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正己胺

正己胺用途

【用途一】
主要用于有机合成
【用途二】
用作有机合成中间体。
【用途三】
用作有机合成中间体及生化试剂。

正己胺名称

[ CAS 号 ]:
111-26-2

[ 中文名 ]:
正己胺

[ 英文名 ]:
Hexylamine

[中文别名 ]:

[英文别名 ]:

Aminohexane
Product HDN
Carboxymethyl-hexadecyl-dimethyl-ammonium-betain
hexan-1-amine
C16BET
N-n-hexylamine
1-Hexanamine
Palmityldimethylbetaine
N,N-Dimethyl-N-hexadecylglycine
hexanamine

正己胺物理化学性质

[ 密度 ]:
0.8±0.1 g/cm3

[ 沸点 ]:
131.8±3.0 °C at 760 mmHg

[ 熔点 ]:
−23 °C(lit.)

[ 分子式 ]:
C₆H₁₅N

[ 分子量 ]:
101.190

[ 闪点 ]:
8.9±0.0 °C

[ 精确质量 ]:
101.120445

[ PSA ]:
26.02000

[ LogP ]:
1.99

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
9.1±0.2 mmHg at 25°C

[ 折射率 ]:
1.422

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 稳定性 ]:
Stable. Incompatible with acids, acid anhydrides, acid chlorides, carbon dioxide, strong oxidizing agents.

[ 水溶解性 ]:
14 g/L (20 ºC)

正己胺MSDS

正己胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MQ4540000

CHEMICAL NAME :: Hexylamine

CAS REGISTRY NUMBER :: 111-26-2

BEILSTEIN REFERENCE NO. :: 1731298

LAST UPDATED :: 199710

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C6-H15-N

MOLECULAR WEIGHT :: 101.22

WISWESSER LINE NOTATION :: Z6

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 11/3/1971

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: UCDS** Union Carbide Data Sheet. (Union Carbide Corp., 39 Old Ridgebury Rd., Danbury, CT 06817) Volume(issue)/page/year: 11/3/1971

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,434,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 670 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 420 uL/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: AMIHBC AMA Archives of Industrial Hygiene and Occupational Medicine. (Chicago, IL) V.2-10, 1950-54. For publisher information, see AEHLAU. Volume(issue)/page/year: 10,61,1954

正己胺安全信息

[ 符号 ]:

GHS02, GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H301 + H311-H314-H411

[ 警示性声明 ]:
P273-P280-P301 + P310-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive;

[ 风险声明 (欧洲) ]:
R10;R20/21/22;R35

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S16

[ 危险品运输编码 ]:
UN 2734 8/PG 1

[ WGK德国 ]:
1

[ RTECS号 ]:
MQ4540000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
29211980

正己胺合成路线

正己胺上下游产品

正己胺上游产品

正己胺下游产品

正己胺制备

1.由甲基正已基甲酮肟用五氯化磷处理而得。将甲基正已基甲酮肟于乙醚中用五氯化磷处理，然后加水搅匀后分层。重排生成的N-乙酰正乙胺溶在乙醚中，将乙醚层分出。蒸馏回收乙醚，剩余的油状液用氢氧化钾稀溶液水解，再进行蒸馏。收集130-133℃馏分即得己胺。

正己胺海关

[ 海关编码 ]: 2921199090

[ 中文概述 ]:
2921199090 其他无环单胺及其衍生物及其盐。监管条件:无。增值税率:17.0%。退税率:9.0%。最惠国关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2921199090 other acyclic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

正己胺文献

Plasmonic ag@oxide nanoprisms for enhanced performance of organic solar cells.

Small 11 , 2454-62, (2015)

Localized surface plasmon resonance (LSPR), light scattering, and lowering the series resistance of noble metal nanoparticles (NPs) provide positive effect on the performance of photovoltaic device. H...

Protic ionic liquids (PILs) nanostructure and physicochemical properties: development of high-throughput methodology for PIL creation and property screens.

Phys. Chem. Chem. Phys. 17(4) , 2357-65, (2014)

A high-throughput approach was developed in order to prepare and dry a series of protic ionic liquids (PILs) from 48 Brønsted acid-base combinations. Many combinations comprised an alkyl carboxylic ac...

Electrospray ionization mass spectrometry of non-covalent complexes formed between N-alkylimidazolium-containing zwitterionic sulfonates and protonated bases.

Eur. J. Mass Spectrom. (Chichester, Eng.) 20(6) , 467-75, (2015)

This paper describes non-covalent complexes between zwitterionic 3-(1-alkyl-3N-imidazolio)- propane-1-sulfonates and different amines. Electrospray ionization (ESI) mass spectrometry and collision- in...

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正己胺