硫化钠

硫化钠用途

【用途一】
用作分析试剂及皮革脱毛剂
【用途二】
染料工业中用于生产硫化染料，是硫化青和硫化蓝的原料。印染工业用作溶解硫化染料的助染剂。制革工业中用于水解使生皮脱毛，还用以配制多硫化钠以加速干皮浸水助软。造纸工业用作纸张的蒸煮剂。纺织工业用于人造纤维脱硝和硝化物的还原，以及棉织物染色的媒染剂。制药工业用于生产非那西丁等解热药。此外还用于制硫代硫酸钠、硫氢化钠、多硫化钠等。
【用途三】
用于生产高级硫化染料、优质制革。可用于造纸工业中高档纸张生产。

硫化钠名称

[ CAS 号 ]:
1313-82-2

[ 中文名 ]:
硫化钠

[ 英文名 ]:
Sodium sulfide

[中文别名 ]:

[英文别名 ]:

EINECS 215-211-5
Disodium sulfide
MFCD00003498
Sodium sulfide

硫化钠物理化学性质

[ 密度 ]:
1.86 g/mL at 25 °C(lit.)

[ 沸点 ]:
174ºC

[ 熔点 ]:
950 °C(lit.)

[ 分子式 ]:
Na₂S

[ 分子量 ]:
78.045

[ 精确质量 ]:
77.951607

[ PSA ]:
25.30000

[ 外观性状 ]:
多变色的晶体,带有一种令人厌恶的气味

[ 储存条件 ]:
库房通风低温干燥,与氧化剂、酸类分开存放

[ 稳定性 ]:
Spontaneously flammable. Incompatible with acids, metals, oxidizing agents. Contact with acid liberates toxic gas. Fine dust/air mixtures are explosive. Hygroscopic.

[ 水溶解性 ]:
186 g/L (20 ºC)

硫化钠MSDS

详细MSDS(安全技术说明书)

硫化钠毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WE1905000

CHEMICAL NAME :: Sodium sulfide

CAS REGISTRY NUMBER :: 1313-82-2

LAST UPDATED :: 199710

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: Na2-S

MOLECULAR WEIGHT :: 78.04

WISWESSER LINE NOTATION :: .NA2.S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 208 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 147 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 205 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2 mg/kg/17W-I

TOXIC EFFECTS :: Behavioral - changes in motor activity (specific assay) Blood - pigmented or nucleated red blood cells Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 30(8),30,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X2975 No. of Facilities: 301 (estimated) No. of Industries: 8 No. of Occupations: 13 No. of Employees: 3058 (estimated) No. of Female Employees: 350 (estimated)

硫化钠安全信息

[ 符号 ]:

GHS02, GHS05, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H251-H290-H301 + H311-H314-H400

[ 补充危害声明 ]:
Contact with acids liberates toxic gas., Corrosive to the respiratory tract.

[ 警示性声明 ]:
P273-P280-P301 + P310 + P330-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R31;R34;R50

[ 安全声明 (欧洲) ]:
S26-S45-S61

[ 危险品运输编码 ]:
UN 1849 8/PG 2

[ WGK德国 ]:
2

[ RTECS号 ]:
WE1905000

[ 包装等级 ]:
II

[ 危险类别 ]:
4.2

[ 海关编码 ]:
2830101000

硫化钠制备

1.煤粉还原法将芒硝与煤粉按100：(21～22.5)(重量比)配比混合于800～1100℃高温下煅烧还原，生成物经冷却后用稀碱液热溶成液体，静置澄清后，把上部浓碱液进行浓缩，即得固体硫化钠。经中转槽、制片(或造粒)制得片(或粒)状硫化钠产品。其

2.吸收法用380～420 g/L氢氧化钠溶液吸收含H2S＞85％硫化氢废气，-所得产物经蒸发浓缩，制得硫化钠成品。其

3.硫化钡法用硫酸钠与硫化钡进行复分解反应制沉淀硫酸钡时可以副产得到硫化钠。其

4.气体还原法在有铁催化剂存在下，将氢气(或一氧化碳、发生炉煤气、甲烷气)在沸腾炉中与硫酸钠进行反应，可制得优质无水颗粒状硫化钠(含Na2S 95％～97％)。其
5.将水合硫化钠置于蒸馏瓶中，在砂浴上加热同时通入氢气。起初硫化钠晶体溶于结晶水中，继续加热，蒸发出的水分被氢气夹带出来，直至逸出的氢气不含水分，水合硫化钠即脱水而转变成硫化钠。图I-11 制备硫化钠的装置 6.制备硫化钠的装置将一个称出重量装着纯净金属钠的安瓿的尖端折断，将安瓿放入侧管1中，立即将1密闭。从2抽真空，并小心加热1使金属钠熔融并经过3流到垂熔玻璃砂板4上。在折断安瓿尖端时所生成的氧化钠就残留在4上。然后将干燥的、纯制氮气猛烈地从2通入，打开1取出安瓿，再称量之，即可得金属钠的净重。将所需量的硫由5加入，用干冰冷却剂将6冷却，把约100mL的纯液氨冷凝在硫上，随后将垂熔玻璃砂板4和管7冷却，直到有液氨聚集在滤板上，于是有一些金属钠溶解在这部分液氨中。使4上面的空间在短时间内压力较大，使钠的氨溶液压向6中与硫的氨液混合。重复操作，每次用小部分氨提取滤板4上的钠，直到钠完全溶解为止。这时生成的为多硫化钠。随着钠溶液的加进，多硫化钠分解而转变成硫化钠。移去6外面的干冰浴，NH3会逐渐蒸发，抽真空，再加热至400～500℃，用力振荡可以打碎结晶，将晶体翻入8中，在氮气氛围中，将8熔封拉下，制得的Na2S很纯，收率几近定量。 7. 工业生产主要有两种方法。
（1）碳还原法　将硫酸钠用煤还原，仅应在转炉内进行，产物再经碱熔、洗渣、沉降、浓缩、过滤后得60%含量的硫化钠溶液。反应如下：（2）硫化氢法　将净化后的硫化氢气体通入浓碱溶液中，反应生成硫化碱，控制硫化钠的含量，产物经蒸发浓缩后即为成品。反应如下：

硫化钠海关

[ 海关编码 ]: 2830101000

硫化钠文献

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Orig. Life Evol. Biosph. 45 , 427-37, (2015)

Researchers have formed peptide bonds under a variety of presumed prebiotic conditions. Here it is proposed that these same conditions would have also formed amide bonds between fatty acids and amino ...

Determination of ethanol using permanganate-CdS quantum dot chemiluminescence system.

Luminescence 30 , 660-7, (2015)

A novel and highly sensitive chemiluminescence (CL) method for the determination of ethanol was developed based on the CdS quantum dots (QDs)-permanganate system. It was found that KMnO4 could directl...

Sensitive naked eye detection of hydrogen sulfide and nitric oxide by aza-BODIPY dyes in aqueous medium.

Anal. Chem. 86(18) , 9335-42, (2014)

With an objective to develop optical probes for biologically important anions and neutral molecules, we synthesized three novel NIR absorbing aza-BODIPY derivatives, 3a-3c, and have systematically tun...

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硫化钠