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硫双灭多威标准溶液

硫双灭多威标准溶液用途

Thiodicarb 是一种氨基甲酸酯杀虫剂,用于控制动物,家禽舍和奶牛场中的苍蝇。Thiodicarb 在动物和植物中代谢为灭多威 (methomyl),然后降解为二氧化碳和乙腈。

硫双灭多威标准溶液名称

[ CAS 号 ]:
59669-26-0

[ 中文名 ]:
硫双威

[ 英文名 ]:
thiodicarb

[中文别名 ]:

[英文别名 ]:

semevin
LARVIN
SKIPPER
CHIPCO
NIVRAL
lepicron
MFCD00145401
Thiodicarb
EINECS 261-848-7

硫双灭多威标准溶液生物活性

[ 描述 ]:

[ 相关类别 ]:

研究领域 >> 感染

信号通路 >> 其他 >> 其他

[体外研究]

硫灭威对主要鳞翅目、鞘翅目、双翅目和半翅目害虫都具有口服和接触活性,这些害虫影响棉花、大豆、玉米、葡萄藤、水果和蔬菜[1]。

[参考文献]

[1]. Md Musfiqur Rahman, et al. Simultaneous Determination and Identity Confirmation of Thiodicarb and Its Degradation Product Methomyl in Animal-Derived Foodstuffs Using High-Performance Liquid Chromatography With Fluorescence Detection and Tandem Mass Spectrometry. J Chromatogr B Analyt Technol Biomed Life Sci. 2017 Jan 1;1040:97-104.

硫双灭多威标准溶液物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
433.8±28.0 °C at 760 mmHg

[ 熔点 ]:
168-172°C

[ 分子式 ]:
C₁₀H₁₈N₄O₄S₃

[ 分子量 ]:
354.469

[ 闪点 ]:
216.2±24.0 °C

[ 精确质量 ]:
354.049011

[ PSA ]:
159.70000

[ LogP ]:
1.52

[ 外观性状 ]:
白色结晶粉末

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.575

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

硫双灭多威标准溶液MSDS

详细MSDS(安全技术说明书)

硫双灭多威标准溶液毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: KJ4301050

CHEMICAL NAME :: Ethanimidothioic acid, N,N'-(thiobis((methylimino)carbonyloxy))bis-, dimethyl ester

CAS REGISTRY NUMBER :: 59669-26-0

LAST UPDATED :: 199806

DATA ITEMS CITED :: 9

MOLECULAR FORMULA :: C10-H18-N4-O4-S3

MOLECULAR WEIGHT :: 354.50

WISWESSER LINE NOTATION :: 1SY1&UNOVN1&SN1&VONUY1&S1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 66 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),29,1988

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 520 mg/m3/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FMCHA2 Farm Chemicals Handbook. (Meister Pub., 37841 Euclid Ave., Willoughy, OH 44094) Volume(issue)/page/year: -,C181,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >1600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: JEENAI Journal of Economic Entomology. (Entomological Soc. of America, 4603 Calvert Rd., College Park, MD 20740) V.1- 1908- Volume(issue)/page/year: 70(6),803,1977

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 800 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,817,1991

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 556 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),29,1988

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 6310 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 42(254),29,1988

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - domestic

DOSE/DURATION :: 2023 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: DEVEAA Defense des Vegetaux. (Federation Nationale des Groupements de Protection des Cultures, 149, rue de Bercy, 75595 Paris Cedex, 12, France) V.1- 1947- Volume(issue)/page/year: 38,119,1984 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

硫双灭多威标准溶液安全信息

[ 符号 ]:

GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H301-H330-H400

[ 警示性声明 ]:
P260-P273-P284-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ 危害码 (欧洲) ]:
T+: Very toxic;

[ 风险声明 (欧洲) ]:
R25

[ 安全声明 (欧洲) ]:
S28-S36/37-S45

[ 危险品运输编码 ]:
2757

[ RTECS号 ]:
KJ4301050

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

硫双灭多威标准溶液制备

通过灭多威合成
将一定量的吡啶与二甲苯加重主反应器中搅拌，用冰盐水将温度降至预定值，然后在该温度下，将配制好的二氯化硫溶液慢慢加入到反应器中，加完后继续反应一定时间，再加入灭多威升温到预定值，搅拌反应一定时间后，将反应液冷却到20℃以下，慢慢加入一定量水，搅拌10min以上，停止搅拌，将反应物过滤、洗涤、过滤，重复3次，滤饼称重，在60℃以下干燥即得硫双灭多威产品。滤液分层，二甲苯层待用，水层用二氯甲烷萃取，萃取液蒸发脱溶，回收灭多威，母液加入一定量固碱，充分搅拌，静置分层，油层与二甲苯层合并，并送精馏塔回收吡啶和二甲苯。经工业性试验，产品质量好，收率高。
也有资料报道，以吡啶为溶剂，灭多威与S2Cl2（或SCl2-S2Cl2)作用，制得硫双威，收率91。3%。
通过灭多威肟合成
通过灭多威生产中间体灭多威肟（甲硫乙醛肟，见灭多威的制法）在三乙胺存在下与N-甲基甲酰氟硫醚作用制得硫双威，收率达92%。

硫双灭多威标准溶液文献

Nematicides enhance growth and yield of rotylenchulus reniformis resistant cotton genotypes.

J. Nematol. 46(4) , 365-75, (2015)

Rotylenchulus reniformis resistant LONREN-1×FM966 breeding lines developed at Auburn University have demonstrated that the nematode resistance is accompanied by severe stunting, limited growth, and lo...

Tobacco budworm P-glycoprotein: biochemical characterization and its involvement in pesticide resistance.

Biochim. Biophys. Acta 1291(2) , 155-62, (1996)

Since pesticides have been shown to interact with P-glycoprotein (P-gp), the purpose of this study was to examine the possible role of P-gp in pesticide resistance in the tobacco budworm (Heliothis vi...

Thiodicarb and methomyl tissue distribution in a fatal multiple compounds poisoning.

J. Forensic Sci. 53(2) , 499-502, (2008)

Thiodicarb is a nonsystemic carbamate insecticide whose acetylcholinesterase activity is related to its main methomyl degradation product. A 40-year-old woman was found dead in her car. Empty packages...

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