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4-氯苯硫酚

4-氯苯硫酚用途

【用途一】
用作医药、染料中间体
【用途二】
农药和医药的中间体，也用于增塑剂、油类添加剂、润湿剂。

4-氯苯硫酚名称

[ CAS 号 ]:
106-54-7

[ 中文名 ]:
4-氯苯硫酚

[ 英文名 ]:
4-Chlorothiophenol

[中文别名 ]:

[英文别名 ]:

Benzenethiol, 4-chloro-
4-Chloromercaptobenzene
EINECS 203-408-9
MFCD00004847
4-Chlorobenzenethiol
4-Chlorothiophenol

4-氯苯硫酚物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
206.8±13.0 °C at 760 mmHg

[ 熔点 ]:
49-51 °C(lit.)

[ 分子式 ]:
C₆H₅ClS

[ 分子量 ]:
144.622

[ 闪点 ]:
78.6±19.2 °C

[ 精确质量 ]:
143.980042

[ PSA ]:
38.80000

[ LogP ]:
3.36

[ 外观性状 ]:
白色至近乎于白色结晶固体

[ 蒸汽压 ]:
0.3±0.4 mmHg at 25°C

[ 折射率 ]:
1.606

[ 储存条件 ]:
库房通风低温干燥,与食品原料、酸类、氧化剂分开储运

[ 水溶解性 ]:
insoluble

4-氯苯硫酚MSDS

4-氯苯硫酚毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DC1050000

CHEMICAL NAME :: Benzenethiol, p-chloro-

CAS REGISTRY NUMBER :: 106-54-7

BEILSTEIN REFERENCE NO. :: 0605971

LAST UPDATED :: 199709

DATA ITEMS CITED :: 5

MOLECULAR FORMULA :: C6-H5-Cl-S

MOLECULAR WEIGHT :: 144.62

WISWESSER LINE NOTATION :: SHR DG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,989,1986

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,989,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 75 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD691-490 ** TUMORIGENIC DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 8000 mg/kg/20W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Skin and Appendages - tumors

REFERENCE :: CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year: 19,413,1959

4-氯苯硫酚安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R22;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3261 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
DC1050000

[ 包装等级 ]:
III

[ 危险类别 ]:
8

[ 海关编码 ]:
2934999090

4-氯苯硫酚合成路线

4-氯苯硫酚上下游产品

4-氯苯硫酚上游产品

4-氯苯硫酚下游产品

4-氯苯硫酚制备

氯苯经氯磺化、还原而得。

4-氯苯硫酚海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

4-氯苯硫酚文献

Growth of Thin, Anisotropic, π-Conjugated Molecular Films by Stepwise "Click" Assembly of Molecular Building Blocks: Characterizing Reaction Yield, Surface Coverage, and Film Thickness versus Addition Step Number.

J. Am. Chem. Soc. 137 , 8819-28, (2015)

We report the systematic characterization of anisotropic, π-conjugated oligophenyleneimine (OPI) films synthesized using stepwise imine condensation, or "click" chemistry. Film synthesis began with a ...

Concave Rhombic Dodecahedral Au Nanocatalyst with Multiple High-Index Facets for CO2 Reduction.

ACS Nano 9 , 8384-93, (2015)

A concave rhombic dodecahedron (RD) gold nanoparticle was synthesized by adding 4-aminothiophenol (4-ATP) during growth from seeds. This shape is enclosed by stabilized facets of various high-indexes,...

Synthesis and antibacterial activity of some novel 4-oxopyrido[2,3-a]phenothiazines.

Arch. Pharm. (Weinheim) 347(11) , 861-72, (2014)

A series of substituted 4-oxopyrido[2,3-a]phenothiazine-3-carboxylic acids (6a-d) were prepared via cyclization of the corresponding ethyl 7-(arylthioxy)-8-nitro(or azido)-4-oxoquinoline-3-carboxylate...

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