二聚环戊二烯

二聚环戊二烯用途

环戊二烯二聚体（或环戊二烯）的主要用途有：
（1）用作乙烯-丙烯二元共聚物（EPDM）的第三组份；
（2）用作合成乙叉降冰片烯（ENB）的原料；
（3）与顺丁烯二酸酐反应得到降冰片烯二酸酐，用作环氧树脂固化剂、聚酯树脂、醇酸树脂、杀虫剂的原料；
（4）环戊二烯的六氯化物——六氯环戊二烯，与顺酐反应得到的六氯化内亚甲基的氢化邻苯二甲酸酐，用作合成树脂的阻燃剂；
（5）二聚环戊二烯用于桐油、亚麻仁油、大豆油、鱼油等的改性，可加快干燥性，提高耐水、耐碱性；（6）二聚环戊二烯树脂可用作橡胶粘合剂、压敏粘接剂、热溶粘合剂、油墨、涂料等；
（7）二聚环戊二烯氧化物可用作注射成型和层压成型树脂；
（8）环戊二烯部分加氢得到的环戊烯，再聚合制得1,5-反式聚环戊烯；
（9）环戊二烯是生产艾氏剂、荻氏剂类杀虫剂原料；
（10）环戊二烯还用于药物合成。例如胃长乐的中间体α-环戊二烯基扁桃酸甲酯，由苯乙酮酸甲酯与环戊二烯加成而得；
（11）加氢后用作高能燃料。
高分子聚合反应的单体。用于制造合成橡胶胶黏剂、医药、农药、合成香料等产品。与马来酸的共聚物可用作涂料、胶黏剂；与顺酐的共聚物可用作纸张施胶剂；与萜烯油的共聚物可制成胶版印刷墨水；与间戊二烯的共聚物可用作橡胶补强剂。本品的四氢化物是火箭及喷气发动机的高能燃料。

二聚环戊二烯名称

[ CAS 号 ]:
77-73-6

[ 中文名 ]:
双环戊二烯

[ 英文名 ]:
Tricyclo[5.2.1.02,6]deca-3,8-diene

[中文别名 ]:

[英文别名 ]:

4,7-Methano-1H-indene, 3a,4,7,7a-tetrahydro-
MFCD00078246
Tricyclo[5.2.1.0]deca-3,8-diene
3a,4,7,7a-tetrahydo-4,7-methano-1H-indene
EINECS 201-052-9
4,7-Methano-1H-indene,3a,4,7,7a-tetrahydro-

二聚环戊二烯物理化学性质

[ 密度 ]:
1.0±0.1 g/cm3

[ 沸点 ]:
170.0 °C at 760 mmHg

[ 熔点 ]:
-1ºC

[ 分子式 ]:
C₁₀H₁₂

[ 分子量 ]:
132.202

[ 闪点 ]:
26 ºC

[ 精确质量 ]:
132.093903

[ LogP ]:
3.30

[ 外观性状 ]:
无色晶体带有一种带有樟脑股气味

[ 蒸汽压 ]:
2.0±0.1 mmHg at 25°C

[ 折射率 ]:
1.571

[ 储存条件 ]:
库房通风低温干燥,与氧化剂分开存放,不宜久储,以防聚合

[ 稳定性 ]:
Stable at room temperature, but may form explosive peroxides if stored in contact with air. Incompatible with oxidizing agents. Decomposes on heating. Flammable. Mixtures of the vapour with air are explosive.

[ 水溶解性 ]:
水溶性：不溶；水溶解度：40 mg/l ；可溶于：乙醚,醇,丙酮,二氯甲烷,甲苯

[ 凝固点 ]:
31.5℃

二聚环戊二烯MSDS

详细MSDS(安全技术说明书)

二聚环戊二烯毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: PC1050000

CHEMICAL NAME :: 4,7-Methanoindene, 3a,4,7,7a-tetrahydro-

CAS REGISTRY NUMBER :: 77-73-6

BEILSTEIN REFERENCE NO. :: 1904092

LAST UPDATED :: 199806

DATA ITEMS CITED :: 42

MOLECULAR FORMULA :: C10-H12

MOLECULAR WEIGHT :: 132.22

WISWESSER LINE NOTATION :: L C555 A DU IUTJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Open irritation test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: AIHAAP American Industrial Hygiene Association Journal. (AIHA, 475 Wolf Ledges Pkwy., Akron, OH 44311) V.19- 1958- Volume(issue)/page/year: 23,95,1962

