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氧化萎锈灵

氧化萎锈灵用途

用于防治谷物和蔬菜锈病。制剂有5％液剂和75％可湿性粉剂。

氧化萎锈灵名称

[ CAS 号 ]:
5259-88-1

[ 中文名 ]:
氧化萎锈灵

[ 英文名 ]:
1,4-Oxathiin-3-carboxamide,5,6-dihydro-2-methyl-N-phenyl-, 4,4-dioxide

[中文别名 ]:

氧化莠锈灵

[英文别名 ]:

EINECS 226-066-2
Plantvax 20
Oxycarboxine
Plantvax
Dcmod
MFCD00055404
Oxicarboxin
OXYCARBOXIN
Vitavax sulfone
Plant wax

氧化萎锈灵物理化学性质

[ 密度 ]:
1.392g/cm3

[ 沸点 ]:
527.6ºC at 760mmHg

[ 熔点 ]:
128-130℃ (ethanol )

[ 分子式 ]:
C₁₂H₁₃NO₄S

[ 分子量 ]:
267.30100

[ 闪点 ]:
272.9ºC

[ 精确质量 ]:
267.05700

[ PSA ]:
80.85000

[ LogP ]:
2.45540

[ 折射率 ]:
1.606

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

氧化萎锈灵MSDS

详细MSDS(安全技术说明书)

氧化萎锈灵毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RP4900000

CHEMICAL NAME :: 1,4-Oxathiin-3-carboxanilide, 5,6-dihydro-2-methyl-, 4,4-dioxide

CAS REGISTRY NUMBER :: 5259-88-1

LAST UPDATED :: 199612

DATA ITEMS CITED :: 3

MOLECULAR FORMULA :: C12-H13-N-O4-S

MOLECULAR WEIGHT :: 267.32

WISWESSER LINE NOTATION :: T6O DSW BUTJ B1 CVMR

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 2 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: WRPCA2 World Review of Pest Control. (London, UK) V.1-10, 1962-71. Discontinued. Volume(issue)/page/year: 9,119,1970

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >16 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 28,30,1974 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

氧化萎锈灵安全信息

[ 符号 ]:

GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H302-H412

[ 警示性声明 ]:
P273

[ 个人防护装备 ]:
dust mask type N95 (US);Eyeshields;Gloves

[ 危害码 (欧洲) ]:
Xn

[ 风险声明 (欧洲) ]:
22-52/53

[ 安全声明 (欧洲) ]:
S61

[ 危险品运输编码 ]:
UN3077 (solid)

[ RTECS号 ]:
RP4900000

[ 海关编码 ]:
2934999038

氧化萎锈灵制备

将萎锈灵用双氧水氧化而得。将 235.2g 萎锈灵加入90ml冰醋酸中，边搅拌边加热，当温度达 100 ℃ ，使之糊状化。然后冷却至 70 ℃ ，搅拌下滴加250ml双氧水，先控制70 -75 ℃，后控制90 -95 ℃下反应。冷却，析出固体物，过滤，水洗，干燥而得粗品，用甲醇重结晶得纯的氧化萎锈灵。

氧化萎锈灵海关

[ 海关编码 ]: 2934999038

[ 中文概述 ]:
2934999038 萎锈灵,氧化萎锈灵。监管条件:S(进出口农药登记证明)。增值税率:17.0%。退税率:9.0%。最低关税:6.5%。普通关税:20.0%

[ 申报要素 ]: 品名, 成分含量, 用途

[ 监管条件 ]: S.进出口农药登记证明

[ Summary ]:
2934999038 2-methyl-n-phenyl-5,6-dihydro-1,4-oxathiine-3-carboxamide 4,4-dioxide。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%

氧化萎锈灵文献

The rate of penetration of leaf tissues by the systemic fungicides benodanil (2-iodobenzanilide) and oxycarboxin (2,3-dihydro-6 methyl-5 phenylcarbamoyl-1,4-oxathin-4,4-dioxide).

Beitr. Trop. Landwirtsch. Veterinarmed. 22(1) , 91-4, (1984)

Leaf washing after application of benodanil and oxycarboxin reduced the protectant effect more than the eradicant effect. Oxycarboxin penetrated more rapidly than did benodanil . Residues of benodanil...

[Methods of identifying and determining plantvax and vitavax in water].

Gig. Sanit. (6) , 54-5, (1984)

Degradation of carboxin (Vitavax) and oxycarboxin (Plantvax) by Pseudomonas aeruginosa isolated from soil.

J. Environ. Sci. Health B 15(5) , 485-505, (1980)

Pseudomonas aeruginosa capable of utilizing carboxin and oxycarboxin as sole sources of carbon and nitrogen was isolated from red sandy loam soil perfused with the solutions of these fungicides. The b...

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