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己酰胺

己酰胺用途

【用途一】
用作有机合成。

己酰胺名称

[ CAS 号 ]:
628-02-4

[ 中文名 ]:
已酰胺

[ 英文名 ]:
n-Hexanamide

[中文别名 ]:

[英文别名 ]:

n-Caproamide
Hexanoamide
hexanoic acid amide
Hexanamide
4-02-00-00929 (Beilstein Handbook Reference)
Capronamide
EINECS 211-024-8
Hexylamide
n-Hexanamide
Alkamid

己酰胺物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
255.0±0.0 °C at 760 mmHg

[ 熔点 ]:
100-102 °C(lit.)

[ 分子式 ]:
C₆H₁₃NO

[ 分子量 ]:
115.174

[ 闪点 ]:
102.2±18.4 °C

[ 精确质量 ]:
115.099716

[ PSA ]:
43.09000

[ LogP ]:
0.89

[ 外观性状 ]:
无色结晶固体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.434

[ 储存条件 ]:
室温

[ 稳定性 ]:
Stable. Combustible. Incompatible with acids, bases, strong oxidizing agents.

己酰胺MSDS

己酰胺毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MN7875000

CHEMICAL NAME :: Hexanamide

CAS REGISTRY NUMBER :: 628-02-4

BEILSTEIN REFERENCE NO. :: 1741923

LAST UPDATED :: 199710

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C6-H13-N-O

MOLECULAR WEIGHT :: 115.20

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 438 gm/kg/1Y-C

TOXIC EFFECTS :: Tumorigenic - Carcinogenic by RTECS criteria Blood - tumors Blood - lymphoma, including Hodgkin's disease

REFERENCE :: JEPTDQ Journal of Environmental Pathology and Toxicology. (Park Forest South, IL) V.1-5(3), 1977-81(?). For publisher information, see JEPOEC. Volume(issue)/page/year: 3(5-6),149,1980

己酰胺安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
MN7875000

[ 海关编码 ]:
2924199090

己酰胺合成路线

己酰胺上下游产品

己酰胺上游产品

己酰胺下游产品

己酰胺制备

由己酸与氨反应而得。将己酸加热到170-180℃，通氨反应约5h，然后蒸馏分离未反应的己酸，将剩余物用苯重结晶，得己酰胺，产率70-80%。

己酰胺海关

[ 海关编码 ]: 2924199090

[ 中文概述 ]:
2924199090. 其他无环酰胺（包括无环氨基甲酸酯)(包括其衍生物及盐）. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 包装

[ Summary ]:
2924199090. other acyclic amides (including acyclic carbamates) and their derivatives; salts thereof. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

己酰胺文献

Zirconium-mediated conversion of amides to nitriles: a surprising additive effect.

Angew. Chem. Int. Ed. Engl. 43(40) , 5375-7, (2004)

Aliphatic and enantioselective amidases: from hydrolysis to acyl transfer activity.

J. Appl. Microbiol. 91(3) , 381-93, (2001)

Carcinogenesis bioassay of acetamide, hexanamide, adipamide, urea and P-tolylurea in mice and rats.

J. Environ. Pathol. Toxicol. 3(5-6) , 149-70, (1980)

As a part of the National Cancer Institute's effort to screen environmental and occupational chemicals for chronic toxicity and carcinogenicity, the amides acetamide, hexanamide, adipamide, urea, and ...

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己酰胺