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奥克托今

奥克托今用途

该品与硝基胍、特屈儿（四硝基甲基苯胺）、黑索今（环三亚甲基三硝胺，六素精）都属于硝基胺类炸药。可用作传爆药及雷管的装药，除军用外，还用于雷管的主装药、成型炸药，并已逐渐应用于导弹、火箭推进剂等高技术领域。

奥克托今名称

[ CAS 号 ]:
2691-41-0

[ 中文名 ]:
环四亚甲基四硝基胺

[ 英文名 ]:
hmx

[中文别名 ]:

奥克托今

[英文别名 ]:

1,3,5,7-tetranitrooctahydro-1,3,5,7-tetrazocine
Oktogen
HW 4
Octogen
cyclotetranitromethylenetetranitramine
1,3,5,7-tetranitro-1,3,5,7-tetraazacyclooctane
1,3,5,7-Tetrazocine,octahydro-1,3,5,7-tetranitro
cyclotetramethylenetetranitramine
Tetramethylenetetranitramine
Octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine

奥克托今物理化学性质

[ 密度 ]:
1.95 g/cm3

[ 沸点 ]:
906.1ºC

[ 熔点 ]:
286ºC

[ 分子式 ]:
C₄H₈N₈O₈

[ 分子量 ]:
296.15500

[ 闪点 ]:
501.8ºC

[ 精确质量 ]:
296.04700

[ PSA ]:
196.24000

[ 外观性状 ]:
白色结晶固体

[ 蒸汽压 ]:
2.07E-32mmHg at 25°C

[ 折射率 ]:
1.693

[ 储存条件 ]:
库房通风低温干燥,轻装轻卸、与氧化剂、酸类分开存放

奥克托今MSDS

详细MSDS(安全技术说明书)

奥克托今毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: XF7450000

CHEMICAL NAME :: 1,3,5,7-Tetrazocine, octahydro-1,3,5,7-tetranitro-

CAS REGISTRY NUMBER :: 2691-41-0

BEILSTEIN REFERENCE NO. :: 0361386

LAST UPDATED :: 199701

DATA ITEMS CITED :: 16

MOLECULAR FORMULA :: C4-H8-N8-O8

MOLECULAR WEIGHT :: 296.20

WISWESSER LINE NOTATION :: T8N CN EN GNTJ ANW CNW ENW GNW

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A173-743 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 6490 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A173-743

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 25 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A171-598

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 7300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A159-418

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 40(11),17,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Unreported

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 2700 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A159-418

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 40 mg/kg

TOXIC EFFECTS :: Cardiac - pulse rate Lungs, Thorax, or Respiration - other changes

REFERENCE :: EATR** U.S. Army, Edgewood Arsenal Technical Report. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: EB-TR-73040

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 50 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A171-598

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 630 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A171-598

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 10 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A173-743

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 300 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 40(11),17,1975

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 28 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: EATR** U.S. Army, Edgewood Arsenal Technical Report. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: EB-TR-73040 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 153 mg/kg/22W-I

TOXIC EFFECTS :: Brain and Coverings - other degenerative changes Behavioral - alteration of classical conditioning

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 40(11),17,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X5883 No. of Facilities: 3 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 6 (estimated)

奥克托今安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302 + H312 + H332-H319

[ 警示性声明 ]:
P210-P261-P302 + P352 + P312-P304 + P340 + P312-P337 + P313-P403 + P235

[ 危害码 (欧洲) ]:
T: Toxic;F: Flammable;

[ 风险声明 (欧洲) ]:
R11

[ 安全声明 (欧洲) ]:
16-27-45

[ 危险品运输编码 ]:
0226

[ 危险类别 ]:
1.1

[ 海关编码 ]:
2933990060

奥克托今上下游产品

奥克托今上游产品

奥克托今下游产品

奥克托今制备

采用乙酐法生产，先配制乌洛托品的乙酸溶液及硝酸铵的硝酸溶液，然后向硝化器中加入乙酐，再分段加入配制好的溶液，经保温、升温将副产物热解。然后降温、过滤、驱酸，进行水洗，制得粗品。再经过转晶，制成β型的奥克托今成品。

奥克托今海关

[ 海关编码 ]: 2933990060

[ 中文概述 ]:
2933990060 (环)四亚甲基四硝胺〔俗名奥托金HMX〕。监管条件:3(两用物项和技术出口许可证)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 乌洛托品请注明外观, 6－己内酰胺请注明外观, 签约日期

[ 监管条件 ]: 3.两用物项和技术出口许可证

[ Summary ]:
2933990060 1,3,5,7-tetranitro-1,3,5,7-tetrazocane。supervision conditions:3(export license for dual-use item and technologies)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

奥克托今文献

Detection of explosives by positive corona discharge ion mobility spectrometry.

J. Hazard. Mater. 176(1-3) , 692-6, (2010)

In this work, thermal decomposition has been used to detect explosives by IMS in positive polarity. Explosives including Pentaerythritol Tetranitrate (PETN), Cyclo-1,3,5-Trimethylene-2,4,6-Trinitramin...

Phytoremediation of explosives (TNT, RDX, HMX) by wild-type and transgenic plants

J. Environ. Manage. 113 , 85-92, (2012)

The large-scale production and processing of munitions has led to vast environmental pollution by the compounds TNT(2,4,6-trinitrotoluene), RDX(hexahydro-1,3,5-trinitro-1,3,5-triazine) and HMX(octahyd...

Modeling the dissolution of various types of mixed energetic residues under different flow conditions.

J. Hazard. Mater. 235-236 , 138-43, (2012)

Energetic residues are scattered around active ranges due to the detonation events and dissolution is usually the first step for the entry of explosive compounds into the environment. The current mode...

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