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4,4'-二甲苯亚砜

4,4'-二甲苯亚砜名称

[ CAS 号 ]:
1774-35-2

[ 中文名 ]:
4,4'-二甲苯亚砜

[ 英文名 ]:
p-Tolyl sulfoxide (8CI)

[中文别名 ]:

[英文别名 ]:

Benzene, 1,1'-sulfinylbis[4-methyl-
Di-p-tolyl sulfoxide
4,4'-Sulfinylbis(methylbenzene)
1,1'-Sulfinylbis(4-methylbenzene)
4,4'-Ditolyl sulfoxide
di-(4-methylphenyl)sulfoxide
p-Tolyl Sulfoxide
4,4'-Dimethyldiphenylsulphoxide
Bis(4-methylphenyl) sulfoxide
MFCD00008546

4,4'-二甲苯亚砜物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
378.3±31.0 °C at 760 mmHg

[ 熔点 ]:
94-96 °C(lit.)

[ 分子式 ]:
C₁₄H₁₄OS

[ 分子量 ]:
230.325

[ 闪点 ]:
182.6±24.8 °C

[ 精确质量 ]:
230.076538

[ PSA ]:
36.28000

[ LogP ]:
2.98

[ 外观性状 ]:
固体;White to Almost white powder to crystal

[ 蒸汽压 ]:
0.0±0.8 mmHg at 25°C

[ 折射率 ]:
1.641

[ 储存条件 ]:
室温

4,4'-二甲苯亚砜MSDS

4,4'-二甲苯亚砜毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XT4810000

CHEMICAL NAME :: p-Toluene, 1,1'-sulfinylbis-

CAS REGISTRY NUMBER :: 1774-35-2

BEILSTEIN REFERENCE NO. :: 2048587

LAST UPDATED :: 199707

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C14-H14-O-S

MOLECULAR WEIGHT :: 230.34

WISWESSER LINE NOTATION :: 1R DSO&R D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: IJRBA3 International Journal of Radiation Biology and Related Studies in Physics, Chemistry and Medicine. (Taylor & Francis Inc., 242 Cherry St., Philadelphia, PA 19106) V.1- 1959- Volume(issue)/page/year: 3,41,1961

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 180 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#01759

4,4'-二甲苯亚砜安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
XT4810000

[ 海关编码 ]:
2930909090

4,4'-二甲苯亚砜合成路线

4,4'-二甲苯亚砜上下游产品

4,4'-二甲苯亚砜上游产品

4,4'-二甲苯亚砜下游产品

4,4'-二甲苯亚砜海关

[ 海关编码 ]: 2930909090

[ 中文概述 ]:
2930909090. 其他有机硫化合物. 增值税率:17.0%. 退税率:13.0%. 监管条件:无. 最惠国关税:6.5%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

4,4'-二甲苯亚砜文献

Faster Synthesis of Beta-Diketonate Ternary Europium Complexes: Elapsed Times & Reaction Yields.

PLoS ONE 10 , e0143998, (2015)

β-diketonates are customary bidentate ligands in highly luminescent ternary europium complexes, such as Eu(β-diketonate)3(L)2, where L stands for a nonionic ligand. Usually, the syntheses of these com...

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