二氯二茂钛
二氯二茂钛用途
二氯二茂钛名称
[ CAS 号 ]:
1271-19-8
[ 中文名 ]:
二氯二茂钛
[ 英文名 ]:
Titanocene dichloride
[中文别名 ]:
[英文别名 ]:
- Titanocene dichloride
- EINECS 215-035-9
- Bis(cyclopentadienyl)titanium(IV) dichloride
- Di(cyclopentadienyl)titanium(IV) dichloride
- MFCD00003723
- Bis(Cyclopentadienyl)Titanium Dichloride
- Dichlorotitanium(2+) di(2,4-cyclopentadienide)
- Dichlorotitanocene
二氯二茂钛生物活性
二氯二茂钛物理化学性质
[ 密度 ]:
1.6
[ 沸点 ]:
41.5ºC at 760 mmHg
[ 熔点 ]:
287-289ºC
[ 分子式 ]:
C10H10Cl2Ti
[ 分子量 ]:
248.96
[ 精确质量 ]:
247.963898
[ LogP ]:
3.29540
[ 外观性状 ]:
红色至棕色固体
[ 储存条件 ]:
存放于惰性气体之中;避免湿气 (分解)
[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents. Decomposes in water. Moisture sensitive.
[ 水溶解性 ]:
slow decomposition
二氯二茂钛MSDS
二氯二茂钛毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- XR2050000
- CHEMICAL NAME :
- Titanium, dichloro-di-pi-cyclopentadienyl-
- CAS REGISTRY NUMBER :
- 1271-19-8
- LAST UPDATED :
- 199710
- DATA ITEMS CITED :
- 24
- MOLECULAR FORMULA :
- C10-H10-Cl2-Ti
- MOLECULAR WEIGHT :
- 249.00
- WISWESSER LINE NOTATION :
- L50J 0-TI-GG- 0L50J
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 25 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intraperitoneal
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 60 mg/kg
- TOXIC EFFECTS :
- Behavioral - somnolence (general depressed activity) Behavioral - changes in motor activity (specific assay)
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 180 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 6 gm/kg/14D-I
- TOXIC EFFECTS :
- Kidney, Ureter, Bladder - other changes in urine composition Blood - pigmented or nucleated red blood cells Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 4030 mg/kg/13W-I
- TOXIC EFFECTS :
- Cardiac - changes in heart weight Endocrine - changes in thymus weight Nutritional and Gross Metabolic - weight loss or decreased weight gain
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 26 gm/kg/2Y-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Gastrointestinal - tumors
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 720 mg/kg/2Y-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Blood - lymphoma, including Hodgkin's disease Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 75 mg/kg
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Blood - lymphoma, including Hodgkin's disease Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 900 mg/kg/2Y-I
- TOXIC EFFECTS :
- Tumorigenic - neoplastic by RTECS criteria Musculoskeletal - tumors Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TD - Toxic dose (other than lowest)
- ROUTE OF EXPOSURE :
- Intramuscular
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 430 mg/kg/81W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - lymphoma, including Hodgkin's disease Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- DOSE :
- 30 mg/kg
- SEX/DURATION :
- female 10 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Intraperitoneal
- DOSE :
- 60 mg/kg
- SEX/DURATION :
- female 10 day(s) after conception
- TOXIC EFFECTS :
- Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue)
MUTATION DATA
- TYPE OF TEST :
- Morphological transformation
- TEST SYSTEM :
- Rodent - hamster Embryo
- DOSE/DURATION :
- 100 ug/L
- REFERENCE :
- JJIND8 JNCI, Journal of the National Cancer Institute. (Washington, DC) V.61-79, 1978-87. For publisher information, see JNCIEQ. Volume(issue)/page/year: 67,1303,1981
二氯二茂钛安全信息
[ 危害码 (欧洲) ]:
T:Toxic;Xi:Irritant;
[ 风险声明 (欧洲) ]:
R33;R34;R37/38;R40;R61
[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S6-S7/8
[ 危险品运输编码 ]:
UN3261
[ WGK德国 ]:
3
[ RTECS号 ]:
XR2050000
[ 包装等级 ]:
II
[ 危险类别 ]:
8
[ 海关编码 ]:
29310095
二氯二茂钛合成路线
二氯二茂钛上下游产品
二氯二茂钛上游产品
二氯二茂钛下游产品
二氯二茂钛海关
[ 海关编码 ]: 2903890090
[ 中文概述 ]:
2903890090. 其他环烷烃、环烯烃或环萜烯烃的卤化衍生物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:5.5%. 普通关税:30.0%
[ 申报要素 ]: 品名, 成分含量, 用途
[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%
相关化工产品/化学物质:
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价格:
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产品详情:二氯二茂钛
公司名:上海吉至生化科技有限公司
区域:上海市奉贤区
价格:
¥178.0/25g
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产品详情:二氯二茂钛
公司名:上海阿拉丁生化科技股份有限公司
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价格:
¥528.9/100g
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产品详情:二氯二茂钛
公司名:上海创赛科技有限公司
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价格:
¥2197.0/500g
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¥48.0/5g
联系人:夏言
公司名:中山市迪欣化工有限公司
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价格:
¥800.0/500kg
联系人:王洁
产品详情:双(环戊二烯基)二氯化钛
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