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N-甲基乙二胺

N-甲基乙二胺名称

[ CAS 号 ]:
109-81-9

[ 中文名 ]:
N-甲基乙二胺

[ 英文名 ]:
N-Methyldiaminoethane

[中文别名 ]:

[英文别名 ]:

N-Methylethylenediamine
N'-methylethane-1,2-diamine
MFCD00008165
EINECS 203-707-4

N-甲基乙二胺物理化学性质

[ 密度 ]:
0.85 g/mL at 20 °C(lit.)

[ 沸点 ]:
114-117 °C(lit.)

[ 分子式 ]:
C₃H₁₀N₂

[ 分子量 ]:
74.12490

[ 闪点 ]:
106 °F

[ 精确质量 ]:
74.08440

[ PSA ]:
38.05000

[ LogP ]:
0.25570

[ 外观性状 ]:
透明非常淡黄色液体

[ 蒸汽压 ]:
19.4mmHg at 25°C

[ 折射率 ]:
n20/D 1.4395(lit.)

[ 储存条件 ]:
Flammables area

N-甲基乙二胺MSDS

N-甲基乙二胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KV5250500

CHEMICAL NAME :: Ethylenediamine, N-methyl-

CAS REGISTRY NUMBER :: 109-81-9

BEILSTEIN REFERENCE NO. :: 0878141

LAST UPDATED :: 199710

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C3-H10-N2

MOLECULAR WEIGHT :: 74.15

WISWESSER LINE NOTATION :: Z2M1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 50 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique. (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France) V.9- 1974- Volume(issue)/page/year: 17,235,1982

N-甲基乙二胺安全信息

[ 符号 ]:

GHS02, GHS05

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H314

[ 警示性声明 ]:
P210-P280-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338-P403 + P235

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R10;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
UN 2734 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
KV5250500

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2921290000

N-甲基乙二胺合成路线

N-甲基乙二胺上下游产品

N-甲基乙二胺上游产品

N-甲基乙二胺下游产品

N-甲基乙二胺海关

[ 海关编码 ]: 2921290000

[ 中文概述 ]:
2921290000. 其他无环多胺及其衍生物及它们的盐. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921290000 other acyclic polyamines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

N-甲基乙二胺文献

A chemical genetics analysis of the roles of bypass polymerase DinB and DNA repair protein AlkB in processing N2-alkylguanine lesions in vivo.

PLoS ONE 9(4) , e94716, (2014)

DinB, the E. coli translesion synthesis polymerase, has been shown to bypass several N2-alkylguanine adducts in vitro, including N2-furfurylguanine, the structural analog of the DNA adduct formed by t...

Rationally designed PKA inhibitors for positron emission tomography: Synthesis and cerebral biodistribution of N-(2-(4-bromocinnamylamino)ethyl)-N-[11C]methyl-isoquinoline-5-sulfonamide.

Bioorg. Med. Chem. 16(9) , 5277-84, (2008)

Protein kinase A (PKA) is an important signal transduction target for drug development because it influences critical cellular processes implicated in neuropsychiatric illnesses such as major depressi...

Cu(II)-azide polynuclear complexes of Cu4 building clusters with Schiff-base co-ligands: synthesis, structures, magnetic behavior and DFT studies.

Dalton Trans. 42(11) , 4019-30, (2013)

Three new copper-azido complexes [Cu(4)(N(3))(8)(L(1))(2)](n) (1), [Cu(4)(N(3))(6)(L(2))(2)(H(2)O)(2)] (2), and [Cu(4)(N(3))(6)(L(3))(2)](n) (3) [L(1) is the imine resulting from the condensation of p...

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