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氯氟氰菊酯

氯氟氰菊酯用途

对多种鳞翅目幼虫有很好的杀灭效果,亦可有效地防治某些地下害虫,并对某些成虫有拒避作用

氯氟氰菊酯名称

[ CAS 号 ]:
68085-85-8

[ 中文名 ]:
氯氟氰菊酯

[ 英文名 ]:
Cyhalothrin

[中文别名 ]:

[英文别名 ]:

氯氟氰菊酯物理化学性质

[ 密度 ]:
1.344g/cm3

[ 沸点 ]:
498.9ºC at 760 mmHg

[ 熔点 ]:
49.2ºC

[ 分子式 ]:
C23H19ClF3NO3

[ 分子量 ]:
449.85000

[ 闪点 ]:
2ºC

[ 精确质量 ]:
449.10100

[ PSA ]:
59.32000

[ LogP ]:
6.54398

[ 外观性状 ]:
无色固体

[ 折射率 ]:
1.574

[ 储存条件 ]:
库房通风低温干燥,与食品原料分开储运

氯氟氰菊酯MSDS

氯氟氰菊酯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :
GZ1227770
CHEMICAL NAME :
Cyclopropanecarboxylic acid, 3-(2-chloro-3,3,3-trifluoro-1-propenyl)-2,2-dimethyl- , cyano(3-phenoxyphenyl)methyl ester
CAS REGISTRY NUMBER :
68085-85-8
LAST UPDATED :
199710
DATA ITEMS CITED :
10
MOLECULAR FORMULA :
C23-H19-Cl-F3-N-O3
MOLECULAR WEIGHT :
449.88

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
144 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,201,1991
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
83 mg/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,201,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>1 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,201,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,201,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,201,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,201,1991 *** U.S. STANDARDS AND REGULATIONS *** DOT-HAZARD:EXPLOSIVE 1.2D; LABEL:EXPLOSIVE 1.2D (UN0285) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 49,172.101,1992

氯氟氰菊酯安全信息

[ 符号 ]:

GHS02, GHS07

[ 信号词 ]:
Danger

[ 危害声明 ]:
H225-H302-H312-H319-H332-H412

[ 警示性声明 ]:
P210-P273-P280-P305 + P351 + P338

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F,Xn

[ 风险声明 (欧洲) ]:
R11

[ 安全声明 (欧洲) ]:
26-36/37

[ 危险品运输编码 ]:
UN 2902

[ 包装等级 ]:
III

[ 危险类别 ]:
6.1(b)

[ 海关编码 ]:
2926909010

氯氟氰菊酯合成路线

氯氟氰菊酯上下游产品

氯氟氰菊酯制备

先以二甲基戊烯酸甲酯为原料,与三氯三氟乙烷、过氧苯甲酸在催化剂存在下反应,反应产物与特丁醇钠在四氢呋喃溶剂中环合,再经皂化等处理得到1,2-二氯-3,3,3,3-三氟丙烯基-2,'2'-二甲基环丙羧酸。另在液碱、甲醇存在下,由间苯氧基苯甲醛与甲醛反应,得到间苯氧基苯甲醇,再与氰化钠溶液在酸性条件下反应制得α-氰基-间苯氧基苯甲醇。最后以氯化亚砜为氯化剂,使环丙羧酸形成环丙酰氯,然后在吡啶存在下,与α-氰基-间苯氧基苯甲醇制成氯氟氰菊酯。

氯氟氰菊酯海关

[ 海关编码 ]: 2926909010

氯氟氰菊酯文献

Efficacy and duration of three residual insecticides on cotton duck and vinyl tent surfaces for control of the sand fly Phlebotomus papatasi (Diptera: Psychodidae).

US Army Med. Dep. J. , 66-72, (2013)

This study evaluated the toxicity and duration of 3 residual insecticides against the Old World sand fly, Phlebotomus papatasi, an important vector of cutaneous leishmaniasis, on 2 types of tent mater...

Pyrethroid insecticides in municipal wastewater.

Environ. Toxicol. Chem. 32(11) , 2460-8, (2013)

Pyrethroids are widely used insecticides, but minimal information has been published on their presence in municipal wastewater in the United States. Pyrethroids in wastewater from the Sacramento, Cali...

Status of pyrethroid resistance in Anopheles gambiae s. s. M form prior to the scaling up of Long Lasting Insecticidal Nets (LLINs) in Adzopé, Eastern Côte d'Ivoire.

Parasit. Vectors 5 , 289, (2012)

The growing development of pyrethroid resistance constitutes a serious threat to malaria control programmes and if measures are not taken in time, resistance may compromise control efforts in the fore...


更多文献

推荐生产厂家/供应商:

公司名:上海化源世纪贸易有限公司

区域:上海市普陀区

价格:

联系人:徐经理

产品详情:Cyhalothrinsolution100mug/mLinacetonitrile,PESTANAL(R),analyticalstandard


公司名:上海阿拉丁生化科技股份有限公司

区域:上海市浦东新区

价格:
¥227.9/1ml ¥需询单/1g ¥需询单/1g ¥需询单/1g

联系人:阿拉丁

产品详情:氟氰菊酯溶液


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