9, (2014) The combination of cyclic ketones and stannyl amine protocol (SnAP) reagents affords saturated, spirocyclic N-heterocycles under operationally simple reaction conditions. The resulting, N-unprotected ... |