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1,4-二氨基蒽醌

1,4-二氨基蒽醌用途

【用途一】
用作合成染料的中间体
【用途二】
用作染料中间体，广泛用于还原灰BG、分散翠蓝HBF及酸性染料等
【用途三】
用于涤纶的染色
【用途四】
蒽醌还原染料、分散染料、酸性染料和中间体。本身为分散染料紫。

1,4-二氨基蒽醌名称

[ CAS 号 ]:
128-95-0

[ 中文名 ]:
1,4-二氨基蒽醌

[ 英文名 ]:
1,4-Diaminoanthraquinone

[中文别名 ]:

[英文别名 ]:

EINECS 204-922-6
1,4-Diaminoanthraquinone
MFCD00001224
1,4-Diaminoanthracene-9,10-dione
1,4-Diamino anthraquinone
9,10-Anthracenedione, 1,4-diamino-
1,4-Diamino-9,10-anthraquinone

1,4-二氨基蒽醌物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
544.2±50.0 °C at 760 mmHg

[ 熔点 ]:
265-269 °C(lit.)

[ 分子式 ]:
C₁₄H₁₀N₂O₂

[ 分子量 ]:
238.241

[ 闪点 ]:
282.9±30.1 °C

[ 精确质量 ]:
238.074234

[ PSA ]:
86.18000

[ LogP ]:
2.98

[ 外观性状 ]:
紫罗兰色粉末

[ 蒸汽压 ]:
0.0±1.5 mmHg at 25°C

[ 折射率 ]:
1.757

[ 储存条件 ]:
Amber Vial, Refrigerator

1,4-二氨基蒽醌MSDS

1,4-二氨基蒽醌毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CB6300000

CHEMICAL NAME :: Anthraquinone, 1,4-diamino-

CAS REGISTRY NUMBER :: 128-95-0

LAST UPDATED :: 199710

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C14-H10-N2-O2

MOLECULAR WEIGHT :: 238.26

WISWESSER LINE NOTATION :: L C666 BV IVJ DZ GZ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5790 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 250 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Microorganism - not otherwise specified

DOSE/DURATION :: 12800 ug/L

REFERENCE :: HEREAY Hereditas (Lund, Sweden). (Gjoerloffsgatan 121, S-261 34 Landskrona, Sweden) V.1- 1947- Volume(issue)/page/year: 99,209,1983 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M2230 No. of Facilities: 245 (estimated) No. of Industries: 6 No. of Occupations: 12 No. of Employees: 3654 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M2230 No. of Facilities: 78 (estimated) No. of Industries: 2 No. of Occupations: 6 No. of Employees: 2483 (estimated)

1,4-二氨基蒽醌安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S22-S36/37

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
CB6300000

[ 海关编码 ]:
2922399090

1,4-二氨基蒽醌合成路线

1,4-二氨基蒽醌上下游产品

1,4-二氨基蒽醌上游产品

1,4-二氨基蒽醌下游产品

1,4-二氨基蒽醌制备

生产方法简述

由对苯二酚与苯酐缩合得1,4-二羟基蒽醌，然后氨化得1,4-二氨基蒽醌隐色体，再以发烟硫酸氧化而得。原料消耗定额：苯酐2131kg/t、对苯二酚887kg/t、氨水（20%）10788kg/t、发烟硫酸3580kg/t。

1,4-二氨基蒽醌海关

[ 海关编码 ]: 2922399090

[ 中文概述 ]:
2922399090 其他氨基醛、氨基酮及其盐（包括氨基醌及其盐，但含有一种以上含氧基的除外）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乙醇胺及其盐应报明色度, 乙醇胺及其盐应报明包装

[ Summary ]:
2922399090 other amino-aldehydes, amino-ketones and amino-quinones, other than those containing more than one kind of oxygen function; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

1,4-二氨基蒽醌文献

Sensitivity of the valence structure in diruthenium complexes as a function of terminal and bridging ligands.

Inorg. Chem. 53(12) , 6082-93, (2014)

The compounds [(acac)2Ru(III)(μ-H2L(2-))Ru(III)(acac)2] (rac, 1, and meso, 1') and [(bpy)2Ru(II)(μ-H2L(•-))Ru(II)(bpy)2](ClO4)3 (meso, [2](ClO4)3) have been structurally, magnetically, spectroelectroc...

Vibrational analysis of 1,4-diaminoanthraquinone and 1,5-dichloroanthraquinone. A joint FTIR, FT-Raman and scaled quantum mechanical study.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 61(8) , 1799-809, (2005)

This work deals with the vibrational spectroscopy of 1,4-diaminoanthraquinone (1,4-DAAQ) and 1,5-dichloroanthraquinone (1,5-DCAQ). The mid and far FTIR and FT-Raman spectra were measured in the conden...

A new dark quencher for use in genetic analysis.

Chem. Commun. (Camb.) (8) , 970-1, (2003)

A novel, long-wavelength, non-fluorescent quencher (LQ), based on 1,4-diaminoanthraquinone, has been incorporated at the 3' and 5'-termini of oligonucleotides. The quencher has been used in Molecular ...

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