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2-甲基-1-戊醇

2-甲基-1-戊醇用途

主要用作硝基喷漆、清漆的溶剂或稀释剂，也可用作染料和油类的溶剂。

2-甲基-1-戊醇名称

[ CAS 号 ]:
105-30-6

[ 中文名 ]:
2-甲基-1-戊醇

[ 英文名 ]:
2-Hexanol

[中文别名 ]:

2-甲基戊醇

[英文别名 ]:

UNII:U8933MB30H
(RS)-2-hexanol
Methylpentanol
2-methylpentan-1-ol
2-Methyl-1-pentanol
Hexan-2-ol
2-methyl-2-propylethanol
1-Pentanol, 2-methyl-
Pentanol, methyl-
2-Propylpropanol

2-甲基-1-戊醇物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
148.0±0.0 °C at 760 mmHg

[ 分子式 ]:
C₆H₁₄O

[ 分子量 ]:
102.175

[ 闪点 ]:
50.6±0.0 °C

[ 精确质量 ]:
102.104462

[ PSA ]:
20.23000

[ LogP ]:
1.75

[ 外观性状 ]:
透明无色液体

[ 蒸汽密度 ]:
3.5 (vs air)

[ 蒸汽压 ]:
1.7±0.5 mmHg at 25°C

[ 折射率 ]:
1.414

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开储运

2-甲基-1-戊醇MSDS

2-甲基-1-戊醇毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SA7175000

CHEMICAL NAME :: 1-Pentanol, 2-methyl-

CAS REGISTRY NUMBER :: 105-30-6

BEILSTEIN REFERENCE NO. :: 1718974

LAST UPDATED :: 199710

DATA ITEMS CITED :: 18

MOLECULAR FORMULA :: C6-H14-O

MOLECULAR WEIGHT :: 102.20

WISWESSER LINE NOTATION :: Q1Y3&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,198,1986

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,198,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Human

DOSE/DURATION :: 50 ppm

TOXIC EFFECTS :: Sense Organs and Special Senses (Eye) - effect, not otherwise specified

REFERENCE :: JIHTAB Journal of Industrial Hygiene and Toxicology. (Cambridge, MA) V.18-31, 1936-49. For publisher information, see AEHLAU. Volume(issue)/page/year: 28,262,1946

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1410 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >5000 ppm/6H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >3200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: KODAK* Kodak Company Reports. (343 State St., Rochester, NY 14650) Volume(issue)/page/year: 21MAY1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 3560 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-DENMARK:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-THE NETHERLANDS:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-THE PHILIPPINES:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-TURKEY:TWA 25 ppm (100 mg/m3);Skin JAN 1993 OEL-UNITED KINGDOM:TWA 25 ppm (100 mg/m3);STEL 40 ppm;Skin JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X9059 No. of Facilities: 732 (estimated) No. of Industries: 8 No. of Occupations: 11 No. of Employees: 7512 (estimated)

2-甲基-1-戊醇安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H302

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn: Harmful;

[ 风险声明 (欧洲) ]:
R10

[ 安全声明 (欧洲) ]:
S24/25

[ 危险品运输编码 ]:
UN 1987 3/PG 3

[ WGK德国 ]:
3

[ RTECS号 ]:
SA7175000

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

[ 海关编码 ]:
2905199090

2-甲基-1-戊醇合成路线

2-甲基-1-戊醇上下游产品

2-甲基-1-戊醇上游产品

2-甲基-1-戊醇下游产品

2-甲基-1-戊醇制备

工业上由戊烯羰基合成后，再经加氢得产品。

2-甲基-1-戊醇海关

[ 海关编码 ]: 2905199090

[ 中文概述 ]:
2905199090. 其他饱和一元醇. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2905199090. saturated monohydric alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

2-甲基-1-戊醇文献

Ripening-dependent metabolic changes in the volatiles of pineapple (Ananas comosus (L.) Merr.) fruit: I. Characterization of pineapple aroma compounds by comprehensive two-dimensional gas chromatography-mass spectrometry.

Anal. Bioanal. Chem 407(9) , 2591-608, (2015)

Qualitative ripening-dependent changes of pineapple volatiles were studied via headspace solid-phase microextraction and analyzed by comprehensive two-dimensional gas chromatography quadrupole mass sp...

Stereoselective bioconversions in continuously operated fixed bed reactors: Modeling and process optimization.

Biotechnol. Bioeng. 52(4) , 459-71, (1996)

The nonaqueous lipase-catalyzed kinetic resolution of racemic 2-methyl-1-pentanol in a continuously operated fixed bed reactor was theoretically and experimentally studied. A 2-dimensional mathematica...

Excess enthalpies of binary mixtures of 2-methyl-1-pentanol with hexane isomers. Kimura F and Benson GC.

Fluid Phase Equilib. 8(1) , 107-112, (1982)

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