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2-氯乙烷磺酰氯

2-氯乙烷磺酰氯名称

[ CAS 号 ]:
1622-32-8

[ 中文名 ]:
2-氯乙烷磺酰氯

[ 英文名 ]:
2-Chloroethanesulfonyl chloride

[中文别名 ]:

[英文别名 ]:

Ethanesulfonylchloride, 2-chloro-
2-Chloroethanesulfonylchloride
Ethanesulfonyl chloride, 2-chloro-
2-CHLOROETHANE SULFOCHLORIDE
EINECS 216-594-1
MFCD00007461
2-Chloroethanesulfonyl chloride
2-Chloroethylsulfonyl chloride

2-氯乙烷磺酰氯物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
202.4±13.0 °C at 760 mmHg

[ 分子式 ]:
C₂H₄Cl₂O₂S

[ 分子量 ]:
163.023

[ 闪点 ]:
76.2±19.8 °C

[ 精确质量 ]:
161.930908

[ PSA ]:
42.52000

[ LogP ]:
0.83

[ 外观性状 ]:
无色液体

[ 蒸汽压 ]:
0.4±0.4 mmHg at 25°C

[ 折射率 ]:
1.477

[ 储存条件 ]:
库房低温,通风,干燥,防火,与氧化剂,食品原料分开存放

2-氯乙烷磺酰氯MSDS

2-氯乙烷磺酰氯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KI8060000

CHEMICAL NAME :: Ethanesulfonyl chloride, 2-chloro-

CAS REGISTRY NUMBER :: 1622-32-8

BEILSTEIN REFERENCE NO. :: 1751202

LAST UPDATED :: 199701

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C2-H4-Cl2-O2-S

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 240 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 15(6),59,1971

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 420 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 15(6),59,1971

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 250 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 15(6),59,1971 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 10 mg/m3/4H/17W-I

TOXIC EFFECTS :: Brain and Coverings - recordings from specific areas of CNS Vascular - BP lowering not characterized in autonomic section

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 15(6),59,1971

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 10 mg/m3/4H/17W-I

TOXIC EFFECTS :: Vascular - BP lowering not characterized in autonomic section Liver - liver function tests impaired Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol)

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 15(6),59,1971 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.3 mg/m3;Skin JAN 1993

2-氯乙烷磺酰氯安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H314-H330

[ 警示性声明 ]:
P260-P280-P284-P301 + P310-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
T+: Very toxic;

[ 风险声明 (欧洲) ]:
R22

[ 安全声明 (欧洲) ]:
S26-S28-S36/37/39-S45

[ 危险品运输编码 ]:
UN 3390 6.1/PG 1

[ WGK德国 ]:
3

[ RTECS号 ]:
KI8060000

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
2904909090

2-氯乙烷磺酰氯合成路线

2-氯乙烷磺酰氯上下游产品

2-氯乙烷磺酰氯上游产品

2-氯乙烷磺酰氯下游产品

2-氯乙烷磺酰氯海关

[ 海关编码 ]: 2904909090

[ 中文概述 ]:
2904909090 其他烃的磺化、硝化、亚硝化衍生物（不论是否卤化）. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:5.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2904909090 sulphonated, nitrated or nitrosated derivatives of hydrocarbons, whether or not halogenated VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

2-氯乙烷磺酰氯文献

Synthesis of a Library of 1,5,2-Dithiazepine 1,1-Dioxides. Part 1: A One-Pot Sulfonylation/Thia-Michael Protocol.

Heterocycles 86(2) , doi:10.3987/COM-12-S(N)121, (2012)

A novel one-pot sulfonylation/intramolecular thia-Michael protocol is reported for the synthesis of 1,5,2-dithiazepine 1,1-dioxides. Sulfonylation between cysteine ethyl ester/cysteamine and 2-chloroe...

Thermal and high pressure intramolecular Diels-Alder reaction of vinylsulfonamides.

Nat. Protoc. 1(6) , 3076-87, (2006)

Vinylsulfonamides with a furan, carbocyclic, semicyclic or acyclic 1,3-diene moiety are synthetized via a domino elimination-amidation reaction of 2-chloroethanesulfonyl chloride. Intramolecular Diels...

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