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9-溴菲

9-溴菲用途

【用途一】
用于有机合成。

9-溴菲名称

[ CAS 号 ]:
573-17-1

[ 中文名 ]:
9-溴菲

[ 英文名 ]:
9-Bromophenanthrene

[中文别名 ]:

[英文别名 ]:

9-Bromophenanthrene
Phenanthrene, 9-bromo-
9-Br-phenanthrene
9-Br-Phenanterene
9-monobromophenanthrene
9-Phenathryl bromide
9-Bromo phenanthrene
9-phenanthrenyl bromide
9-bromophenathrene
9-Bromo-phenanthrene

9-溴菲物理化学性质

[ 密度 ]:
1.5±0.1 g/cm3

[ 沸点 ]:
389.7±11.0 °C at 760 mmHg

[ 熔点 ]:
60-64 °C(lit.)

[ 分子式 ]:
C₁₄H₉Br

[ 分子量 ]:
257.125

[ 闪点 ]:
190.3±13.7 °C

[ 精确质量 ]:
255.988754

[ LogP ]:
5.45

[ 外观性状 ]:
黄色晶体粉末

[ 蒸汽压 ]:
0.0±0.9 mmHg at 25°C

[ 折射率 ]:
1.733

[ 储存条件 ]:
室温

[ 水溶解性 ]:
chloroform: 50 mg/mL, clear

9-溴菲MSDS

9-溴菲毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: SF7197000

CHEMICAL NAME :: Phenanthrene, 9-bromo-

CAS REGISTRY NUMBER :: 573-17-1

BEILSTEIN REFERENCE NO. :: 1869927

LAST UPDATED :: 199612

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C14-H9-Br

MOLECULAR WEIGHT :: 257.14

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :: Mutation in microorganisms

TEST SYSTEM :: Bacteria - Salmonella typhimurium

DOSE/DURATION :: 50 ug/plate

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 116,91,1983

9-溴菲安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xn: Harmful;Xi: Irritant;

[ 风险声明 (欧洲) ]:
R20/21/22

[ 安全声明 (欧洲) ]:
S22-S24/25

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ RTECS号 ]:
SF7197000

[ 海关编码 ]:
29036990

9-溴菲合成路线

9-溴菲上下游产品

9-溴菲上游产品

9-溴菲下游产品

9-溴菲制备

将菲溶于干燥的四氯化碳，加热回流，滴加溴素，继续回流逸尽生成的溴化氢。反应液减压蒸除溶剂，继续减压蒸馏，收集177-190℃（0.16kPa）馏分，即为9-溴菲，产率90%-94%。

9-溴菲海关

[ 海关编码 ]: 29036990

9-溴菲文献

Cumulative health risk assessment of halogenated and parent polycyclic aromatic hydrocarbons associated with particulate matters in urban air.

Ecotoxicol. Environ. Saf. 113 , 31-7, (2015)

Halogenated polycyclic aromatic hydrocarbons (HPAHs) have been reported to occur widely in urban air. Nevertheless, knowledge about the human health risk associated with inhalation exposure to HPAHs i...

UVA photoirradiation of halogenated-polycyclic aromatic hydrocarbons leading to induction of lipid peroxidation.

Int. J. Environ. Res. Public Health 3(2) , 191-5, (2006)

Since the finding in the 1930s, a large number of polycyclic aromatic hydrocarbons (PAHs) of different structures have been tested for potential tumorigenicity. Structure-activity relationships of hal...

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