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对甲氧基苯乙酮

对甲氧基苯乙酮用途

【用途一】
用于配制香精,常用于高级化妆品和皂用香料中,也可用于有机合成
【用途二】
用于香料合成
【用途三】
适用于山楂花、金合欢、含羞花、刺槐、香薇、素心兰、新刈草、三叶草等香型,常用于药草香、木香等型皂用香精中。但一般宜与大茴香醛和大茴香醇共用。也可作为茴香和豆香的协调香气,而广泛用于各类香精的配方,还可用于食用香精如奶油、烟糖、巧克力、鲜果、坚果、香荚兰豆等香型及烟草香精中。
【用途四】
GB 2760--1996规定为允许使用的食用香料。主要用于配制香荚兰豆、果仁、奶油和烟草等型香精。
【用途五】
该品具有浓郁的山楂香气,是含羞、山楂等香型香精不可缺少的原料。常用于高级化妆品和皂用香精中,在肥皂中有很高的稳定性,亦可作果实食品香精。我国 GB 2760-86规定为允许使用的食用香料,主要用于配制香荚兰豆、果仁、奶油和烟草等型香料。也用于防晒剂和有机合成,生产对甲氧基苯乙酸用作葛根素的中间体,以及液晶单体的生产。
【用途六】
有机合成。香料。

对甲氧基苯乙酮名称

[ CAS 号 ]:
100-06-1

[ 中文名 ]:
对甲氧基苯乙酮

[ 英文名 ]:
Acetanisole

[中文别名 ]:

[英文别名 ]:

对甲氧基苯乙酮物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
256.4±13.0 °C at 760 mmHg

[ 熔点 ]:
36-38 °C(lit.)

[ 分子式 ]:
C9H10O2

[ 分子量 ]:
150.174

[ 闪点 ]:
113.2±13.4 °C

[ 精确质量 ]:
150.068085

[ PSA ]:
26.30000

[ LogP ]:
1.74

[ 外观性状 ]:
白色结晶

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.504

[ 储存条件 ]:
室温,避光

[ 水溶解性 ]:
insoluble

对甲氧基苯乙酮MSDS

对甲氧基苯乙酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AM9240000
CHEMICAL NAME :
Acetophenone, 4'-methoxy-
CAS REGISTRY NUMBER :
100-06-1
LAST UPDATED :
199701
DATA ITEMS CITED :
9
MOLECULAR FORMULA :
C9-H10-O2
MOLECULAR WEIGHT :
150.19
WISWESSER LINE NOTATION :
1VR DO1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,927,1974 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Human
DOSE/DURATION :
1700 ug/m3/39W-I
TOXIC EFFECTS :
Cardiac - pulse rate increase, without fall in BP Vascular - BP elevation not characterized in autonomic section
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(4),86,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1720 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,927,1974
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
820 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Behavioral - irritability
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(4),86,1985
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,927,1974 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
152 mg/m3/4H/13W-I
TOXIC EFFECTS :
Brain and Coverings - recordings from specific areas of CNS Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases
REFERENCE :
GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(4),86,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83215 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 580 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83215 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 1557 (estimated) No. of Female Employees: 276 (estimated)

对甲氧基苯乙酮安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H315

[ 警示性声明 ]:
P301 + P312 + P330

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn:Harmful

[ 风险声明 (欧洲) ]:
R22;R36/38

[ 安全声明 (欧洲) ]:
S37-S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
AM9240000

[ 海关编码 ]:
2914509090

对甲氧基苯乙酮合成路线

对甲氧基苯乙酮上下游产品

对甲氧基苯乙酮制备

1、由茴香醚在无水三氯化铝(或三氯化铁、氯化锌、酸性白土)的条件下,与乙酐(或乙酰氯)经乙酰化反应制得。将茴香醚、乙酐加入反应锅,加氯化锌后缓缓加热至沸腾,保持回流(约140℃),反应4h后减压蒸馏、水洗、精馏而得成品。

2、由苯甲醚和乙酸在三氟化硼存在下反应而得。

3、由苯甲醚和乙酰氯在氯化铝和二硫化碳存在下反应而得。

4. 烟草:FC,18。

对甲氧基苯乙酮海关

[ 海关编码 ]: 2914509090

[ 中文概述 ]:
2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装

[ Summary ]:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

对甲氧基苯乙酮文献

Synthesis and physiological activity of thiophenes and furans with 3- and 4-methoxyacetophenone derivatives.

J. Oleo Sci. 57(2) , 107-13, (2008)

The synthesis and physiological activity of thiophenes and furans with methoxyacetophenone derivatives were examined. 3-Methoxyacetophenone (1) and 4-methoxyacetophenone (2) were converted, respective...

Electronic effects of para-substitution on acetophenones in the reaction of rat liver 3alpha-hydroxysteroid dehydrogenase.

Bioorg. Med. Chem. 16 , 1084-9, (2008)

Stereoselective reductive metabolism of various p-substituted acetophenone derivatives was studied using isolated rat liver 3alpha-hydroxysteroid dehydrogenase (3alpha-HSD). Kinetic experiments were p...

1-(1-Arylethylidene)thiosemicarbazide derivatives: a new class of tyrosinase inhibitors.

Bioorg. Med. Chem. 16 , 1096-102, (2008)

A series of 1-(1-arylethylidene)thiosemicarbazide compounds and their analogues were synthesized and characterized by 1H NMR, MS. Their tyrosinase inhibitory activities were investigated by an assay b...


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【对甲氧基苯乙酮】化源网提供对甲氧基苯乙酮CAS号100-06-1,对甲氧基苯乙酮MSDS及其说明、性质、英文名、生产厂家、作用/用途、分子量、密度、沸点、熔点、结构式等。CAS号查询对甲氧基苯乙酮上化源网,专业又轻松。>>电脑版:对甲氧基苯乙酮

标题:对甲氧基苯乙酮_MSDS_用途_密度_CAS号【100-06-1】_化源网 地址:https://www.chemsrc.com/amp/cas/100-06-1_952243.html