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N,N-二乙基亚磷酰胺二苄基

N,N-二乙基亚磷酰胺二苄基名称

[ CAS 号 ]:
67746-43-4

[ 中文名 ]:
二苄基二乙基胺基膦

[ 英文名 ]:
dibenzyl diethylphosphoramidite

[中文别名 ]:

[英文别名 ]:

MFCD00191987
N-bis(phenylmethoxy)phosphanyl-N-ethylethanamine

N,N-二乙基亚磷酰胺二苄基物理化学性质

[ 密度 ]:
1.06

[ 沸点 ]:
360ºC at 760 mmHg

[ 分子式 ]:
C₁₈H₂₄NO₂P

[ 分子量 ]:
317.36200

[ 闪点 ]:
34ºC

[ 精确质量 ]:
317.15400

[ PSA ]:
35.29000

[ LogP ]:
4.98870

[ 外观性状 ]:
无色至黄色液体

[ 蒸汽压 ]:
0.71 psi ( 55 °C)

[ 折射率 ]:
1.545

[ 储存条件 ]:
glass bottle, -20°C Freezer, Under Inert Atmosphere

[ 水溶解性 ]:
Soluble in chloroform.

N,N-二乙基亚磷酰胺二苄基MSDS

N,N-二乙基亚磷酰胺二苄基安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Warning

[ 危害声明 ]:
H226-H315-H319-H335

[ 警示性声明 ]:
P261-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R10;R36/37/38

[ 安全声明 (欧洲) ]:
16-26-37/39

[ 危险品运输编码 ]:
UN 1993

[ WGK德国 ]:
3

[ 包装等级 ]:
III

[ 危险类别 ]:
3.2

N,N-二乙基亚磷酰胺二苄基合成路线

N,N-二乙基亚磷酰胺二苄基上下游产品

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N,N-二乙基亚磷酰胺二苄基文献

Asymmetric phosphorylation through catalytic P(III) phosphoramidite transfer: enantioselective synthesis of D-myo-inositol-6-phosphate.

Proc. Natl. Acad. Sci. U. S. A. 107(48) , 20620-4, (2010)

Despite the ubiquitous use of phosphoramidite chemistry in the synthesis of biophosphates, catalytic asymmetric phosphoramidite transfer remains largely unexplored for phosphate ester synthesis. We ha...

Synthesis of Casein-Related Peptides and Phosphopeptides. V. The Efficient Global'Phosphite-Triester'Phosphorylation of Protected Serine Derivatives and Peptides by Using Dibenzyl or Di-t-butyl N, N-Diethylphosphoramidite. Perich JW and Johns RB.

Aust. J. Chem. 43(10) , 1623-32, (1990)

Synthesis of dibenzyl glycosyl phosphites using dibenzyl N, N-diethylphosphoramidite as phosphitylating reagent: an effective route to glycosyl phosphates, nucleotides, and glycosides. Sim MM, et al.

J. Am. Chem. Soc. 115(6) , 2260-67, (1993)

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