10102-05-3

• 常用中文名：硝酸钯
• 常用英文名：Palladium nitrate
• CAS号：10102-05-3
• 分子式：N₂O₆Pd
• 分子量：230.430
• 相关类别： 无机化工 无机盐 金属硝酸盐及亚硝酸盐
• 发布时间：2018-06-20 18:24:29
• 更新时间：2024-01-02 12:34:15
• 【用途一】
  用作分析试剂和氧化剂，也用于氯和碘的分离
  【用途二】
  催化剂，合成多种钯化合物和催化剂的原料，大量用来配制钯镀槽液

名称

• 中文名: 硝酸钯
• 英文名: Palladium nitrate
• 英文别名: PaladiumNitrate; PALLADIUM STANDARD SOLUTION; PALLADIUM(II) NITRATE 2 H2O; Palladous nitrate; Palladium(II) nitrate; Palladium(II) nitrate dihydrate; Palladium(II) nitrate solution; MFCD00011169; palladium dinitrate; palladiumdinitrate; Palladium nitrate di; UNII-5G27LBZ05U; EINECS 233-265-8; Pa Nitrate; nitric acid, palladium(2+) salt; Palladium(2+) dinitrate; PALLACIUM(II)NITRATE

物化性质

• 密度: 1.118 g/mL at 25 °C
• 沸点: 83ºC at 760 mmHg
• 熔点: >100ºC
• 分子式: N₂O₆Pd
• 分子量: 230.430
• 精确质量: 229.879120
• PSA: 137.76000
• LogP: 0.56820
• 外观性状: 黄色或橙色棕色液体,酸味
• 储存条件:

  储存注意事项 储存于阴凉、通风的库房。远离火种、热源。库温不超过30℃，相对湿度不超过80%。包装密封。应与易（可）燃物、还原剂等分开存放，切忌混储。储区应备有合适的材料收容泄漏物。

• 稳定性:

  1.稳定性 稳定

  2.禁配物 还原剂、易燃或可燃物、活性金属粉末、硫、磷

  3.避免接触的条件 受热

  4.聚合危害 不聚合

  5.分解产物 氮氧化物

• 分子结构:

  1、摩尔折射率：无可用的

  2、摩尔体积（cm³/mol）：无可用的

  3、等张比容（90.2K）：无可用的

  4、表面张力（dyne/cm）：无可用的

  5、介电常数：无可用的

  6、极化率（10^-24cm³）：无可用的

  7、单一同位素质量：229.879119 Da

  8、标称质量：230 Da

  9、平均质量：230.4298 Da

• 计算化学:

  1.疏水参数计算参考值（XlogP）:无

  2.氢键供体数量:0

  3.氢键受体数量:6

  4.可旋转化学键数量:0

  5.互变异构体数量:无

  6.拓扑分子极性表面积126

  7.重原子数量:9

  8.表面电荷:0

  9.复杂度:18.8

  10.同位素原子数量:0

  11.确定原子立构中心数量:0

  12.不确定原子立构中心数量:0

  13.确定化学键立构中心数量:0

  14.不确定化学键立构中心数量:0

  15.共价键单元数量:3

• 更多:

