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R-(+)-1,1'-联萘-2,2'-双二苯膦

R-(+)-1,1'-联萘-2,2'-双二苯膦用途

(R) -BINAP是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

R-(+)-1,1'-联萘-2,2'-双二苯膦名称

[ CAS 号 ]:
76189-55-4

[ 中文名 ]:
R-(+)-1,1'-联萘-2,2'-双二苯膦

[ 英文名 ]:
(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl

[中文别名 ]:

[英文别名 ]:

2,2'-Bis(diphenylphosphanyl)-1,1'-binaphthalene
rac-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl
1,1'-binaphthalene-2,2'-diylbis(diphenylphosphane)
(±)-BINAP
1,1'-Binaphthalen-2,2'-diylbis(diphenylphosphan)
1,1'-Binaphthalene-2,2'-diylbis(diphenylphosphine)
UNII:OX12238KWH
BINAP
MFCD00010805
UNII:970O8508MB

R-(+)-1,1'-联萘-2,2'-双二苯膦生物活性

[ 描述 ]:

(R) -BINAP是一种生物化学试剂,可作为生物材料或有机化合物用于生命科学相关研究。

[ 相关类别 ]:

研究领域 >> 其他

信号通路 >> 其他 >> 其他

[体外研究]

(R) -(+)-2,2'-双(二苯基膦)-1,1'-联萘用作金属介导的不对称催化的手性配体。

R-(+)-1,1'-联萘-2,2'-双二苯膦物理化学性质

[ 沸点 ]:
724.3±55.0 °C at 760 mmHg

[ 熔点 ]:
283-286 °C(lit.)

[ 分子式 ]:
C₄₄H₃₂P₂

[ 分子量 ]:
622.67

[ 闪点 ]:
419.0±37.8 °C

[ 精确质量 ]:
622.197937

[ PSA ]:
27.18000

[ LogP ]:
13.38

[ 外观性状 ]:
白色至淡黄色晶体粉末

[ 蒸汽压 ]:
0.0±2.3 mmHg at 25°C

[ 折射率 ]:
235 ° (C=0.3, Toluene)

[ 储存条件 ]:
存放于惰性气体之中;避免空气

[ 水溶解性 ]:
insoluble

R-(+)-1,1'-联萘-2,2'-双二苯膦MSDS

详细MSDS(安全技术说明书)

R-(+)-1,1'-联萘-2,2'-双二苯膦安全信息

[ 个人防护装备 ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ 危害码 (欧洲) ]:
Xi:Irritant

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S22-S24/25-S37/39-S26

[ 危险品运输编码 ]:
NONH for all modes of transport

[ WGK德国 ]:
3

[ 海关编码 ]:
2902909090

R-(+)-1,1'-联萘-2,2'-双二苯膦上下游产品

R-(+)-1,1'-联萘-2,2'-双二苯膦上游产品

R-(+)-1,1'-联萘-2,2'-双二苯膦下游产品

R-(+)-1,1'-联萘-2,2'-双二苯膦海关

[ 海关编码 ]: 2902909090

[ 中文概述 ]:
2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

R-(+)-1,1'-联萘-2,2'-双二苯膦文献

The preparation of bi-functional organophosphine oxides as potential antitumor agents.

Eur. J. Med. Chem. 45 , 5527-30, (2010)

Following our previously reported pyridinyl phosphine oxides as antitumor agents, we targeted the commercially available C(2)-axial chiral organophosphine ligand catalysts, such as 2,2'-bis(diphenylph...

Desymmetrization of meso-dienyne by asymmetric Pauson-Khand type reaction catalysts.

Chem. Commun. (Camb.) , 1134-1135, (2004)

Desymmetrization of the meso dienynes, such as propargyl 1-vinylallyl N-tosylamides (1a-c) and propargyl 1-vinylallyl ethers (1d-e), by asymmetric Pauson-Khand type reaction catalysts was studied. The...

Catalytic enantioselective hetero-Diels-Alder reactions of an azo compound.

J. Am. Chem. Soc. 128 , 16482, (2006)

This communication describes studies in which an azo hetero-Diels-Alder adduct was furnished in high regio- and enantioselectivity using azopyridine as a reagent and silver as a catalyst. The obtained...

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