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乐杀螨

乐杀螨用途

非内吸性杀螨剂、杀菌剂。农药分析标准。

乐杀螨名称

[ CAS 号 ]:
485-31-4

[ 中文名 ]:
乐杀螨

[ 英文名 ]:
Binapacryl

[中文别名 ]:

2-仲丁基-4，6-二硝基苯基-3-甲基丁烯酸酯

[英文别名 ]:

2-sec-Butyl-4,6-dinitrophenyl 3-methylbut-2-enoate
Morocide
MFCD00055425
Caswell No. 086
Dinoseb methacrylate
2-sec-Butyl-4,6-dinitrophenyl 3,3-Dimethylacrylate
2-sec-butyl-4,6-dinitrophenyl-3,3-dimethylacrylate
Dapacryl
Morrocid
EINECS 207-612-9

乐杀螨物理化学性质

[ 密度 ]:
1.2±0.1 g/cm3

[ 沸点 ]:
436.7±45.0 °C at 760 mmHg

[ 熔点 ]:
68-69ºC

[ 分子式 ]:
C₁₅H₁₈N₂O₆

[ 分子量 ]:
322.313

[ 闪点 ]:
171.7±30.7 °C

[ 精确质量 ]:
322.116486

[ PSA ]:
117.94000

[ LogP ]:
4.90

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.553

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

乐杀螨MSDS

详细MSDS(安全技术说明书)

乐杀螨毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: GQ5600000

CHEMICAL NAME :: Crotonic acid, 3-methyl-, 2-sec-butyl-4,6-dinitrophenyl ester

CAS REGISTRY NUMBER :: 485-31-4

LAST UPDATED :: 199612

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C15-H18-N2-O6

MOLECULAR WEIGHT :: 322.35

WISWESSER LINE NOTATION :: 2Y1&R CNW ENW BOV1UY1&1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 58 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 720 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 1600 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - respiratory stimulation

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 750 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 50 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 750 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 200 mg/kg

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Behavioral - convulsions or effect on seizure threshold Lungs, Thorax, or Respiration - respiratory stimulation

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - chicken

DOSE/DURATION :: >800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 5 mg/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 116,185,1983

乐杀螨安全信息

[ 符号 ]:

GHS07, GHS08, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H302 + H312-H360D-H410

[ 警示性声明 ]:
P201-P273-P280-P308 + P313-P501

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves;type P2 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T: Toxic;N: Dangerous for the environment;

[ 风险声明 (欧洲) ]:
61-21/22-50/53

[ 安全声明 (欧洲) ]:
53-45-60-61

[ 危险品运输编码 ]:
2779

[ WGK德国 ]:
3

[ RTECS号 ]:
GQ5600000

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

乐杀螨制备

2-仲丁基-4,6-二硝基酚与β,β二甲基丙烯酰氯在氮气保护下，于 135 ℃ 搅拌反应5h，减压蒸馏除去过量的酰氯，剩余物用石油醚洗涤，经苯-己烷重结晶，得原药乐杀螨。原料消耗定额：2-仲丁基-4,6-二硝基酚 750kg /t、β,β二甲基丙烯酰氯 1120kg /t。

乐杀螨文献

[Pesticides and liver biochemistry].

Arh. Hig. Rada Toksikol. 40(3) , 277-83, (1989)

The effects of various pesticides (lindane, binapacrile and parathion) on the content of cytochrome P450 and glutathione, and on the activity of lipoperoxidase, xanthine oxidase and transaminases (SGO...

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乐杀螨