4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one

Modify Date: 2024-01-12 11:44:02

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure
4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one structure
Common Name 4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one
CAS Number 74684-36-9 Molecular Weight 1127.58000
Density 1.17g/cm3 Boiling Point N/A
Molecular Formula C76H94N4O4 Melting Point N/A
MSDS N/A Flash Point N/A

 Names

Name 4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one
Synonym More Synonyms

 Chemical & Physical Properties

Density 1.17g/cm3
Molecular Formula C76H94N4O4
Molecular Weight 1127.58000
Exact Mass 1126.73000
PSA 137.22000
LogP 16.06860
Index of Refraction 1.636

 Synthetic Route

~37%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Literature: Semeikin, A. S.; Koifman, O. I.; Berezin, B. D. Chemistry of Heterocyclic Compounds (New York, NY, United States), 1986 , vol. 22, # 6 p. 629 - 632 Khimiya Geterotsiklicheskikh Soedinenii, 1986 , vol. 22, # 6 p. 798 - 801

~%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Literature: Traylor, T. G.; Nolan, Kevin B.; Hildreth, Robert Journal of the American Chemical Society, 1983 , vol. 105, # 19 p. 6149 - 6151

~%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Literature: Shundo, Atsuomi; Hill, Jonathan P.; Ariga, Katsuhiko Chemistry - A European Journal, 2009 , vol. 15, # 11 p. 2486 - 2490

~99%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Literature: Melezhik, A.V.; Pokhodenko, V.D. Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, p. 912 - 917 Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 5 p. 1054 - 1059

~%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Literature: Milgrom, Lionel R. Tetrahedron, 1983 , vol. 39, # 23 p. 3895 - 3898

~%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Detail
Literature: Milgrom, Lionel R.; Mofidi, Nasrin; Harriman, Anthony Tetrahedron, 1989 , vol. 45, # 23 p. 7341 - 7352

~%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Detail
Literature: Milgrom, Lionel R.; Mofidi, Nasrin; Jones, Christopher C.; Harriman, Anthony Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 301 - 310

~%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Detail
Literature: Milgrom, Lionel R.; Mofidi, Nasrin; Jones, Christopher C.; Harriman, Anthony Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 301 - 310

~%

4-[(10Z,14Z)-10,15-bis(3,5-ditert-butyl-4-hydroxyphenyl)-20-(3,5-ditert-butyl-4-oxocyclohexa-2,5-dien-1-ylidene)-21,22,23,24-tetrahydroporphyrin-5-ylidene]-2,6-ditert-butylcyclohexa-2,5-dien-1-one Structure

4-[(10Z,14Z)-10...

CAS#:74684-36-9

Detail
Literature: Milgrom, Lionel R.; Mofidi, Nasrin; Jones, Christopher C.; Harriman, Anthony Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1989 , p. 301 - 310

 Synonyms

2,6-Bis(tert-butyl)-4-{7,12,17-tris[3,5-bis(tert-butyl)-4-hydroxyphenyl]-21,22,23,24-tetraazapentacyclo[16.2.1.1
meso-5,10,15,20-tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)porphyrin
5,10,15,20-tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)porphyrin
DD-092
meso-tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)porphyrin
5,10,15,20-tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphyrin
5,10,15,20-tetra(4'-hydroxy-3',5'-di-tert-butylphenyl)-21H,23H-porphyrin
meso-tetrakis(3,5-di-tert-butyl-4-hydroxyphenyl)porphyrin
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