灭草猛

灭草猛用途

【用途1】
选择性土壤处理剂。在杂草发芽出土过程中，通过幼芽及根系吸收药剂，并在植物体内传导，抑制和破坏敏感植物细胞的核糖核酸和蛋白质合成。适用于大豆、花生、马铃薯、甘蔗和烟草田防治野燕麦、稗草、马唐、狗尾草、香附子、油莎草、牛筋草等禾本科杂草及猪毛菜、马齿苋、藜、田旋花、苘麻等部分阔叶杂草。大豆和花生田用88.5%乳油22.5～30mL/100m²，对水喷雾，随即混土。混土深度10～15cm，药后播种，深度不超过5cm。甘蔗田用88.5%乳油30～37.5mL/100m²，对水喷雾甘蔗浅植田，可在植前施药。甘蔗种植深度>15cm的田块，可植后施药。由于药剂挥发性强，应在施后随即混土。
【用途2】
灭草锰是具有选择性的氨基甲酸酯类除草剂。用作芽前土壤处理后，被抗性作物如大豆、花生等的根吸收，向上传导并迅速代谢，而一年生杂草的根吸收后，却能抑制幼芽生长而致死，适用于大豆、花生、甘蔗、马铃薯等地，防除一年生禾本科及某此阔叶杂草。

灭草猛名称

[ CAS 号 ]:
1929-77-7

[ 中文名 ]:
灭草敌

[ 英文名 ]:
Vernolat

[中文别名 ]:

[英文别名 ]:

Vernam G
S-propyl dipropyl(thiocarbamate)
Vanalate
S-propyl dipropylthiocarbamate
S-Propyl N,N-dipropylthiocarbamate
S-propyl N,N-dipropylcarbamothioate
Perbulate
MFCD00078733
Surpass E
VERNOLATE

灭草猛物理化学性质

[ 密度 ]:
0.959g/cm3

[ 沸点 ]:
272.8ºC at 760mmHg

[ 熔点 ]:
<25℃

[ 分子式 ]:
C₁₀H₂₁NOS

[ 分子量 ]:
203.34500

[ 闪点 ]:
118.8ºC

[ 精确质量 ]:
203.13400

[ PSA ]:
45.61000

[ LogP ]:
3.37160

[ 外观性状 ]:
Liquid | Amber

[ 蒸汽压 ]:
0.00596mmHg at 25°C

[ 折射率 ]:
1.479

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

灭草猛MSDS

详细MSDS(安全技术说明书)

灭草猛毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: FA4725000

CHEMICAL NAME :: Carbamic acid, dipropylthio-, S-propyl ester

CAS REGISTRY NUMBER :: 1929-77-7

BEILSTEIN REFERENCE NO. :: 1767659

LAST UPDATED :: 199710

DATA ITEMS CITED :: 10

MOLECULAR FORMULA :: C10-H21-N-O-S

MOLECULAR WEIGHT :: 203.38

WISWESSER LINE NOTATION :: 3SVN3&3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LC - Lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >1102 mg/m3

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1220 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - respiratory stimulation

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >9 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 7 gm/kg/7D-I

TOXIC EFFECTS :: Skin and Appendages - dermatitis, other (after systemic exposure) Related to Chronic Data - death

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Escherichia coli

DOSE/DURATION :: 5 mg/L

REFERENCE :: GNKAA5 Genetika (Moscow). For English translation, see SOGEBZ. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) No.1- 1965- Volume(issue)/page/year: 22,2416,1986 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

灭草猛安全信息

[ 符号 ]:

GHS07, GHS09

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H411

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xn: Harmful;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
22-51/53-36

[ 安全声明 (欧洲) ]:
61-36-26

[ 危险品运输编码 ]:
UN3082 9/PG 3

[ RTECS号 ]:
FA4725000

[ 海关编码 ]:
2930200015

灭草猛制备

备方法一
由N，N-二丙基氨基甲酰氯与丙硫醇钠反应制得灭草猛。
制备方法二
由二丙胺与COS作用，制得N，N-二丙基氨基硫赶甲酸，再与硫酸二丙酯作用合成灭草猛

3.由N,N-二丙基氨基甲酰氯与丙硫醇钠反应制得灭草猛。或由二丙胺与氧硫化碳及硫酸二丙酯反应制得灭草猛。

灭草猛海关

[ 海关编码 ]: 2930200015

[ 中文概述 ]:
2930200015 丁草敌、克草敌、茵草敌、灭草敌等〔包括环草敌〕。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ Summary ]:
2930200015 butyrate。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:30.0%

灭草猛文献

Genotoxicity of selected herbicides.

Ann. Ist. Super. Sanita 25 , 577-582, (1989)

Twenty-two herbicides were studied in 67 tests for induction of DNA damage, gene mutation and chromosomal changes in vitro and in vivo. Triazine and urea-type herbicides were found to be inactive in a...

Aldehyde dehydrogenase of mice inhibited by thiocarbamate herbicides.

Life Sci. 55 , 1537-1544, (1994)

The herbicide S-ethyl N,N-dipropylthiocarbamate (EPTC) and three of its candidate metabolites (the sulfoxide, N-depropyl and S-methyl derivatives) inhibit mitochondrial low-Km aldehyde dehydrogenase (...

[Determination of maximum permissible exposure level for the herbicide vernam in the air of a working zone].

Gig. Tr. Prof. Zabol. (9) , 49-50, (1983)

更多文献

灭草猛