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2,2-D2,2-二甲基-3-(2-甲基丙-1-烯-1-基)环丙烷甲酸

用途

菊花酸(NSC 11779)是一种有机化合物,与多种天然和合成杀虫剂有关,用于预防虫媒疾病等[1]。

名称

[ CAS 号 ]:
10453-89-1

[ 中文名 ]:
菊甲酸

[ 英文名 ]:
Cyclopropanecarboxylicacid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-

[中文别名 ]:

降虫菊酸

[英文别名 ]:

chrysanthemummonocarboxylicacidmixedisomers
CHRYSANTHEMUM MONOCARBOXYLIC ACID
chrysanthemumicacid
CIS/TRANS-CHRYSANTHEMIC ACID

生物活性

[ 描述 ]:

菊花酸(NSC 11779)是一种有机化合物,与多种天然和合成杀虫剂有关,用于预防虫媒疾病等[1]。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[参考文献]

[1]. Takanori Yamashiro, et al. Draft genome of Tanacetum cinerariifolium, the natural source of mosquito coil. Sci Rep. 2019 Dec 3;9(1):18249.

物理化学性质

[ 密度 ]:
1.077g/cm3

[ 沸点 ]:
246.4ºC at 760 mmHg

[ 熔点 ]:
50-51 °C

[ 分子式 ]:
C₁₀H₁₆O₂

[ 分子量 ]:
168.23300

[ 闪点 ]:
119ºC

[ 精确质量 ]:
168.11500

[ PSA ]:
37.30000

[ LogP ]:
2.30940

[ 外观性状 ]:
固体

[ 蒸汽压 ]:
0.0088mmHg at 25°C

[ 折射率 ]:
1.546

[ 储存条件 ]:
室温，密封，干燥

毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GZ1270000

CHEMICAL NAME :: Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methylpropenyl)-

CAS REGISTRY NUMBER :: 10453-89-1

BEILSTEIN REFERENCE NO. :: 2043418

LAST UPDATED :: 199701

DATA ITEMS CITED :: 12

MOLECULAR FORMULA :: C10-H16-O2

MOLECULAR WEIGHT :: 168.26

WISWESSER LINE NOTATION :: L3TJ A1 A1 BVQ C1UY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >400 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >400 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Behavioral - excitement

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 150 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 56 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: >586 mg/m3

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Behavioral - excitement

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 1248 mg/m3

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(1),16,1986

安全信息

[ 危害码 (欧洲) ]:
Xn

[ 海关编码 ]:
2916209090

合成路线

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海关

[ 海关编码 ]: 2916209090

[ 中文概述 ]:
2916209090 其他（环烷、环烯、环萜烯）一元羧酸（包括酸酐、酰卤化物，过氧化物和过氧酸及该税号的衍生物）. 增值税率:17.0% 退税率:9.0% 监管条件:AB(入境货物通关单,出境货物通关单) 最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ 监管条件 ]: A.入境货物通关单 B.出境货物通关单

[ 检验检疫 ]: R.进口食品卫生监督检验 S.出口食品卫生监督检验 M.进口商品检验 N.出口商品检验

[ Summary ]:
2916209090 other cyclanic, cyclenic or cyclotherpenic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:6.5% General tariff:30.0%