1,2-二溴-2,4-二氰基丁烷

1,2-二溴-2,4-二氰基丁烷用途

【用途一】
广泛用作纺织品、化妆品、胶片、涂料、农作物等领域的杀菌剂，循环水处理的杀菌灭藻剂，石油钻探注水剂等。
【用途二】
用于胶片、皮革、涂料、针纺织品、化妆品等作防霉防腐剂，又作石油钻探注水、工业循环水的杀菌剂
【用途三】
属高效、广谱杀菌剂，对细菌、真菌、藻类均具有广谱活性，可用于工业水处理、农用杀菌及环境卫生消毒等
【用途四】
广谱、低毒的防腐、防霉、灭藻杀菌剂。能抑剂和杀死细菌、真菌和藻类的生长，适用于纺织、皮革等防腐、防霉，工业水灭藻，对果树、柑橘、橡胶、黄瓜、辣椒、番茄、西瓜、蔬菜等作物病害，特别是炭疽病有较好防效。也可用于防治黑星病、灰霉病、疮痂病、霜霉病、软腐病、根肿病。推荐浓度500～833mg/L，即300～500倍液。如防治苹果炭疽病每隔7～10d喷1次，共喷3～4次，药量视果树大小而异。
【用途五】
是一种广谱、高效、低毒的杀菌剂，能抑制和铲除真菌、细菌、藻类的生长，对农作物病害有较好的防治效果，对炭疽病有特效。广泛适用于果树、葡萄、蔬菜、棉花、花生、西瓜、烟草、茶树、花卉等多种作物，防治炭疽病、黑星病、疮痂病、白粉病、锈病、立枯病、猝倒病、根茎腐病、溃疡病、青枯病、角斑病等多种真菌性、细菌性的病害。应用方式灵活，叶面喷雾、种子处理和土壤灌根，都表现出较好的防效。还适用于湖泊环境处理的灭藻，改善渔塘水质；纺织品、皮革等防腐、防毒等。

1,2-二溴-2,4-二氰基丁烷名称

[ CAS 号 ]:
35691-65-7

[ 中文名 ]:
溴菌腈

[ 英文名 ]:
Methyldibromo glutaronitrile

[中文别名 ]:

[英文别名 ]:

1-Bromo-1-(bromomethyl)-1,3-propanedicarbonitrile
(2RS)-2-bromo-2-(bromomethyl)glutaronitrile
Methyldibromoglutaronitrile
1,2-Dibromo-2,4-dicyanobutane
Metacide 38
1-Bromo-1-(bromomethyl)propane-1,3-dicarbonitrile
2-bromo-2-(bromomethyl)-glutaronitrile
Tektamer 38AD
Tektamer
Pentanedinitrile, 2-bromo-2-(bromomethyl)-

1,2-二溴-2,4-二氰基丁烷物理化学性质

[ 密度 ]:
1.9±0.1 g/cm3

[ 沸点 ]:
338.6±42.0 °C at 760 mmHg

[ 熔点 ]:
48-50°C

[ 分子式 ]:
C₆H₆Br₂N₂

[ 分子量 ]:
265.933

[ 闪点 ]:
158.6±27.9 °C

[ 精确质量 ]:
263.889771

[ PSA ]:
47.58000

[ LogP ]:
1.71

[ 外观性状 ]:
白色至黄色晶体

[ 蒸汽压 ]:
0.0±0.7 mmHg at 25°C

[ 折射率 ]:
1.554

[ 储存条件 ]:
2-8°C

1,2-二溴-2,4-二氰基丁烷MSDS

详细MSDS(安全技术说明书)

1,2-二溴-2,4-二氰基丁烷毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MA5599000

CHEMICAL NAME :: Glutaronitrile, 2-bromo-2-(bromomethyl)-

CAS REGISTRY NUMBER :: 35691-65-7

LAST UPDATED :: 199712

DATA ITEMS CITED :: 13

MOLECULAR FORMULA :: C6-H6-Br2-N2

MOLECULAR WEIGHT :: 265.96

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 515 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >13 gm/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 84 gm/kg/3W-I

TOXIC EFFECTS :: Blood - pigmented or nucleated red blood cells Blood - changes in erythrocyte (RBC) count Skin and Appendages - dermatitis, other (after systemic exposure)

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 380 mg/kg/13W-C

TOXIC EFFECTS :: Endocrine - changes in thyroid weight

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 120 mg/kg/4W-I

TOXIC EFFECTS :: Blood - pigmented or nucleated red blood cells

REFERENCE :: JACTDZ Journal of the American College of Toxicology. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1-12, 1982-1993. Discontinued. Volume(issue)/page/year: 15,140,1996 ** REPRODUCTIVE DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

DOSE :: 1750 mg/kg

SEX/DURATION :: female 6-15 day(s) after conception

TOXIC EFFECTS :: Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)

REFERENCE :: TOLED5 Toxicology Letters. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1977- Volume(issue)/page/year: 18(Suppl 1),158,1983 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X1017 No. of Facilities: 512 (estimated) No. of Industries: 9 No. of Occupations: 10 No. of Employees: 17713 (estimated) No. of Female Employees: 3345 (estimated)

1,2-二溴-2,4-二氰基丁烷安全信息

[ 符号 ]:

GHS05, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302-H314

[ 警示性声明 ]:
P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
R22;R36/37/38

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45

[ 危险品运输编码 ]:
3439

[ RTECS号 ]:
MA5599000

[ 包装等级 ]:
III

[ 危险类别 ]:
9

[ 海关编码 ]:
2926909038

1,2-二溴-2,4-二氰基丁烷合成路线

详细合成路线

1,2-二溴-2,4-二氰基丁烷上下游产品

1,2-二溴-2,4-二氰基丁烷上游产品

1,2-二溴-2,4-二氰基丁烷下游产品

1,2-二溴-2,4-二氰基丁烷制备

由丙烯腈制取2-亚甲基戊二腈，再与溴素加成制得溴菌腈。

1,2-二溴-2,4-二氰基丁烷海关

[ 海关编码 ]: 2926909038

[ 中文概述 ]:
2926909038 氰菌胺、百菌清、霜脲氰、溴菌腈。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
HS: 2926909038 fenoxanil Educational tariff:17.0% Tax rebate rate:9.0% Regulatory conditions:S(Registration certificate of import and export) Lowest tariff:6.5% General tariff:30.0%

1,2-二溴-2,4-二氰基丁烷文献

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