对甲氧基苯乙酮
对甲氧基苯乙酮用途
用于配制香精,常用于高级化妆品和皂用香料中,也可用于有机合成
【用途二】
用于香料合成
【用途三】
适用于山楂花、金合欢、含羞花、刺槐、香薇、素心兰、新刈草、三叶草等香型,常用于药草香、木香等型皂用香精中。但一般宜与大茴香醛和大茴香醇共用。也可作为茴香和豆香的协调香气,而广泛用于各类香精的配方,还可用于食用香精如奶油、烟糖、巧克力、鲜果、坚果、香荚兰豆等香型及烟草香精中。
【用途四】
GB 2760--1996规定为允许使用的食用香料。主要用于配制香荚兰豆、果仁、奶油和烟草等型香精。
【用途五】
该品具有浓郁的山楂香气,是含羞、山楂等香型香精不可缺少的原料。常用于高级化妆品和皂用香精中,在肥皂中有很高的稳定性,亦可作果实食品香精。我国 GB 2760-86规定为允许使用的食用香料,主要用于配制香荚兰豆、果仁、奶油和烟草等型香料。也用于防晒剂和有机合成,生产对甲氧基苯乙酸用作葛根素的中间体,以及液晶单体的生产。
【用途六】
有机合成。香料。
对甲氧基苯乙酮名称
[ CAS 号 ]:
100-06-1
[ 中文名 ]:
对甲氧基苯乙酮
[ 英文名 ]:
Acetanisole
[中文别名 ]:
[英文别名 ]:
- Methyl 4-methoxyphenyl ketone
- 4-Acetoanisole
- 4’-Methoxyacetophenone
- 1-(4-Methoxyphenyl)ethanone
- 4‘-Methoxyacetophenone
- Acetophenone, 4'-methoxy-
- EINECS 202-815-9
- p-Acetylanisole
- para-Methoxyacetophenone
- p-Methoxyacetophenone
对甲氧基苯乙酮物理化学性质
[ 密度 ]:
1.0±0.1 g/cm3
[ 沸点 ]:
256.4±13.0 °C at 760 mmHg
[ 熔点 ]:
36-38 °C(lit.)
[ 分子式 ]:
C9H10O2
[ 分子量 ]:
150.174
[ 闪点 ]:
113.2±13.4 °C
[ 精确质量 ]:
150.068085
[ PSA ]:
26.30000
[ LogP ]:
1.74
[ 外观性状 ]:
白色结晶
[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C
[ 折射率 ]:
1.504
[ 储存条件 ]:
室温,避光
[ 水溶解性 ]:
insoluble
对甲氧基苯乙酮MSDS
对甲氧基苯乙酮毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- AM9240000
- CHEMICAL NAME :
- Acetophenone, 4'-methoxy-
- CAS REGISTRY NUMBER :
- 100-06-1
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 9
- MOLECULAR FORMULA :
- C9-H10-O2
- MOLECULAR WEIGHT :
- 150.19
- WISWESSER LINE NOTATION :
- 1VR DO1
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- Standard Draize test
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,927,1974 ** ACUTE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Human
- DOSE/DURATION :
- 1700 ug/m3/39W-I
- TOXIC EFFECTS :
- Cardiac - pulse rate increase, without fall in BP Vascular - BP elevation not characterized in autonomic section
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(4),86,1985
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 1720 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,927,1974
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 820 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - muscle weakness Behavioral - irritability
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(4),86,1985
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- >5 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- REFERENCE :
- FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 12,927,1974 ** OTHER MULTIPLE DOSE TOXICITY DATA **
- TYPE OF TEST :
- TCLo - Lowest published toxic concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 152 mg/m3/4H/13W-I
- TOXIC EFFECTS :
- Brain and Coverings - recordings from specific areas of CNS Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases
- REFERENCE :
- GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 50(4),86,1985 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83215 No. of Facilities: 21 (estimated) No. of Industries: 1 No. of Occupations: 2 No. of Employees: 580 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83215 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 1557 (estimated) No. of Female Employees: 276 (estimated)
对甲氧基苯乙酮安全信息
[ 符号 ]:
GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H302-H315
[ 警示性声明 ]:
P301 + P312 + P330
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves
[ 危害码 (欧洲) ]:
Xn:Harmful
[ 风险声明 (欧洲) ]:
R22;R36/38
[ 安全声明 (欧洲) ]:
S37-S37/39-S26
[ 危险品运输编码 ]:
NONH for all modes of transport
[ WGK德国 ]:
2
[ RTECS号 ]:
AM9240000
[ 海关编码 ]:
2914509090
对甲氧基苯乙酮合成路线
对甲氧基苯乙酮上下游产品
对甲氧基苯乙酮上游产品
对甲氧基苯乙酮下游产品
对甲氧基苯乙酮制备
1、由茴香醚在无水三氯化铝(或三氯化铁、氯化锌、酸性白土)的条件下,与乙酐(或乙酰氯)经乙酰化反应制得。将茴香醚、乙酐加入反应锅,加氯化锌后缓缓加热至沸腾,保持回流(约140℃),反应4h后减压蒸馏、水洗、精馏而得成品。
2、由苯甲醚和乙酸在三氟化硼存在下反应而得。
3、由苯甲醚和乙酰氯在氯化铝和二硫化碳存在下反应而得。
4. 烟草:FC,18。
对甲氧基苯乙酮海关
[ 海关编码 ]: 2914509090
[ 中文概述 ]:
2914509090 含其他含氧基的酮. 增值税率:17.0% 退税率:9.0% 监管条件:无 最惠国关税:5.5% 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途, 丙酮报明包装
[ Summary ]:
HS:2914509090 other ketones with other oxygen function VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%
对甲氧基苯乙酮文献
J. Oleo Sci. 57(2) , 107-13, (2008)
The synthesis and physiological activity of thiophenes and furans with methoxyacetophenone derivatives were examined. 3-Methoxyacetophenone (1) and 4-methoxyacetophenone (2) were converted, respective...
Electronic effects of para-substitution on acetophenones in the reaction of rat liver 3alpha-hydroxysteroid dehydrogenase.Bioorg. Med. Chem. 16 , 1084-9, (2008)
Stereoselective reductive metabolism of various p-substituted acetophenone derivatives was studied using isolated rat liver 3alpha-hydroxysteroid dehydrogenase (3alpha-HSD). Kinetic experiments were p...
1-(1-Arylethylidene)thiosemicarbazide derivatives: a new class of tyrosinase inhibitors.Bioorg. Med. Chem. 16 , 1096-102, (2008)
A series of 1-(1-arylethylidene)thiosemicarbazide compounds and their analogues were synthesized and characterized by 1H NMR, MS. Their tyrosinase inhibitory activities were investigated by an assay b...
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相关化合物
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标题:对甲氧基苯乙酮_MSDS_用途_密度_CAS号【100-06-1】_化源网 地址:https://www.chemsrc.com/amp/cas/100-06-1_952243.html