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

REFERENCE :: 85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,50,1986 ** ACUTE TOXICITY DATA **

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 353 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Behavioral - muscle weakness

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1000 ppm/4H

TOXIC EFFECTS :: Behavioral - tremor Behavioral - ataxia Lungs, Thorax, or Respiration - dyspnea

REFERENCE :: BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 27,1,1970

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. (San Francisco, CA 94117) Volume(issue)/page/year: PH43-64-886

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 190 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: 40QBA3 "Proceedings of the International Congress on Toxicology, Toxicology as a Predictive Science, 1st, Toronto, 1977," Plaa, G.L., and W.A. Duncan, eds., New York, Academic Press, Inc., 1978 Volume(issue)/page/year: -,448,1978

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 145 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 200 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCIUS* Progress Report for Contract No. PH-43-64-886, Submitted to the National Cancer Institute by The Institute of Chemical Biology, University of San Francisco. (San Francisco, CA 94117) Volume(issue)/page/year: PH43-64-886

TYPE OF TEST :: LCLo - Lowest published lethal concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Mammal - dog

DOSE/DURATION :: 773 ppm/1H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 771 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: 5080 mg/kg

TOXIC EFFECTS :: Behavioral - convulsions or effect on seizure threshold Behavioral - muscle weakness

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: LC50 - Lethal concentration, 50 percent kill

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - guinea pig

DOSE/DURATION :: 770 ppm/4H

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Mammal - cattle

DOSE/DURATION :: 1200 mg/kg

TOXIC EFFECTS :: Behavioral - ataxia Gastrointestinal - changes in structure or function of salivary glands Nutritional and Gross Metabolic - weight loss or decreased weight gain

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A093-673

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Mammal - species unspecified

DOSE/DURATION :: 960 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A087-257

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Bird - domestic

DOSE/DURATION :: 1010 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD-A087-257 ** OTHER MULTIPLE DOSE TOXICITY DATA **

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 182 mg/kg/26W-I

TOXIC EFFECTS :: Behavioral - alteration of classical conditioning Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - multiple enzyme effects

REFERENCE :: GISAAA Gigiena i Sanitariya. For English translation, see HYSAAV. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1- 1936- Volume(issue)/page/year: 51(2),77,1986

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1120 mg/kg/28D-I

TOXIC EFFECTS :: Kidney, Ureter, Bladder - changes in bladder weight Blood - changes in serum composition (e.g. TP, bilirubin, cholesterol) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - transaminases

REFERENCE :: ESKHA5 Eisei Shikenjo Hokoku. Bulletin of the Institute of Hygienic Sciences. (Kokuritsu Eisei Shikenjo Kagaku, 18-1 Bushitsu Johobu, Setagaya-ku, Tokyo 158, Japan) V.1- 1886- Volume(issue)/page/year: (108),71,1990

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 250 ppm/6H/2W-I

TOXIC EFFECTS :: Behavioral - somnolence (general depressed activity) Nutritional and Gross Metabolic - weight loss or decreased weight gain Related to Chronic Data - death

REFERENCE :: BJIMAG British Journal of Industrial Medicine. (British Medical Journal, Box 560B, Kennebunkport, ME 04046) V.1- 1944- Volume(issue)/page/year: 27,1,1970

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 35 ppm/7H/18W-I

TOXIC EFFECTS :: Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 5 ppm/6H/13W-I

TOXIC EFFECTS :: Kidney, Ureter, Bladder - other changes in urine composition Nutritional and Gross Metabolic - changes in sodium Nutritional and Gross Metabolic - changes in phosphorus

REFERENCE :: TIHEEC Toxicology and Industrial Health. (Princeton Scientific Pub. Co., POB 2155, Princeton, NJ 08540) V.1- 1985- Volume(issue)/page/year: 8,353,1992

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 20 mg/m3/4H/26W-I

TOXIC EFFECTS :: Behavioral - excitement Vascular - BP elevation not characterized in autonomic section Kidney, Ureter, Bladder - proteinuria

REFERENCE :: GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR) V.1-36, 1957-1992. For publisher information, see MTPEEI Volume(issue)/page/year: 9(12),13,1965

