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硝酸钯

硝酸钯用途

【用途一】
用作分析试剂和氧化剂，也用于氯和碘的分离
【用途二】
催化剂，合成多种钯化合物和催化剂的原料，大量用来配制钯镀槽液

硝酸钯名称

[ CAS 号 ]:
10102-05-3

[ 中文名 ]:
硝酸钯

[ 英文名 ]:
Palladium nitrate

[英文别名 ]:

PaladiumNitrate
PALLADIUM STANDARD SOLUTION
PALLADIUM(II) NITRATE 2 H2O
Palladous nitrate
Palladium(II) nitrate
Palladium(II) nitrate dihydrate
Palladium(II) nitrate solution
MFCD00011169
palladium dinitrate
palladiumdinitrate

硝酸钯物理化学性质

[ 密度 ]:
1.118 g/mL at 25 °C

[ 沸点 ]:
83ºC at 760 mmHg

[ 熔点 ]:
>100ºC

[ 分子式 ]:
N₂O₆Pd

[ 分子量 ]:
230.430

[ 精确质量 ]:
229.879120

[ PSA ]:
137.76000

[ LogP ]:
0.56820

[ 外观性状 ]:
黄色或橙色棕色液体,酸味

[ 储存条件 ]:
库房通风低温干燥,轻装轻卸,与有机物、还原剂、硫、磷易燃物分开存放

硝酸钯MSDS

详细MSDS(安全技术说明书)

硝酸钯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: QV0560000

CHEMICAL NAME :: Nitric acid, palladium(2+) salt

CAS REGISTRY NUMBER :: 10102-05-3

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: N2-O6.Pd

MOLECULAR WEIGHT :: 230.42

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TEST SYSTEM :: Rodent - rat

DOSE/DURATION :: 56 umol/kg

REFERENCE :: EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 12,57,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1001 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 140 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1001 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1445 (estimated) No. of Female Employees: 230 (estimated)

硝酸钯安全信息

[ 符号 ]:

GHS03, GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H272-H314

[ 警示性声明 ]:
P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
Xi: Irritant;C: Corrosive;O: Oxidizing agent;

[ 风险声明 (欧洲) ]:
R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S17

[ 危险品运输编码 ]:
UN 3264 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
QV0560000

[ 包装等级 ]:
II

[ 危险类别 ]:
5.1

硝酸钯制备

将金属钯粉或新制备的氢氧化钯加入浓硝酸中，水浴加热。过滤，所得滤液减压蒸馏浓缩后，放入干燥器中冷却结晶。抽滤。产品密封保存。

硝酸钯文献

Metallic and bimetallic nanocatalysts incorporated into highly porous coordination polymer MIL-101. El-Shall M, et al.

J. Mater. Chem. 19(41) , 7625-7631, (2009)

Complete degradation of perchlorate using Pd/N-doped activated carbon with adsorption/catalysis bifunctional roles Kim YN, et al.

Carbon 65 , 315-323, (2013)

Influence of ni addition to a low-loaded palladium catalyst on the selective hydrogenation of 1-heptyne. Lederhos CR, et al.

Quim. Nova 33(4) , 816-820, (2010)

更多文献

硝酸钯