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2,6-二异丙基苯胺(DIPA)

2,6-二异丙基苯胺(DIPA)用途

2,6-二异丙基苯胺是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

2,6-二异丙基苯胺(DIPA)名称

[ CAS 号 ]:
24544-04-5

[ 中文名 ]:
2,6-二异丙基苯胺

[ 英文名 ]:
2,6-Diisopropylaniline

[中文别名 ]:

[英文别名 ]:

2,6-Diisopropylaniline (DIPA)
Aniline,2,6-diisopropyl
EINECS 246-305-4
2,6-Dilsopropylaniline
2,6-bis(1-methylethyl)aniline
2,6-Diisopropyl-phenylamine
2,6-bis(1-methylethyl)benzenamine
2,6-DIISOPROPYLPHENYLAMINE
MFCD00008887
2,6-(i-Pr)2PhNH2

2,6-二异丙基苯胺(DIPA)生物活性

[ 描述 ]:

2,6-二异丙基苯胺是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[体外研究]

2,6-二异丙基苯胺用作生产碳化二亚胺稳定剂、合成树脂、抗氧化剂和药物活性成分的中间体。它还用于制备多主题席夫碱配体前体和 4,5-b是(2,6-二异丙基苯胺基)-2,7-二-叔丁基-9,9-二甲基硫杂吨与三乙酰甲烷缩合生成-[1-(2.6-二异丙基苯基氨基)乙烯]戊烷-2,4-二酮。此外,它还用于制备 N个-杂环卡宾络合物,用于无环酮的 α-芳基化、卤代芳烃的胺化和水性铃木偶联。除此之外,它还用于制备基于萘二酰亚胺的有机催化剂。

2,6-二异丙基苯胺(DIPA)物理化学性质

[ 密度 ]:
0.9±0.1 g/cm3

[ 沸点 ]:
257.3±9.0 °C at 760 mmHg

[ 熔点 ]:
−45 °C(lit.)

[ 分子式 ]:
C₁₂H₁₉N

[ 分子量 ]:
177.29

[ 闪点 ]:
123.9±0.0 °C

[ 精确质量 ]:
177.151749

[ PSA ]:
26.02000

[ LogP ]:
3.61

[ 外观性状 ]:
透明液体

[ 蒸汽压 ]:
0.0±0.5 mmHg at 25°C

[ 折射率 ]:
1.526

[ 储存条件 ]:
室温

[ 水溶解性 ]:
<0.20 g/L

2,6-二异丙基苯胺(DIPA)MSDS

详细MSDS(安全技术说明书)

2,6-二异丙基苯胺(DIPA)毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: BX4025000

CHEMICAL NAME :: Aniline, 2,6-diisopropyl-

CAS REGISTRY NUMBER :: 24544-04-5

BEILSTEIN REFERENCE NO. :: 2208763

LAST UPDATED :: 199701

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C12-H19-N

MOLECULAR WEIGHT :: 177.32

WISWESSER LINE NOTATION :: 1Y1&R BZ CY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 3204 mg/kg

TOXIC EFFECTS :: Liver - other changes Blood - changes in bone marrow (not otherwise specified) Blood - changes in spleen

REFERENCE :: FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 3,285,1983 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 4005 mg/kg/5D-C

TOXIC EFFECTS :: Liver - changes in liver weight Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: FAATDF Fundamental and Applied Toxicology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1981- Volume(issue)/page/year: 3,285,1983

2,6-二异丙基苯胺(DIPA)安全信息

[ 危害声明 ]:
H412

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ 危害码 (欧洲) ]:
Xi:Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S61-S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
2

[ RTECS号 ]:
BX4025000

[ 海关编码 ]:
29214980

2,6-二异丙基苯胺(DIPA)合成路线

详细合成路线

2,6-二异丙基苯胺(DIPA)上下游产品

2,6-二异丙基苯胺(DIPA)上游产品

2,6-二异丙基苯胺(DIPA)下游产品

2,6-二异丙基苯胺(DIPA)制备

其制备方法是在高压釜中加入苯胺，通入丙烯，在一定的温度和压力下反应

或用邻异丙基苯胺与丙烯在高压釜中反应，邻异丙基苯胺是制备异丙隆的副合利用

2,6-二异丙基苯胺(DIPA)海关

[ 海关编码 ]: 2921420090

[ 中文概述 ]:
2921420090 其他苯胺衍生物及其盐. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ Summary ]:
HS:2921420090 aniline derivatives and their salts VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

2,6-二异丙基苯胺(DIPA)文献

Organo-palladium(II) complexes bearing unsymmetrical N,N,N-pincer ligands: synthesis, structures and oxidatively induced coupling reactions.

Dalton Trans. 44(16) , 7230-41, (2015)

The 2-(2′-aniline)-6-imine-pyridines, 2-(C6H4-2′-NH2)-6-(CMe=NAr)C5H3N (Ar = 4-i-PrC6H4 (HL1a), 2,6-i-Pr2C6H3 (HL1b)), have been synthesised via sequential Stille cross-coupling, deprotection and cond...

O,N,N-pincer ligand effects on oxidatively induced carbon-chlorine coupling reactions at palladium.

Dalton Trans. 44(13) , 6040-51, (2015)

The syntheses of two families of sterically tuneable O,N,N pro-ligands are reported, namely the 2-(phenyl-2'-ol)-6-imine-pyridines, 2-(C6H4-2'-OH),6-(CMe=NAr)C5H3N [Ar = 4-i-PrC6H4 (HL1(a)), 2,6-i-Pr2...

Rigid NON- and NSN-ligand complexes of tetravalent and trivalent uranium: comparison of U-OAr2 and U-SAr2 bonding.

Dalton Trans. 41(26) , 8175-89, (2012)

A rigid NSN-donor proligand, 4,5-bis(2,6-diisopropylanilino)-2,7-di-tert-butyl-9,9-dimethylthioxanthene (H(2)[TXA(2)], 1) was prepared by palladium-catalyzed coupling of 2,6-diisopropylaniline with 4,...

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