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1-苯基氨基脲

1-苯基氨基脲用途

1-苯基氨基脲是一种抗真菌剂。1-苯基氨基脲具有防止工业产品上霉菌生长的潜力[1]。

1-苯基氨基脲名称

[ CAS 号 ]:
103-03-7

[ 中文名 ]:
1-苯基氨基脲

[ 英文名 ]:
1-Carbamoyl-2-phenylhydrazin

[中文别名 ]:

苯胺脲

[英文别名 ]:

EINECS 203-072-3
MFCD00007942
anilinourea

1-苯基氨基脲生物活性

[ 描述 ]:

1-苯基氨基脲是一种抗真菌剂。1-苯基氨基脲具有防止工业产品上霉菌生长的潜力[1]。

[ 相关类别 ]:

研究领域 >> 感染

信号通路 >> 抗感染 >> 真菌

[参考文献]

[1]. Iwamoto, Hiromichi, et al. Prevention of mold growth on industrial products. XI. Antifungal activities of various fungicides. 5. Organic nitrogen-sulfur compounds.

1-苯基氨基脲物理化学性质

[ 密度 ]:
1.275g/cm3

[ 熔点 ]:
171-174 °C(lit.)

[ 分子式 ]:
C₇H₉N₃O

[ 分子量 ]:
151.16600

[ 精确质量 ]:
151.07500

[ PSA ]:
67.15000

[ LogP ]:
1.84600

[ 外观性状 ]:
固体;White to Light yellow powder to crystal

[ 折射率 ]:
1.601

[ 储存条件 ]:
库房低温通风干燥

[ 水溶解性 ]:
可溶于：甲醇

1-苯基氨基脲MSDS

详细MSDS(安全技术说明书)

1-苯基氨基脲毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: FD0575000

CHEMICAL NAME :: Carbamic acid, 2-phenylhydrazide

CAS REGISTRY NUMBER :: 103-03-7

BEILSTEIN REFERENCE NO. :: 0743311

LAST UPDATED :: 199707

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C7-H9-N3-O

MOLECULAR WEIGHT :: 151.19

WISWESSER LINE NOTATION :: ZVMMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 198 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 394 mg/kg/62W-C

TOXIC EFFECTS :: Tumorigenic - neoplastic by RTECS criteria Lungs, Thorax, or Respiration - tumors

MUTATION DATA

TYPE OF TEST :: DNA repair

TEST SYSTEM :: Bacteria - Escherichia coli

DOSE/DURATION :: 250 ug/well

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 133,161,1984 *** REVIEWS *** IARC Cancer Review:Animal Limited Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 12,177,1976 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 12,177,1976 IARC Cancer Review:Group 3 IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987

1-苯基氨基脲安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S45-S36/37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
FD0575000

[ 海关编码 ]:
2928000090

1-苯基氨基脲合成路线

详细合成路线

1-苯基氨基脲制备

其制备方法是以苯肼与尿素为原料反应而成。在1000L反应釜中加入136kg苯肼盐酸盐、98kg尿素和240L水。搅拌均匀并升温至100℃以上进行缩合反应，反应6h后，加水280L，冷却至5℃，过滤，即可得到1-苯基氨基脲，含量95％以上，收率93％以上。

1-苯基氨基脲海关

[ 海关编码 ]: 2928000090

[ 中文概述 ]:
2928000090 其他肼（联氨）及胲（羟胺）的有机衍生物。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2928000090 other organic derivatives of hydrazine or of hydroxylamine VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

1-苯基氨基脲文献

New one-pot, efficient, and regioselective method for the synthesis of 3-Trifluoromethyl-1< i> H</i>-1-phenylpyrazoles and alkyl 3-carboxylate analogs. Bonacorso HG, et al.

Tetrahedron Lett. 53(41) , 5488-5491, (2012)

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