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 72 ppm/7H/2W-I

TOXIC EFFECTS :: Related to Chronic Data - death

REFERENCE :: TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 20,552,1971

TYPE OF TEST :: TCLo - Lowest published toxic concentration

ROUTE OF EXPOSURE :: Inhalation

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 714 ppm/6H/11D-F

REFERENCE :: NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: OTS0536197 *** REVIEWS *** ACGIH TLV-TWA 27 mg/m3 (5 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 5 ppm (30 mg/m3) JAN 1993 OEL-BELGIUM:TWA 5 ppm (27 mg/m3) JAN 1993 OEL-DENMARK:TWA 5 ppm (30 mg/m3) JAN 1993 OEL-FINLAND:TWA 5 ppm (30 mg/m3);STEL 10 ppm (54 mg/m3);Skin JAN 1993 OEL-FRANCE:TWA 5 ppm (30 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 5 ppm (30 mg/m3) JAN 1993 OEL-RUSSIA:STEL 5 mg/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 5 ppm (30 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 5 ppm (30 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO DICYCLOPENTADIENE-air:10H TWA 5 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992 NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83439 No. of Facilities: 2292 (estimated) No. of Industries: 24 No. of Occupations: 38 No. of Employees: 41365 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83439 No. of Facilities: 252 (estimated) No. of Industries: 4 No. of Occupations: 8 No. of Employees: 6248 (estimated) No. of Female Employees: 442 (estimated)

二聚环戊二烯安全信息

[ 符号 ]:

GHS02, GHS06, GHS09

[ 信号词 ]:
Danger

[ 危害声明 ]:
H226-H302-H315-H319-H330-H335-H411

[ 警示性声明 ]:
P260-P273-P284-P305 + P351 + P338-P310

[ 个人防护装备 ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ 危害码 (欧洲) ]:
F:Flammable

[ 风险声明 (欧洲) ]:
R11;R20/22;R36/37/38;R51/53

[ 安全声明 (欧洲) ]:
S36/37-S61

[ 危险品运输编码 ]:
UN 2048

[ WGK德国 ]:
3

[ RTECS号 ]:
PC1050000

[ 包装等级 ]:
III

[ 危险类别 ]:
3.0

[ 海关编码 ]:
29021990

二聚环戊二烯合成路线

详细合成路线

二聚环戊二烯上下游产品

二聚环戊二烯上游产品

二聚环戊二烯下游产品

二聚环戊二烯制备

将煤焦油的轻苯馏分蒸馏，切取＜70℃的苯头馏分，其中含环戊二烯约30%，再经加热，聚合，蒸馏得成品双环戊二烯。以烃裂解工业中的C5馏分为原料，经加热二聚，然后进行减压蒸馏分离而得。其次，以环戊二烯为原料，经二聚亦可制得。工艺流程：（1）以C5馏分为原料，首先把C5馏分加热到80-120℃，使环戊二烯发生二聚。接着进行精馏，由塔底分离得到双环戊二烯馏分。因为该馏分中除环戊二烯、异戊间干烯等外，还混有二烯烃类。把它加热到170℃以上，只有双环戊二烯优先分解、精馏。得到的环戊二烯通过热聚合、精馏，则得到双环戊二烯。（2）可采用热聚合的方法使环戊二烯转变为沸点为170℃的二聚体，然后用蒸馏法提纯。二聚反应在70℃时进行最完全但反应过程很缓慢。采用加热全回流16-18h，再升温至取前馏分（82℃以下）、苯馏分（82℃以上），直至釜温达到110℃为止。釜底残留物为二聚环戊二烯，含量约60%，再经减压蒸馏，可得含量≥99%的二聚体。

二聚环戊二烯海关

[ 海关编码 ]: 2902909090

[ 中文概述 ]:
2902909090. 其他芳香烃. 增值税率:17.0%. 退税率:9.0%. 监管条件:无. 最惠国关税:2.0%. 普通关税:30.0%

[ 申报要素 ]: 品名, 成分含量

[ Summary ]:
2902909090 other aromatic hydrocarbons。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

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A new protocol for the simultaneous determination of methyl tert-butyl ether (MTBE); its main degradation products: tert-butyl alcohol (TBA) and tert-butyl formate (TBF); other gasoline additives, oxy...

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