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苯并蒽酮

苯并蒽酮用途

【用途一】
用于制深色的还原染料
【用途二】
重要的染料中间体，用于生产还原艳绿FFB、还原橄榄绿B、还原橄榄T、还原灰M、还原黑BBN等。

苯并蒽酮名称

[ CAS 号 ]:
82-05-3

[ 中文名 ]:
苯并蒽酮

[ 英文名 ]:
BENZANTHRONE

[中文别名 ]:

[英文别名 ]:

BENZANTHRONE
7H-Benzo[de]anthracen-7-one
de>anthracene-7-one
BENZAMIDE OXIME
benzohydroxamamide
Benzamidoxim
N'-hydroxybenzimdamide
7H-benz<d,e>anthracen-7-one
benzenylaminoxime
benzamidoxide

苯并蒽酮物理化学性质

[ 密度 ]:
1.3±0.1 g/cm3

[ 沸点 ]:
436.2±12.0 °C at 760 mmHg

[ 熔点 ]:
168-170 °C(lit.)

[ 分子式 ]:
C₁₇H₁₀O

[ 分子量 ]:
230.261

[ 闪点 ]:
196.1±14.5 °C

[ 精确质量 ]:
230.073166

[ PSA ]:
17.07000

[ LogP ]:
4.81

[ 外观性状 ]:
淡黄色针状

[ 蒸汽压 ]:
0.0±1.0 mmHg at 25°C

[ 折射率 ]:
1.735

[ 储存条件 ]:
通风低温干燥,与库房食品原料,氢氧化钾,硝基苯分开存放

[ 稳定性 ]:
Stable. Incompatible with strong oxidizing agents.

苯并蒽酮MSDS

详细MSDS(安全技术说明书)

苯并蒽酮毒性和生态

CHEMICAL IDENTIFICATION

RTECS NUMBER :: CX5075000

CHEMICAL NAME :: 7H-Benz(de)anthracen-7-one

CAS REGISTRY NUMBER :: 82-05-3

LAST UPDATED :: 199710

DATA ITEMS CITED :: 11

MOLECULAR FORMULA :: C17-H10-O

MOLECULAR WEIGHT :: 230.27

WISWESSER LINE NOTATION :: L C6666 1A Q IVJ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: Standard Draize test

ROUTE OF EXPOSURE :: Administration into the eye

SPECIES OBSERVED :: Rodent - rabbit

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 1500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 290 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 15 gm/kg/30D-I

TOXIC EFFECTS :: Liver - changes in liver weight Kidney, Ureter, Bladder - changes in bladder weight Blood - changes in erythrocyte (RBC) count

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 117 gm/kg/34W-I

TOXIC EFFECTS :: Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - hepatic microsomal mixed oxidase (dealkylation, hydroxylation, etc.) Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other transferases Biochemical - Enzyme inhibition, induction, or change in blood or tissue levels - other Enzymes

MUTATION DATA

TYPE OF TEST :: Mutation in mammalian somatic cells

TEST SYSTEM :: Human Lymphocyte

DOSE/DURATION :: 3300 ug/L

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 371,123,1996 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-RUSSIA:STEL 0.2 mg/m3 JAN 1993

苯并蒽酮安全信息

[ 危害码 (欧洲) ]:
Xi: Irritant;

[ 风险声明 (欧洲) ]:
R36/37/38

[ 安全声明 (欧洲) ]:
S26-S37/39

[ WGK德国 ]:
3

[ RTECS号 ]:
CX5075000

苯并蒽酮合成路线

详细合成路线

苯并蒽酮上下游产品

苯并蒽酮上游产品

苯并蒽酮下游产品

苯并蒽酮制备

由蒽醌和甘油经下述步骤反应而得。（1）蒽醌在硫酸铜存在下，用铁粉还原生成羟基蒽酮。（2）甘油在浓硫酸作用下失去水分转变为丙烯醛。（3）在硫酸存在下，羟基蒽醌和丙烯醛加合，并失去一分子水形成新环。（4）再用硫酸氧化成苯并蒽酮。原料消耗定额：蒽醌（98%）900kg/t、甘油600kg/t、锌粉440kg/t、硫酸铜（96%）205kg/t、硫酸（100%）5000kg/t。