  1.性状：棕黄色结晶或粉末，有潮解性。

  2.熔点（℃）：分解

  3.相对密度（水=1）：1.118

  4.溶解性：溶于水，溶于稀硝酸。

MSDS

Section 1: Product Identification Chemical Name:Palladium (II) nitrate hydrate(Pd approx. 40%) (99.9%-Pd) CAS Registry Number:10102-05-3 Formula:Pd(NO3)2.XH2O EINECS Number:233-265-8 Chemical Family:metal nitrate salts Synonym:Palladium dinitrate, Nitric acid, palladium (+2) salt Section 2: Composition and Information on Ingredients IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL) Title Compound10102-05-3100%no datano data Section 3: Hazards Identification Emergency Overview:Irritating to eyes, skin and respiratory tract. May be harmful if swallowed. Primary Routes of Exposure:Ingestion Eye Contact:Causes slight to mild irritation of the eyes Skin Contact:Causes slight to mild irritation of the skin. Inhalation:Irritating to the nose, mucous membranes and respiratory tract. Ingestion:Ingestion may lead to dizziness, abdominal cramps, vomiting, bloody diarrhea, weakness, and convulsions. Acute Health Affects:Irritating to skin, eyes and respiratory tract. Chronic Health Affects:No information available on long-term chronic effects. NTP:No IARC:No OSHA:No SECTION 4: First Aid Measures Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need Eye Exposure: assistance in keeping their eye lids open. Get immediate medical attention. Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if Skin Exposure: irritation persists. Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty Inhalation: in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance. Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce Ingestion: vomiting only if directed by medical personnel. SECTION 5: Fire Fighting Measures Flash Point:not applicable Autoignition Temperature:none Explosion Limits:none Extinguishing Medium:carbon dioxide, foam or dry powder If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure Special Fire Fighting Procedures: self-contained breathing apparatus and full protective clothing. Hazardous Combustion andIf involved in a fire this material may emit irritating fumes. Decomposion Products: Unusual Fire or Explosion Hazards: Metal nitrates can be oxidizers. Contact with strong reducing agents could lead to fires and/or explosions. SECTION 6: Accidental Release Measures Spill and Leak Procedures:Small spills can be mixed with vermiculite or sodium carbonate and swept up. SECTION 7: Handling and Storage Handling and Storage:Store in a tightly sealed container. Keep away from heat and direct sunlight. SECTION 8: Exposure Controls and Personal Protection Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory. Skin Protection:Wear protective clothing and gloves Ventilation:If possible, handle the material in an efficient fume hood. If ventilation is not available a respirator should be worn. The use of respirators requires a Respiratory Respirator: Protection Program to be in compliance with 29 CFR 1910.134. Ventilation:If possible, handle the material in an efficient fume hood. Additional Protection:No additional protection required. SECTION 9: Physical and Chemical Properties Color and Form:brown xtl. Molecular Weight:230.72 Melting Point:dec. Boiling Point:no data Vapor Pressure:not applicable Specific Gravity:no data Odor:none Solubility in Water:very soluble SECTION 10: Stability and Reactivity Stability:air and moisture stable Hazardous Polymerization:no hazardous polymerization Contact with strong reducing agents or organic matter. Some nitrates can explode if heated to high Conditions to Avoid: temperatures. Incompatibility:reducing agents, organic matter, phosphorus and sulfur Decomposition Products:nitrogen oxides and palladium salts SECTION 11: Toxicological Information RTECS Data:Intraperitoneal (rat); DNA inhibition: 56 umol/kg. Carcinogenic Effects:No data available Mutagenic Effects:Possible mutagenic effects reported in RTECS Tetratogenic Effects:No data available SECTION 12: Ecological Information Ecological Information:No data available SECTION 13: Disposal Considerations Disposal:Dispose of according to local, state and federal regulations. SECTION 14: Transportation Shipping Name (CFR):Nitrates, Inorganic, N.O.S. Hazard Class (CFR):5.1 Additional Hazard Class (CFR):NA Packaging Group (CFR):II UN ID Number (CFR):UN# 1477 Shipping Name (IATA):Nitrates, Inorganic, N.O.S. Hazard Class (IATA):5.1 Additional Hazard Class (IATA):NA Packaging Group (IATA):II UN ID Number (IATA):UN# 1477 SECTION 15: Regulatory Information TSCA:Listed in the TSCA inventory. SARA (Title 313):Title Compound: See Category Code N511 for reporting. Second Ingredient:none SECTION 16 - ADDITIONAL INFORMATION N/A

毒性和生态

毒理学数据: 1.急性毒性 暂无资料 2.刺激性 暂无资料 生态学数据: 1.生态毒性 暂无资料 2.生物降解性 暂无资料 3.非生物降解性 暂无资料 4.其他有害作用 该物质对环境有危害，应特别注意对水体的污染。 CHEMICAL IDENTIFICATION RTECS NUMBER : QV0560000 CHEMICAL NAME : Nitric acid, palladium(2+) salt CAS REGISTRY NUMBER : 10102-05-3 LAST UPDATED : 199701 DATA ITEMS CITED : 4 MOLECULAR FORMULA : N2-O6.Pd MOLECULAR WEIGHT : 230.42 HEALTH HAZARD DATA ACUTE TOXICITY DATA MUTATION DATA TEST SYSTEM : Rodent - rat DOSE/DURATION : 56 umol/kg REFERENCE : EVHPAZ EHP, Environmental Health Perspectives. (U.S. Government Printing Office, Supt of Documents, Washington, DC 20402) No.1- 1972- Volume(issue)/page/year: 12,57,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - A1001 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 140 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1001 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1445 (estimated) No. of Female Employees: 230 (estimated)

安全

• 符号: GHS03, GHS05
• 信号词: Danger
• 危害声明: H272-H314
• 警示性声明: P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338
• 个人防护装备: Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
• 危害码 (欧洲): Xi: Irritant;C: Corrosive;O: Oxidizing agent;
• 风险声明 (欧洲): R34
• 安全声明 (欧洲): S26-S36/37/39-S45-S17
• 危险品运输编码: UN 3264 8/PG 2
• WGK德国: 3
• RTECS号: QV0560000
• 包装等级: II
• 危险类别: 5.1

制备

将金属钯粉或新制备的氢氧化钯加入浓硝酸中，水浴加热。过滤，所得滤液减压蒸馏浓缩后，放入干燥器中冷却结晶。抽滤。产品密封保存。