四氟硼酸银
四氟硼酸银用途
合成用
四氟硼酸银名称
[ CAS 号 ]:
14104-20-2
[ 中文名 ]:
四氟硼酸银
[ 英文名 ]:
Silver tetrafluoroborate
[中文别名 ]:
[英文别名 ]:
- Silver tetrafluoroborate
- Borate(1-), tetrafluoro-, silver(1+) (1:1)
- silver(i) tetrafluoroborate
- MFCD00003408
- EINECS 237-956-5
- Silver(1+) tetrafluoroborate
- silver,tetrafluoroborate
四氟硼酸银物理化学性质
[ 熔点 ]:
70-73 °C(lit.)
[ 分子式 ]:
AgBF4
[ 分子量 ]:
194.673
[ 精确质量 ]:
193.908005
[ LogP ]:
1.30000
[ 外观性状 ]:
米色固体
[ 储存条件 ]:
库房通风低温干燥,与食品、酸类分开储运
[ 水溶解性 ]:
SOLUBLE
四氟硼酸银MSDS
四氟硼酸银毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- ED2875000
- CHEMICAL NAME :
- Borate(1-), tetrafluoro-, silver (1+)
- CAS REGISTRY NUMBER :
- 14104-20-2
- LAST UPDATED :
- 199712
- DATA ITEMS CITED :
- 21
- MOLECULAR FORMULA :
- Ag.B-F4
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Intravenous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 56 mg/kg
- REFERENCE :
- CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#06756 *** REVIEWS *** ACGIH TLV-TWA 0.01 mg(Ag)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.01 mg(Ag)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,231,1971 OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-ARAB Republic of Egypt:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-AUSTRALIA:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-BELGIUM:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-DENMARK:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-FINLAND:TWA 0.01 mg(Ag)/m3;STEL 0.03 mg(Ag)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-SWITZERLAND:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.01 mg(Ag)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X7186 No. of Facilities: 7 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 1445 (estimated) No. of Female Employees: 230 (estimated)
四氟硼酸银安全信息
[ 符号 ]:
GHS05
[ 信号词 ]:
Danger
[ 危害声明 ]:
H314
[ 警示性声明 ]:
P280-P305 + P351 + P338-P310
[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ 危害码 (欧洲) ]:
C:Corrosive;
[ 风险声明 (欧洲) ]:
R22;R34
[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45
[ 危险品运输编码 ]:
UN 3260 8/PG 2
[ WGK德国 ]:
3
[ RTECS号 ]:
ED2875000
[ 包装等级 ]:
III
[ 危险类别 ]:
6.1
[ 海关编码 ]:
28432900
四氟硼酸银合成路线
四氟硼酸银上下游产品
四氟硼酸银上游产品
四氟硼酸银下游产品
四氟硼酸银海关
[ 海关编码 ]: 28432900
四氟硼酸银文献
J. Org. Chem. 78(3) , 920-34, (2013)
A novel gold-catalyzed method for the regioselective synthesis of highly substituted pyrroles directly from oximes and alkynes was developed via independent optimization of two key steps of the proces...
Investigating silver coordination to mixed chalcogen ligands.Molecules 17(11) , 13307-29, (2012)
Six silver(I) coordination complexes have been prepared and structurally characterised. Mixed chalcogen-donor acenaphthene ligands L1-L3 [Acenap(EPh)(E'Ph)] (Acenap = acenaphthene-5,6-diyl; E/E' = S, ...
J. Mol. Catal. 79 , 85, (1993)
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