亚硝酸二环已胺
亚硝酸二环已胺用途
用作气相缓蚀剂。主要用于金属缓蚀保护和阻止金属锈蚀的继续进行。如用于汽车及汽车零件、减速机箱、内燃机、机床工具、刃具量具等,也可用于武器、雷达等设备的金属保护。气相缓蚀剂具有优良的性能,防锈期长,防锈效果好,复杂与简单的部件均适宜。但对黄铜、锡及其合金有腐蚀作用。
【用途二】
用作气相缓蚀剂。主要用于金属缓蚀保护和阻止金属锈蚀的继续进行。如用于汽车及汽车零件;减速机箱;内燃机;机床工具;刃具量具等,也可用于武器;雷达等设备的金属保护。气相缓蚀剂具有优良的性能,防锈期长,防锈效果好,复杂与简单的部件均适宜。但对黄铜;锡及其合金有腐蚀作用。
亚硝酸二环已胺名称
[ CAS 号 ]:
3129-91-7
[ 中文名 ]:
亚硝酸二环己胺
[ 英文名 ]:
Dicyclohexylamine nitrite
[中文别名 ]:
[英文别名 ]:
- dichau
- dicyclohexyl-amine,nitrite
- vp1260
- vpi260
- MFCD00013128
- vpt-260
- dichan
- dicyclohexyl ammonium nitrite
- N-cyclohexyl-cyclohexanamine
- Dicyclohexyl-amin,Nitrit
亚硝酸二环已胺物理化学性质
[ 密度 ]:
0.91g/cm3
[ 沸点 ]:
256.1ºC at 760mmHg
[ 熔点 ]:
188-194 °C (dec.)
[ 分子式 ]:
C12H24N2O2
[ 分子量 ]:
228.33100
[ 闪点 ]:
100ºC
[ 精确质量 ]:
228.18400
[ PSA ]:
61.69000
[ LogP ]:
3.77430
[ 外观性状 ]:
白色粉末
[ 蒸汽压 ]:
3.3 mm Hg ( 25 °C)
[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运
[ 水溶解性 ]:
水溶性:可溶;可溶于:醇;极微溶:苯,丙酮
亚硝酸二环已胺MSDS
亚硝酸二环已胺毒性和生态
CHEMICAL IDENTIFICATION
- RTECS NUMBER :
- HY4200000
- CHEMICAL NAME :
- Dicyclohexylamine, nitrite
- CAS REGISTRY NUMBER :
- 3129-91-7
- LAST UPDATED :
- 199701
- DATA ITEMS CITED :
- 18
- MOLECULAR FORMULA :
- C12-H23-N.H-N-O2
- MOLECULAR WEIGHT :
- 228.38
- WISWESSER LINE NOTATION :
- L6TJ AM- AL6TJ &..H..N-O2
HEALTH HAZARD DATA
ACUTE TOXICITY DATA
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 330 mg/kg
- TOXIC EFFECTS :
- Liver - other changes Blood - normocytic anemia
- TYPE OF TEST :
- LC - Lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- >90 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Administration onto the skin
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2 gm/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 565 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 80 mg/kg
- TOXIC EFFECTS :
- Behavioral - changes in motor activity (specific assay) Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - dyspnea
- TYPE OF TEST :
- LC - Lethal concentration
- ROUTE OF EXPOSURE :
- Inhalation
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- >90 mg/m3/4H
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 155 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 220 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LDLo - Lowest published lethal dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Mammal - cat
- DOSE/DURATION :
- 50 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Unreported
- SPECIES OBSERVED :
- Rodent - rabbit
- DOSE/DURATION :
- 375 mg/kg
- TOXIC EFFECTS :
- Details of toxic effects not reported other than lethal dose value
- TYPE OF TEST :
- LD50 - Lethal dose, 50 percent kill
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - guinea pig
- DOSE/DURATION :
- 350 mg/kg
- TOXIC EFFECTS :
- Behavioral - convulsions or effect on seizure threshold Behavioral - muscle contraction or spasticity Lungs, Thorax, or Respiration - other changes
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Oral
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 6370 mg/kg/13W-I
- TOXIC EFFECTS :
- Blood - changes in erythrocyte (RBC) count Blood - changes in leukocyte (WBC) count
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - rat
- DOSE/DURATION :
- 2400 mg/kg/48W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
- TYPE OF TEST :
- TDLo - Lowest published toxic dose
- ROUTE OF EXPOSURE :
- Subcutaneous
- SPECIES OBSERVED :
- Rodent - mouse
- DOSE/DURATION :
- 2040 mg/kg/52W-I
- TOXIC EFFECTS :
- Tumorigenic - equivocal tumorigenic agent by RTECS criteria Tumorigenic - tumors at site of application
MUTATION DATA
- TYPE OF TEST :
- Mutation in microorganisms
- TEST SYSTEM :
- Bacteria - Salmonella typhimurium
- DOSE/DURATION :
- 1 mg/plate
- REFERENCE :
- EMMUEG Environmental and Molecular Mutagenesis. (Alan R. Liss, Inc., 41 E. 11th St., New York, NY 10003) V.10- 1987- Volume(issue)/page/year: 11(Suppl 12),1,1988 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.5 mg/m3 JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - A1490 No. of Facilities: 142 (estimated) No. of Industries: 1 No. of Occupations: 5 No. of Employees: 3828 (estimated) No. of Female Employees: 1560 (estimated)
亚硝酸二环已胺安全信息
[ 符号 ]:
GHS02, GHS07
[ 信号词 ]:
Warning
[ 危害声明 ]:
H228-H302 + H332
[ 警示性声明 ]:
P210
[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves
[ 危害码 (欧洲) ]:
Xn
[ 风险声明 (欧洲) ]:
R20/22
[ 安全声明 (欧洲) ]:
S15-S41
[ 危险品运输编码 ]:
UN 2687 4.1/PG 3
[ WGK德国 ]:
1
[ RTECS号 ]:
HY4200000
[ 包装等级 ]:
III
[ 危险类别 ]:
4.1
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亚硝酸二环已胺制备
由二环己胺与磷酸反应生成磷酸二环己胺,然后加入亚硝酸钠反应生成亚硝酸二环己胺,反应生成物干燥得成品。
亚硝酸二环已胺文献
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Retention time prediction of compounds in Grob standard mixture for apolar capillary columns in temperature-programmed gas chromatography.Anal. Bioanal. Chem 393(1) , 327-34, (2009)
This paper presents an extension of a previous investigation in which the behavior of nonpolar compounds in temperature-programmed gas chromatographic runs was predicted using thermodynamic (entropy a...
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