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3-苯丙酰氯

3-苯丙酰氯用途

用作医药中间体，也用于有机合成

3-苯丙酰氯名称

[ CAS 号 ]:
645-45-4

[ 中文名 ]:
3-苯基丙酰氯

[ 英文名 ]:
3-Phenylpropanoyl chloride

[中文别名 ]:

[英文别名 ]:

MFCD00000748
β-Phenylpropanoyl chloride
3-Phenylpropionyl chloride
3-Phenyl propanoyl chlovide
3-Phenylpropanoyl chloride
β-Phenylpropionyl chloride
EINECS 211-443-6
Benzenepropanoyl chloride

3-苯丙酰氯物理化学性质

[ 密度 ]:
1.1±0.1 g/cm3

[ 沸点 ]:
232.0±0.0 °C at 760 mmHg

[ 熔点 ]:
−7-−5 °C(lit.)

[ 分子式 ]:
C₉H₉ClO

[ 分子量 ]:
168.620

[ 闪点 ]:
108.3±0.0 °C

[ 精确质量 ]:
168.034195

[ PSA ]:
17.07000

[ LogP ]:
2.65

[ 外观性状 ]:
深绿色-黄色

[ 蒸汽压 ]:
0.1±0.4 mmHg at 25°C

[ 折射率 ]:
1.528

[ 储存条件 ]:
-20°C

3-苯丙酰氯MSDS

3-苯丙酰氯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: MW5652395

CHEMICAL NAME :: Hydrocinnamoyl chloride

CAS REGISTRY NUMBER :: 645-45-4

BEILSTEIN REFERENCE NO. :: 0742586

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C9-H9-Cl-O

MOLECULAR WEIGHT :: 168.63

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: CBCCT* "Summary Tables of Biological Tests," National Research Council Chemical-Biological Coordination Center. (National Academy of Science Library, 2101 Constitution Ave., NW, Washington, DC 20418) Volume(issue)/page/year: 6,221,1954

3-苯丙酰氯安全信息

[ 符号 ]:

GHS05, GHS06

[ 信号词 ]:
Danger

[ 危害声明 ]:
H314-H331

[ 警示性声明 ]:
P261-P280-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
C:Corrosive

[ 风险声明 (欧洲) ]:
R20;R34

[ 安全声明 (欧洲) ]:
S26-S36/37/39-S45-S8-S30-S23

[ 危险品运输编码 ]:
UN 3265 8/PG 2

[ WGK德国 ]:
3

[ RTECS号 ]:
MW5652395

[ 包装等级 ]:
II

[ 危险类别 ]:
8

[ 海关编码 ]:
29163900

3-苯丙酰氯合成路线

3-苯丙酰氯上下游产品

3-苯丙酰氯上游产品

3-苯丙酰氯下游产品

3-苯丙酰氯海关

[ 海关编码 ]: 2916399090

[ 中文概述 ]:
2916399090 其他芳香一元羧酸. 增值税率:17.0% 退税率:9.0% 监管条件:无最惠国关税:6.5% 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量, 用途, 丙烯酸、丙烯酸盐或酯应报明包装

[ Summary ]:
2916399090 other aromatic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

3-苯丙酰氯文献

Asymmetric synthesis, structure, and reactivity of unexpectedly stable spiroepoxy-beta-lactones including facile conversion to tetronic acids: application to (+)-maculalactone A.

J. Org. Chem. 74(13) , 4772-81, (2009)

A novel class of small spirocyclic heterocycles, spiroepoxy-beta-lactones (1,4-dioxaspiro[2.3]-hexan-5-ones), is described that exhibit a number of interesting reactivity patterns. These spiroheterocy...

Liver prenylated methylated protein methyl esterase is the same enzyme as Sus scrofa carboxylesterase.

J. Biochem. Mol. Toxicol. 22(1) , 51-62, (2008)

The C-terminal --COOH of prenylated proteins is methylated to --COOCH3. The --COOCH3 ester forms are hydrolyzed by prenylated methylated protein methyl esterase (PMPMEase) to the original acid forms. ...

Electrochemical reduction of phenylacetyl chloride and hydrocinnamoyl chloride at mercury cathodes in acetonitrile. Mubarak MS, et al.

J. Electroanal. Chem. 350(1) , 205-16, (1993)

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